Patent US4294743A successfully refreshed from Google Patents.
US4294743A
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Epoxy imide
Assignee: EIDP Inc
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Filing: 1980-06-06
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Granted: 1981-10-13
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Expires: 2000-06-06
Abstract
Abstract A composition useful for making circuit boards which is the reaction product of (a) an epoxy resin or an epoxy novolac resin and optionally, a brominated epoxy resin and (b) a bismaleimide; wherein the product of (a) and (b) is subsequently reacted with a curing agent such as a diamine of the formula H 2 N--R 1 --NH 2 where R 1 is an aromatic, aliphatic or cycloaliphatic group. The composition is used to impregnate a fibrous substrate of fiberglass, high temperature polyamides or graphite fibers which is laminated to a copper sheet; the resulting laminate is used to form circuit boards that have good electrical and physical properties.
Inventors
- 👤 William F. Graham
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 13:17
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/14; B32B27/00; B32B27/04; C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/244; H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/40; H05; H05K; H05K1/00; H05K1/02; H05K1/03; H05K1/0313; H05K1/032; H05K1/0346; H05K1/0353; H05K1/0366; B32B2457/00; B32B2457/08; C08J2363/00; H05K2201/00; H05K2201/02; H05K2201/0275; H05K2201/0278; H05K2201/03; H05K2201/032; H05K2201/0323
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
208 words
A composition comprising 50-70% by weight of a reaction product and about 30-50% by weight of a solvent selected from the group consisting of acetone, methylene dichloride, cyclohexanone, pentanedione, methyl-N-amyl ketone, methylisobutyl ketone, methylethyl ketone; and mixtures thereof; wherein the reaction product consists essentially of about (1) 10-96% by weight, based on the weight of the reaction product, of a blend of the following ##STR14## wherein n is a positive integer sufficient to provide a viscosity of 16,000-25,000 centipoises measured at 25° C. and having an epoxide equivalent of about 180-300 and (b) a brominated epoxy resin of the formula ##STR15## wherein n is a positive integer sufficiently large to provide a viscosity of 250-4,000 centipoises measured at 25° C., and the resin having an epoxide equivalent of about 300-800; (2) 2-60% by weight, based on the weight of the reaction product, of a bismaleimide of the formula ##STR16## wherein (1) and (2) are reacted for about 0.5-2 hours at about 115°-135° C. and subsequently reacting the product of (1) and (2) with (3) 2-30% by weight, based on the weight of the reaction product, of a diamine of the formula ##STR17## to form the reaction product; wherein the molar ratio of bismaleimide to diamine is about 0.6-0.8.
Claim 2
Dependent Claim
208 words
A composition comprising 50-70% by weight of a reaction product and about 30-50% by weight of a solvent selected from the group consisting of acetone, methylene dichloride, cyclohexanone, pentanedione, methyl-N-amyl ketone, methylisobutyl ketone, methylethyl ketone; and mixtures thereof; wherein the reaction product consists essentially of about (1) 10-96% by weight, based on the weight of the reaction product, of a blend of the following ##STR14## wherein n is a positive integer sufficient to provide a viscosity of 16,000-25,000 centipoises measured at 25° C. and having an epoxide equivalent of about 180-300 and (b) a brominated epoxy resin of the formula ##STR15## wherein n is a positive integer sufficiently large to provide a viscosity of 250-4,000 centipoises measured at 25° C., and the resin having an epoxide equivalent of about 300-800; (2) 2-60% by weight, based on the weight of the reaction product, of a bismaleimide of the formula ##STR16## wherein (1) and (2) are reacted for about 0.5-2 hours at about 115°-135° C. and subsequently reacting the product of (1) and (2) with (3) 2-30% by weight, based on the weight of the reaction product, of a diamine of the formula ##STR17## to form the reaction product; wherein the molar ratio of bismaleimide to diamine is about 0.6-0.8.
Claim 3
Dependent Claim
51 words
A process for forming the reaction product of claim 1 which comprises the following steps: (1) contacting the blend of epoxy resin and brominated epoxy resin with bismaleimide at about 115°-135° C. for about 0.5-2.0 hours to form a product and (2) adding the diamine to the product of Step 1.
Claim 4
Dependent Claim
217 words
A composition comprising 50-70% by weight of a reaction product and 30-50% by weight of a solvent selected from the group consisting of acetone, methylene dichloride, cyclohexanone, pentanedione, methyl-N-amyl ketone, methyl isobutyl ketone, methylethyl ketone mixtures thereof; wherein the reaction product consists essentially of about (1) 10-96% by weight, based on the weight of the reaction product, of a blend of the following (a) an epoxy novolac resin of the formula ##STR18## where n is a positive integer and the resin has an epoxide equivalent of about 170-180 and a viscosity of about 1400-2000 centipoises measured at 25° C. and (b) a brominated epoxy resin of the formula ##STR19## wherein n is a positive integer sufficiently large to provide a viscosity of 250-4,000 centipoises measured at 25° C., and the resin having an epoxide equivalent of about 300-800; - 60% by weight, based on the weight of the reaction product, of a bismaleimide of the formula ##STR20## and wherein (1) and (2) are reacted at about 115°-135° C. for about 0.5-2.0 hours and subsequently reacting the product of (1) and (2) with (3) 2-30% by weight, based on the weight of the reaction product, of a diamine of the formula ##STR21## to form the reaction product; wherein the molar ratio of bismaleimide to diamine is about 0.6-0.8.
Claim 5
Dependent Claim
217 words
A composition comprising 50-70% by weight of a reaction product and 30-50% by weight of a solvent selected from the group consisting of acetone, methylene dichloride, cyclohexanone, pentanedione, methyl-N-amyl ketone, methyl isobutyl ketone, methylethyl ketone mixtures thereof; wherein the reaction product consists essentially of about (1) 10-96% by weight, based on the weight of the reaction product, of a blend of the following (a) an epoxy novolac resin of the formula ##STR18## where n is a positive integer and the resin has an epoxide equivalent of about 170-180 and a viscosity of about 1400-2000 centipoises measured at 25° C. and (b) a brominated epoxy resin of the formula ##STR19## wherein n is a positive integer sufficiently large to provide a viscosity of 250-4,000 centipoises measured at 25° C., and the resin having an epoxide equivalent of about 300-800; - 60% by weight, based on the weight of the reaction product, of a bismaleimide of the formula ##STR20## and wherein (1) and (2) are reacted at about 115°-135° C. for about 0.5-2.0 hours and subsequently reacting the product of (1) and (2) with (3) 2-30% by weight, based on the weight of the reaction product, of a diamine of the formula ##STR21## to form the reaction product; wherein the molar ratio of bismaleimide to diamine is about 0.6-0.8.
Claim 6
Dependent Claim
49 words
A process for forming the reaction product of claim 3 which comprises the following steps (1) contacting epoxy novolac resin and brominated epoxy resin with bismaleimide at about 115°-135° C. for about 0.5-2 hours to form a product and (2) adding the daimine to the product of Step (1).
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-12 | 1985-04-13 | 1985-10-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-12 | 1989-04-13 | 1989-10-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-12 | 1993-04-13 | 1993-10-13 | $7700.00 | Window Closed / Lapsed |