US4127615A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Epoxide resin mixtures
Assignee: BASF Corp
•
Filing: 1977-06-06
•
Granted: 1978-11-28
•
Expires: 1997-06-06
Abstract
Abstract The invention relates to storage-stable, thermosetting mixtures which contain polymaleimides, alkenylphenols and/or alkenylphenol ethers, epoxide compounds with or without allyl groups, and, optionally, curing accelerators for epoxide resins. These mixtures can be converted by curing into high-polymers which have excellent electrical properties (especially at high temperatures) and very good thermal properties.
Inventors
- 👤 Abdul-Cader Zahir
- 👤 Alfred Renner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 11:27
CPC Classifications
C; C08; C08L; C08L79/00; C08L79/04; C08L79/08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/24; C08G59/245; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08G59/62; C08G59/621; C08L63/00
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
225 words
A storage-stable, thermosetting mixture which comprises: (a) a polyimide containing in the molecule at least two radicals of the general formula ##STR11## wherein D represents a bivalent radical containing a carbon-carbon double bond; (b) 0.1 to 10 moles of an akenylphenol, an alkenylphenol ether or mixtures thereof per equivalent of said polyimide; (c) 0.1 to 10 moles per equivalent of said polyimides of an epoxide compound of a mixture of several epoxide compounds selected from the group consisting of: (α) glycidyl ethers of the formula ##STR12## wherein R 3 represents an allyl group or H atom, (β) glycidyl ethers of novolaks (X') which contain two or more epoxy groups of said glycidyl ethers additionally substituted on the aromatic nuclei with one or more allyl groups, (α) polyepoxy adducts (Y'), having two or more epoxy groups per molecule, produced by an advancement reaction of one or more diepoxide compounds with one or more bisphenols or said diepoxide compounds or bisphenols additionally substituted on the aromatic nuclei with one or more allyl groups, (δ) epoxide compounds (Z') produced by the reaction of one or more phenols or said phenols, additionally substituted on the aromatic nuclei with one or more allyl groups, with epichlorohydrin in an alkaline solution, and (d) up to 5 percent by weight, relative to the epoxide resin, of a curing accelerator for epoxide resins.
Claim 2
Dependent Claim
225 words
A storage-stable, thermosetting mixture which comprises: (a) a polyimide containing in the molecule at least two radicals of the general formula ##STR11## wherein D represents a bivalent radical containing a carbon-carbon double bond; (b) 0.1 to 10 moles of an akenylphenol, an alkenylphenol ether or mixtures thereof per equivalent of said polyimide; (c) 0.1 to 10 moles per equivalent of said polyimides of an epoxide compound of a mixture of several epoxide compounds selected from the group consisting of: (α) glycidyl ethers of the formula ##STR12## wherein R 3 represents an allyl group or H atom, (β) glycidyl ethers of novolaks (X') which contain two or more epoxy groups of said glycidyl ethers additionally substituted on the aromatic nuclei with one or more allyl groups, (α) polyepoxy adducts (Y'), having two or more epoxy groups per molecule, produced by an advancement reaction of one or more diepoxide compounds with one or more bisphenols or said diepoxide compounds or bisphenols additionally substituted on the aromatic nuclei with one or more allyl groups, (δ) epoxide compounds (Z') produced by the reaction of one or more phenols or said phenols, additionally substituted on the aromatic nuclei with one or more allyl groups, with epichlorohydrin in an alkaline solution, and (d) up to 5 percent by weight, relative to the epoxide resin, of a curing accelerator for epoxide resins.
Claim 3
Dependent Claim
61 words
A mixture according to claim 1, which contain as polyepoxy adducts (Y') such products which have been produced by an advancement reaction of a diglycidyl ether of the formula ##STR13## wherein R 2 represents one of the radicals --CH 2 -- and ##STR14## and R 3 has the aforegiven meaning, with one or more of the bisphenols of the formulae ##STR15##
Claim 4
Dependent Claim
32 words
A mixture according to claim 1, which contain polyimides having radicals of the formula (I) in which D represents a bivalent radical of the formula ##STR16## wherein R represents hydrogen or methyl.
Claim 5
Dependent Claim
23 words
A mixture according to claim 1, which contain polyimides having the radical of the formula (I) two or three times in the molecule.
Claim 6
Dependent Claim
30 words
A mixture according to claim 3, which contain as polyimide a compound of the general formula ##STR17## wherein L represents a bivalent organic radical having 2 to 30 C atoms.
Claim 7
Dependent Claim
45 words
A mixture according to claim 5, which contain as polyimide a compound of the formula (VII) wherein L represents a radical of the formula ##STR18## in which R 1 represents one of the radicals --CH 2 --, ##STR19## --SO 2 --, --SO--, --S-- and --O--.
Claim 8
Dependent Claim
11 words
A mixture according to claim 6, which contain as polyimide 4,4'-bis-maleimidodiphenylmethane.
Claim 9
Dependent Claim
19 words
A mixture according to claim 1, which additionally contain monoimides containing the radical of the formula I, preferably monomaleimides.
Claim 10
Dependent Claim
22 words
A mixture according to claim 1, which contain as alkenylphenol or alkenylphenol ether an allylphenol or a methallylphenol or an ether thereof.
Claim 11
Dependent Claim
17 words
A mixture according to claim 1, which contain as alkenylphenol phenol or alkenylphenol ether a mononuclear compound.
Claim 12
Dependent Claim
18 words
A mixture according to claim 10, which contain as alkenylphenol or alkenylphenol ether eugenol or eugenol methyl ether.
Claim 13
Dependent Claim
35 words
A mixture according to claim 1, which contain as alkenylphenol or alkenylphenol ether a mononuclear, preferably binuclear, compound containing at least on one nucleus both an alkenyl group and a phenolic, optionally etherified, OH group.
Claim 14
Dependent Claim
25 words
A mixture according to claim 12, which contain as alkenylphenol a bivalent compound of the formula V ##STR20## wherein R 1 has the above meaning.
Claim 15
Dependent Claim
11 words
A mixture according to claim 13, which contain as alkenylphenol o,o'-diallylbisphenol-A.
Claim 16
Dependent Claim
17 words
A mixture according to claim 1, which additionally contain phenols and/or phenol ethers having no alkenyl groups.
Claim 17
Dependent Claim
16 words
A mixture according to claim 1, which contain as curing accelerator for epoxide resin mixtures 2-phenylimidazole.
Claim 18
Dependent Claim
47 words
Process for producing cross-linked polymers containing imide groups, which process comprises bringing to reaction and 9 curing mixture according to claim 1 at temperatures of 50 to 250° C., preferably at 100° to 250° C., whereby an initial part of the reaction can be performed in solution.
References Cited (Backward Citations)
US3429947A
Cited
US3730948A
Cited
US3880811A
Cited
US3839493A
Cited
US3883486A
Cited
US4005154A
Cited
US3875113A
Cited
US3962182A
Cited
JPS5078697A
Cited
US3920768A
Cited
US3978152A
Cited
US3985928A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-11-27 | 1982-05-29 | 1982-11-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-11-27 | 1986-05-29 | 1986-11-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-11-27 | 1990-05-29 | 1990-11-28 | $7700.00 | Window Closed / Lapsed |