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US4124560A Expired / Lapsed US ⏱️ 0.0 years remaining

Two-component silicone rubber

Assignee: Bayer AG
•
Filing: 1977-08-03
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Granted: 1978-11-07
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Expires: 1997-08-03
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Abstract

Abstract A room temperature vulcanizable silica-containing silicone rubber can be produced without pretreatment of the silica by mixing specified amounts of (a) a linear organopolysiloxane of the formula ##STR1## (b) silica of a specific surface area of at least about 50 m 2 /g in the presence of water and a modifying agent of the formula (R.sub.3 Si)nX, then adding ##STR2## (E) ANOTHER FILLER OR PIGMENT, THIS CONSTITUTING A FIRST COMPONENT WHICH IS MIXED WITH A SECOND COMPONENT WHICH COMPRISES (f) a silicic acid ester of the formula (RO).sub.3 SiR' (g) a heavy metal catalyst, and (h) a monohydric aliphatic alcohol of the formula R--(CH.sub.2).sub.a --OH even though the silica is not pretreated as was heretofore necessary, the mixtures exhibit good flow properties and the rubber is characterized by improved mechanical properties.

Inventors

  • 👤 Joachim Herzig

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 18:49
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C08K3/36; C08K3/18; C08K5/00; C08K5/04; C08K5/05; C08K5/54; C08L; C08L83/00; C08L83/04; Y; Y10; Y10S; Y10S524/00; Y10S524/906

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 379 words
A vulcanized silicone rubber produced by mixing and vulcanizing a two-component system, component I consisting essentially of (a) about 20 to 100 parts by weight of a linear organopolysiloxane of the formula ##STR6## in which R each independently is a monofunctional hydrocarbon radical, and n is a positive integer of a value such that the viscosity amounts to between about 500 and 1,000,000 cP at a temperature of 25° C., (b) 0 to about 50 parts by weight of a linear organopolysiloxane of the formula ##STR7## in which n is a positive integer of a value such that the viscosity amounts to between about 5 and 1,000 cP at a temperature of 25° C., (c) 0 to about 20 parts by weight of a linear organopolysiloxane of the formula ##STR8## in which R and n are as defined above, m is a positive integer of a value such that the viscosity amounts to between about 2 and 50 cP at a temperature of 25° C., (d) about 10 to 50 parts by weight of a very finely divided pyrogenic silica with a specific surface area according to BET of at least about 50 m 2 /g, and (e) 0 to about 100 parts by weight of another filler or pigment, component I being a mixture obtained by mixing constituents a) and d) in the presence of water and a modifying agent of the formula (R.sub.3 Si).sub.p X in which R and n are as defined above, p is 1 or 2, X is OH, OR, halogen, S, OOCR, NH, NH 2 , NHY, NY or NY 2 , and Y is a monofunctional hydrocarbon radical, and subsequently adding the constituents (b), (c) and (e), and component II consisting essentially of (f) about 20 to 50 parts by weight of a silicic acid ester of the formula (RO).sub.3 SiR' in which R is as defined above, R' is an alkyl or alkoxy radical with up to 6 carbon atoms, (g) about 1 to 20 parts by weight of a catalytically active heavy metal compound, and (h) 0 to about 50 parts by weight of a monohydric aliphatic alcohol of the formula (R--(CH.sub.2).sub.a --OH in which R is as defined above, and a is an integer from 1 to about 10.
Claim 2
Dependent Claim 379 words
A vulcanized silicone rubber produced by mixing and vulcanizing a two-component system, component I consisting essentially of (a) about 20 to 100 parts by weight of a linear organopolysiloxane of the formula ##STR6## in which R each independently is a monofunctional hydrocarbon radical, and n is a positive integer of a value such that the viscosity amounts to between about 500 and 1,000,000 cP at a temperature of 25° C., (b) 0 to about 50 parts by weight of a linear organopolysiloxane of the formula ##STR7## in which n is a positive integer of a value such that the viscosity amounts to between about 5 and 1,000 cP at a temperature of 25° C., (c) 0 to about 20 parts by weight of a linear organopolysiloxane of the formula ##STR8## in which R and n are as defined above, m is a positive integer of a value such that the viscosity amounts to between about 2 and 50 cP at a temperature of 25° C., (d) about 10 to 50 parts by weight of a very finely divided pyrogenic silica with a specific surface area according to BET of at least about 50 m 2 /g, and (e) 0 to about 100 parts by weight of another filler or pigment, component I being a mixture obtained by mixing constituents a) and d) in the presence of water and a modifying agent of the formula (R.sub.3 Si).sub.p X in which R and n are as defined above, p is 1 or 2, X is OH, OR, halogen, S, OOCR, NH, NH 2 , NHY, NY or NY 2 , and Y is a monofunctional hydrocarbon radical, and subsequently adding the constituents (b), (c) and (e), and component II consisting essentially of (f) about 20 to 50 parts by weight of a silicic acid ester of the formula (RO).sub.3 SiR' in which R is as defined above, R' is an alkyl or alkoxy radical with up to 6 carbon atoms, (g) about 1 to 20 parts by weight of a catalytically active heavy metal compound, and (h) 0 to about 50 parts by weight of a monohydric aliphatic alcohol of the formula (R--(CH.sub.2).sub.a --OH in which R is as defined above, and a is an integer from 1 to about 10.
Claim 3
Dependent Claim 16 words
A rubber according to claim 1, wherein a is an integer from about 2 to 5.
Claim 4
Dependent Claim 13 words
A rubber according to claim 1, wherein the modifying agent is hexamethyl disilazane.
Claim 5
Dependent Claim 29 words
A rubber as claimed in claim 1, wherein the modifying agent is used in the presence of about 3 to 20% by weight of water based on component I.
Claim 6
Dependent Claim 155 words
A rubber according to claim 1, wherein in (a) and (b) at least about 70% of the radicals R are methyl and the balance if any are vinyl or phenyl, the viscosity of a) ranging from about 5,000 to 20,000 cP at 25° C., the viscosity of (b) and (c) ranging from about 10 to 50 cP at 25° C., the specific surface area of (d) ranging from about 120 to 250 m 2 /g, component (e) if present is in up to about 50 parts by weight, in at least about 2 to 5 parts of (f) R being ethyl or n-propyl and R' being ethoxy or n-propoxy, the heavy metal of (g) being lead, tin, zirconium, antimony, iron, cadmium, barium, calcium, titanium, bismuth or manganese, and in (h) R is methyl, the modifying agent having been used in the presence of about 3 to 20% by weight of water based on component I.

References Cited (Backward Citations)

US3642685A Cited
US3696127A Cited
US3897376A Cited
US3888815A Cited
US3919136A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-11-06 1982-05-08 1982-11-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-11-06 1986-05-08 1986-11-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-11-06 1990-05-08 1990-11-07 $7700.00 Window Closed / Lapsed

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