US4128598A
Expired / Lapsed
US
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Thermosetting resin compositions having excellent high temperature characteristics
Assignee: Toshiba Chemical Products Co Ltd
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Filing: 1977-06-24
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Granted: 1978-12-05
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Expires: 1997-06-24
Abstract
Abstract Thermosetting resin compounds produced by polymerizing together bismaleimide expressed by the general structural formula: ##STR1## where: R 1 is hydrogen or alkyl group, R 2 is --O--, --CH 2 --, --SO 2 -- or --S--S--, and R 3 is hydrogen, alkyl group or chlorine; Aminophenol expressed by the general structural formula: ##STR2## where R 4 is hydrogen, halogens or alkyl group; A SPECIFIED EPOXY COMPOUND; AND IMIDAZOLE WHICH IS EXPRESSED BY THE GENERAL STRUCTURAL FORMULA: ##STR3## where R 7 to R 10 are hydrogen or alkyl group and R 7 and R 8 may be benzyl or phenyl, and which may be added, if necessary.
Inventors
- 👤 Kiyoji Makino
- 👤 Tsutomu Ohkawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 13:42
CPC Classifications
C; C08; C08L; C08L79/00; C08L79/04; C08L79/08; C08L79/085; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08G73/00; C08G73/06; C08G73/10; C08G73/12; C08G73/125; C08G73/126; C08G73/127; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31518; Y10T428/31522; Y10T442/00; Y10T442/20; Y10T442/2475; Y10T442/2631; Y10T442/2721
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
225 words
A thermosetting resin composition which is essentially prepared from a polymeric reaction product obtained by mixing an addition product of at least one bismaleimide compound expressed by the general structural formula: ##STR11## where: R 1 is, the same or different, hydrogen or alkyl group having one or two carbon atoms, R 2 is --O--, --CH 2 --, --SO 2 -- or --S--S--, and R 3 is, the same or different, hydrogen, chlorine or alkyl group having one or two carbon atoms; and at least one aminophenol compound expressed by the general structural formula: ##STR12## where R 4 is hydrogen, halogens, or alkyl group having one or two carbon atoms, wherein said addition product is formed of from 0.2 to 2 mols of said aminophenol per mol of said bismaleimide; with at least one epoxy compound selected from the group consisting of a compound expressed by the general structural formula: ##STR13## where m is 0 or an integer of 1 to 4, a compound expressed by the general structural formula: ##STR14## where: n is 0 or 1, and R 5 is, the same or different, hydrogen or methyl, a compound expressed by the general structural formula: ##STR15## where: p is 0, 1 or 2, and R 6 is, the same or different, hydrogen, bromine or methyl, and a compound expressed by the general structural formula: ##STR16##
Claim 2
Dependent Claim
225 words
A thermosetting resin composition which is essentially prepared from a polymeric reaction product obtained by mixing an addition product of at least one bismaleimide compound expressed by the general structural formula: ##STR11## where: R 1 is, the same or different, hydrogen or alkyl group having one or two carbon atoms, R 2 is --O--, --CH 2 --, --SO 2 -- or --S--S--, and R 3 is, the same or different, hydrogen, chlorine or alkyl group having one or two carbon atoms; and at least one aminophenol compound expressed by the general structural formula: ##STR12## where R 4 is hydrogen, halogens, or alkyl group having one or two carbon atoms, wherein said addition product is formed of from 0.2 to 2 mols of said aminophenol per mol of said bismaleimide; with at least one epoxy compound selected from the group consisting of a compound expressed by the general structural formula: ##STR13## where m is 0 or an integer of 1 to 4, a compound expressed by the general structural formula: ##STR14## where: n is 0 or 1, and R 5 is, the same or different, hydrogen or methyl, a compound expressed by the general structural formula: ##STR15## where: p is 0, 1 or 2, and R 6 is, the same or different, hydrogen, bromine or methyl, and a compound expressed by the general structural formula: ##STR16##
Claim 3
Dependent Claim
55 words
The thermosetting resin composition according to claim 1, which further contains at least one imidazole compound expressed by the general structural formula: ##STR17## where R 7 to R 10 are, the same or different, hydrogen or alkyl group having one or two carbon atoms, and R 7 and R 8 may be benzyl or phenyl.
Claim 4
Dependent Claim
35 words
The thermosetting resin composition according to claim 1, wherein the bismaleimide expressed by the general structural formula (A) is at least one selected from the group consisting of 4,4'-methylene-bis-(N-phenylmaleimide), 4,4'oxy-bis-(N-phenylmaleimide), 4,4'-sulfone-bis-(N-phenylmaleimide), 4,4'-dithio-bis-(N-phenylmaleimide), 4,4'-methylene-bis-(N-3-chlorophenyleimide) and 4,4'-methylene-bis-(N-2-methylphenyl-maleimide).
Claim 5
Dependent Claim
35 words
The thermosetting resin composition according to claim 1, wherein the aminophenol expressed by the general structural formula (B) is at least one selected from the group consisting of o-aminophenol, m-aminophenol, p-aminophenol, 2-amino-4-chlorophenol, 2-amino-4-methylphenol and 2-amino-4-ethylphenol.
Claim 6
Dependent Claim
33 words
The thermosetting resin composition according to claim 2, wherein the imidazole expressed by the general structural formula (D) is at least one selected from the group consisting of 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-phenylimidazole and 1-benzyl-2-methylimidazole.
Claim 7
Dependent Claim
62 words
The thermosetting resin composition according to claim 1, which is essentially prepared from a polymeric reaction product of bismaleimide expressed by the general structural formula (A) and aminophenol expressed by the general structural formula (B) with 70 to 20% by weight of at least one of said epoxy compound expressed by the general structural formulas (C 1 ) to (C 4 ).
Claim 8
Dependent Claim
35 words
The thermosetting resin composition according to claim 2, wherein the imidazole expressed by the general structural formula (D) is added in an amount corresponding to 0.1 to 5% by weight of the thermosetting resin composition.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-12-04 | 1982-06-05 | 1982-12-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-12-04 | 1986-06-05 | 1986-12-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-12-04 | 1990-06-05 | 1990-12-05 | $7700.00 | Window Closed / Lapsed |