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US4469522A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for treating fillers with fluorosilicone compounds

Assignee: General Electric Co
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Filing: 1982-04-16
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Granted: 1984-09-04
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Expires: 2002-04-16
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Abstract

Abstract A process for treating fillers with a fluorosilicone compound comprising contacting a filler more preferably a silica filler with a fluorosilicone nitrogen compound. Such a treated filler is preferably incorporated in fluorosilicone room temperature vulcanizable silicone rubber compositions and heat vulcanizable silicone rubber compositions.

Inventors

  • 👤 Makoto Matsumoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 13:01
CPC Classifications
C; C08; C08K; C08K9/00; C08K9/08; C09; C09C; C09C1/00; C09C1/28; C09C1/30; C09C1/3081; C09C3/00; C09C3/10; C01; C01P; C01P2006/00; C01P2006/12

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 216 words
A process for treating fillers with a fluorosilicone-nitrogen polymer comprising contacting a filler having a specific surface area of, approximately, 20 to 800 square meters per gram with a fluorine functional silicon-nitrogen polymer comprising: (1) from 3 to 100 mole percent of chemically combined units selected from the class consisting of: ##STR19## and (2) from 0 to 97 mole percent of chemically combined structural units represented by the formula: ##EQU1## wherein the silicon atoms of said silicon-nitrogen polymer are joined by linkages selected from Si-O-Si linkages and Si-N(R 11 )-Si linkages, wherein the free valences of said silicon atoms other than those required to form siloxy and silazy units are joined to a member selected from an R 11 radical and an (R 11 ) 2 N radical where the ratio of the sum of R 11 radicals and (R 11 ) 2 N radicals to the silicon atoms of said silicon nitrogen polymer has a value of from 1.1 to 3, inclusive, where R f is a fluoroalkyl radical, R 11 is a radical selected from the class consisting of hydrogen and monovalent hydrocarbon radicals, R 111 is a radical selected from the class consisting of hydrogen, fluoroalkyl radicals and monovalent hydrocarbon radicals and c is a whole number equal to 0 to 3, inclusive.
Claim 2
Dependent Claim 216 words
A process for treating fillers with a fluorosilicone-nitrogen polymer comprising contacting a filler having a specific surface area of, approximately, 20 to 800 square meters per gram with a fluorine functional silicon-nitrogen polymer comprising: (1) from 3 to 100 mole percent of chemically combined units selected from the class consisting of: ##STR19## and (2) from 0 to 97 mole percent of chemically combined structural units represented by the formula: ##EQU1## wherein the silicon atoms of said silicon-nitrogen polymer are joined by linkages selected from Si-O-Si linkages and Si-N(R 11 )-Si linkages, wherein the free valences of said silicon atoms other than those required to form siloxy and silazy units are joined to a member selected from an R 11 radical and an (R 11 ) 2 N radical where the ratio of the sum of R 11 radicals and (R 11 ) 2 N radicals to the silicon atoms of said silicon nitrogen polymer has a value of from 1.1 to 3, inclusive, where R f is a fluoroalkyl radical, R 11 is a radical selected from the class consisting of hydrogen and monovalent hydrocarbon radicals, R 111 is a radical selected from the class consisting of hydrogen, fluoroalkyl radicals and monovalent hydrocarbon radicals and c is a whole number equal to 0 to 3, inclusive.
Claim 3
Dependent Claim 17 words
A process as in claim 1 wherein the filler is selected from fumed silica and precipitated silica.
Claim 4
Dependent Claim 27 words
A process as in claim 1 wherein there is further present from 0.02 to 1 part by weight of water present per part of said silicon-nitrogen compound.
Claim 5
Dependent Claim 29 words
A process as in claim 3 wherein the contacting of the filler with the silicon-nitrogen compound takes place at a temperature in the range of 100° to 170° C.
Claim 6
Dependent Claim 20 words
A process as in claim 4 wherein the contacting is carried out for a period of at least 0.5 hours.
Claim 7
Dependent Claim 24 words
A process as in claim 5 wherein there is present from 0.1 to 100 parts of silicon-nitrogen compound per 5 to 200 parts filler.
Claim 8
Dependent Claim 9 words
A filler produced by the process of claim 5.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-09-04 1988-03-05 1988-09-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-09-04 1992-03-05 1992-09-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-09-04 1996-03-05 1996-09-04 $7700.00 Window Closed / Lapsed

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