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US4513164A Expired / Lapsed US ⏱️ 0.0 years remaining

Condensation of natural gas or methane into gasoline range hydrocarbons

Assignee: Individual
•
Filing: 1984-02-14
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Granted: 1985-04-23
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Expires: 2004-02-14
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Abstract

Abstract This invention relates to a new process for the direct conversion of natural gas or methane into gasoline-range hydrocarbons (i.e., synthetic transportation fuels or lower olefins) via catalytic condensation using superacid catalysts.

Inventors

  • 👤 George A. Olah

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 13:10
CPC Classifications
C; C07; C07C; C07C17/00; C07C17/093; C07C17/10; C07C17/26; C07C17/263; C07C2/00; C07C2/76; C07C2/82; C07C2/84; C07C2521/00; C07C2521/16; C07C2521/18; C07C2527/00; C07C2527/02; C07C2527/03; C07C2527/06; C07C2527/08; C07C2527/12; C07C2527/1206; C07C2527/125; C07C2531/00; C07C2531/02; C07C2531/025; C07C2531/06; C07C2531/08; C07C2531/10; Y; Y10; Y10S; Y10S585/00; Y10S585/929; Y10S585/943

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 63 words
A process for the direct heterogeneous catalytic gas-phase oxidative conversion of natural gas or methane into gasoline-range hydrocarbons by reacting natural gas or methane in the presence of an oxidizing agent comprised of air, oxygen-ozone mixture, sulfur, selenium, sulfur trioxide, nitrogen oxides or a halogen in the presence of a superacid catalyst having a Hammett activity function H o of less than -11.9.
Claim 2
Dependent Claim 63 words
A process for the direct heterogeneous catalytic gas-phase oxidative conversion of natural gas or methane into gasoline-range hydrocarbons by reacting natural gas or methane in the presence of an oxidizing agent comprised of air, oxygen-ozone mixture, sulfur, selenium, sulfur trioxide, nitrogen oxides or a halogen in the presence of a superacid catalyst having a Hammett activity function H o of less than -11.9.
Claim 3
Dependent Claim 40 words
The process of claim 1 carried out utilizing solid superacid catalysts of strong Lewis acid fluorides of metals of Groups IV, V and VI of the Periodic Table deposited on a chalconide carrier including alumina, silica, alumina-silica or fluoridated alumina.
Claim 4
Dependent Claim 69 words
The process of claim 1 carried out utilizing a conjugate solid superacid catalyst composed of a strong Bronsted acid component selected from fluorosulfuric acid, perfluoroalkanesulfonic acids of 1 to 18 carbon atoms deposited on a suitable carrier, perfluorinated polymeric resinsulfonic acids or copolymers of perfluorovinylsulfonic acid and tetrafluoroethylene or trifluorochloroethylene complexed with a Lewis acid fluoride of a metal of Groups IV, V and VI of the Periodic Table.
Claim 5
Dependent Claim 23 words
The process of claim 1 carried out at a temperature between 50° to 250° C. and a pressure of 1 to 150 temperatures.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-04-22 1988-10-22 1989-04-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-04-22 1992-10-22 1993-04-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-04-22 1996-10-22 1997-04-23 $7700.00 Window Closed / Lapsed

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