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Patent US4469522A successfully refreshed from Google Patents.
US4469522A
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Process for treating fillers with fluorosilicone compounds
Assignee: General Electric Co
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Filing: 1982-04-16
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Granted: 1984-09-04
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Expires: 2002-04-16
Abstract
Abstract A process for treating fillers with a fluorosilicone compound comprising contacting a filler more preferably a silica filler with a fluorosilicone nitrogen compound. Such a treated filler is preferably incorporated in fluorosilicone room temperature vulcanizable silicone rubber compositions and heat vulcanizable silicone rubber compositions.
Inventors
- 👤 Makoto Matsumoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 15:20
CPC Classifications
C; C08; C08K; C08K9/00; C08K9/08; C09; C09C; C09C1/00; C09C1/28; C09C1/30; C09C1/3081; C09C3/00; C09C3/10; C01; C01P; C01P2006/00; C01P2006/12
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
216 words
A process for treating fillers with a fluorosilicone-nitrogen polymer comprising contacting a filler having a specific surface area of, approximately, 20 to 800 square meters per gram with a fluorine functional silicon-nitrogen polymer comprising: (1) from 3 to 100 mole percent of chemically combined units selected from the class consisting of: ##STR19## and (2) from 0 to 97 mole percent of chemically combined structural units represented by the formula: ##EQU1## wherein the silicon atoms of said silicon-nitrogen polymer are joined by linkages selected from Si-O-Si linkages and Si-N(R 11 )-Si linkages, wherein the free valences of said silicon atoms other than those required to form siloxy and silazy units are joined to a member selected from an R 11 radical and an (R 11 ) 2 N radical where the ratio of the sum of R 11 radicals and (R 11 ) 2 N radicals to the silicon atoms of said silicon nitrogen polymer has a value of from 1.1 to 3, inclusive, where R f is a fluoroalkyl radical, R 11 is a radical selected from the class consisting of hydrogen and monovalent hydrocarbon radicals, R 111 is a radical selected from the class consisting of hydrogen, fluoroalkyl radicals and monovalent hydrocarbon radicals and c is a whole number equal to 0 to 3, inclusive.
Claim 2
Dependent Claim
216 words
A process for treating fillers with a fluorosilicone-nitrogen polymer comprising contacting a filler having a specific surface area of, approximately, 20 to 800 square meters per gram with a fluorine functional silicon-nitrogen polymer comprising: (1) from 3 to 100 mole percent of chemically combined units selected from the class consisting of: ##STR19## and (2) from 0 to 97 mole percent of chemically combined structural units represented by the formula: ##EQU1## wherein the silicon atoms of said silicon-nitrogen polymer are joined by linkages selected from Si-O-Si linkages and Si-N(R 11 )-Si linkages, wherein the free valences of said silicon atoms other than those required to form siloxy and silazy units are joined to a member selected from an R 11 radical and an (R 11 ) 2 N radical where the ratio of the sum of R 11 radicals and (R 11 ) 2 N radicals to the silicon atoms of said silicon nitrogen polymer has a value of from 1.1 to 3, inclusive, where R f is a fluoroalkyl radical, R 11 is a radical selected from the class consisting of hydrogen and monovalent hydrocarbon radicals, R 111 is a radical selected from the class consisting of hydrogen, fluoroalkyl radicals and monovalent hydrocarbon radicals and c is a whole number equal to 0 to 3, inclusive.
Claim 3
Dependent Claim
17 words
A process as in claim 1 wherein the filler is selected from fumed silica and precipitated silica.
Claim 4
Dependent Claim
27 words
A process as in claim 1 wherein there is further present from 0.02 to 1 part by weight of water present per part of said silicon-nitrogen compound.
Claim 5
Dependent Claim
29 words
A process as in claim 3 wherein the contacting of the filler with the silicon-nitrogen compound takes place at a temperature in the range of 100° to 170° C.
Claim 6
Dependent Claim
20 words
A process as in claim 4 wherein the contacting is carried out for a period of at least 0.5 hours.
Claim 7
Dependent Claim
24 words
A process as in claim 5 wherein there is present from 0.1 to 100 parts of silicon-nitrogen compound per 5 to 200 parts filler.
Claim 8
Dependent Claim
9 words
A filler produced by the process of claim 5.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-04 | 1988-03-05 | 1988-09-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-04 | 1992-03-05 | 1992-09-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-04 | 1996-03-05 | 1996-09-04 | $7700.00 | Window Closed / Lapsed |