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US4127615A Expired / Lapsed US ⏱️ 0.0 years remaining

Epoxide resin mixtures

Assignee: BASF Corp
•
Filing: 1977-06-06
•
Granted: 1978-11-28
•
Expires: 1997-06-06
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Abstract

Abstract The invention relates to storage-stable, thermosetting mixtures which contain polymaleimides, alkenylphenols and/or alkenylphenol ethers, epoxide compounds with or without allyl groups, and, optionally, curing accelerators for epoxide resins. These mixtures can be converted by curing into high-polymers which have excellent electrical properties (especially at high temperatures) and very good thermal properties.

Inventors

  • 👤 Abdul-Cader Zahir
  • 👤 Alfred Renner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 16:15
CPC Classifications
C; C08; C08L; C08L79/00; C08L79/04; C08L79/08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/24; C08G59/245; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08G59/62; C08G59/621; C08L63/00

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 225 words
A storage-stable, thermosetting mixture which comprises: (a) a polyimide containing in the molecule at least two radicals of the general formula ##STR11## wherein D represents a bivalent radical containing a carbon-carbon double bond; (b) 0.1 to 10 moles of an akenylphenol, an alkenylphenol ether or mixtures thereof per equivalent of said polyimide; (c) 0.1 to 10 moles per equivalent of said polyimides of an epoxide compound of a mixture of several epoxide compounds selected from the group consisting of: (α) glycidyl ethers of the formula ##STR12## wherein R 3 represents an allyl group or H atom, (β) glycidyl ethers of novolaks (X') which contain two or more epoxy groups of said glycidyl ethers additionally substituted on the aromatic nuclei with one or more allyl groups, (α) polyepoxy adducts (Y'), having two or more epoxy groups per molecule, produced by an advancement reaction of one or more diepoxide compounds with one or more bisphenols or said diepoxide compounds or bisphenols additionally substituted on the aromatic nuclei with one or more allyl groups, (δ) epoxide compounds (Z') produced by the reaction of one or more phenols or said phenols, additionally substituted on the aromatic nuclei with one or more allyl groups, with epichlorohydrin in an alkaline solution, and (d) up to 5 percent by weight, relative to the epoxide resin, of a curing accelerator for epoxide resins.
Claim 2
Dependent Claim 225 words
A storage-stable, thermosetting mixture which comprises: (a) a polyimide containing in the molecule at least two radicals of the general formula ##STR11## wherein D represents a bivalent radical containing a carbon-carbon double bond; (b) 0.1 to 10 moles of an akenylphenol, an alkenylphenol ether or mixtures thereof per equivalent of said polyimide; (c) 0.1 to 10 moles per equivalent of said polyimides of an epoxide compound of a mixture of several epoxide compounds selected from the group consisting of: (α) glycidyl ethers of the formula ##STR12## wherein R 3 represents an allyl group or H atom, (β) glycidyl ethers of novolaks (X') which contain two or more epoxy groups of said glycidyl ethers additionally substituted on the aromatic nuclei with one or more allyl groups, (α) polyepoxy adducts (Y'), having two or more epoxy groups per molecule, produced by an advancement reaction of one or more diepoxide compounds with one or more bisphenols or said diepoxide compounds or bisphenols additionally substituted on the aromatic nuclei with one or more allyl groups, (δ) epoxide compounds (Z') produced by the reaction of one or more phenols or said phenols, additionally substituted on the aromatic nuclei with one or more allyl groups, with epichlorohydrin in an alkaline solution, and (d) up to 5 percent by weight, relative to the epoxide resin, of a curing accelerator for epoxide resins.
Claim 3
Dependent Claim 61 words
A mixture according to claim 1, which contain as polyepoxy adducts (Y') such products which have been produced by an advancement reaction of a diglycidyl ether of the formula ##STR13## wherein R 2 represents one of the radicals --CH 2 -- and ##STR14## and R 3 has the aforegiven meaning, with one or more of the bisphenols of the formulae ##STR15##
Claim 4
Dependent Claim 32 words
A mixture according to claim 1, which contain polyimides having radicals of the formula (I) in which D represents a bivalent radical of the formula ##STR16## wherein R represents hydrogen or methyl.
Claim 5
Dependent Claim 23 words
A mixture according to claim 1, which contain polyimides having the radical of the formula (I) two or three times in the molecule.
Claim 6
Dependent Claim 30 words
A mixture according to claim 3, which contain as polyimide a compound of the general formula ##STR17## wherein L represents a bivalent organic radical having 2 to 30 C atoms.
Claim 7
Dependent Claim 45 words
A mixture according to claim 5, which contain as polyimide a compound of the formula (VII) wherein L represents a radical of the formula ##STR18## in which R 1 represents one of the radicals --CH 2 --, ##STR19## --SO 2 --, --SO--, --S-- and --O--.
Claim 8
Dependent Claim 11 words
A mixture according to claim 6, which contain as polyimide 4,4'-bis-maleimidodiphenylmethane.
Claim 9
Dependent Claim 19 words
A mixture according to claim 1, which additionally contain monoimides containing the radical of the formula I, preferably monomaleimides.
Claim 10
Dependent Claim 22 words
A mixture according to claim 1, which contain as alkenylphenol or alkenylphenol ether an allylphenol or a methallylphenol or an ether thereof.
Claim 11
Dependent Claim 17 words
A mixture according to claim 1, which contain as alkenylphenol phenol or alkenylphenol ether a mononuclear compound.
Claim 12
Dependent Claim 18 words
A mixture according to claim 10, which contain as alkenylphenol or alkenylphenol ether eugenol or eugenol methyl ether.
Claim 13
Dependent Claim 35 words
A mixture according to claim 1, which contain as alkenylphenol or alkenylphenol ether a mononuclear, preferably binuclear, compound containing at least on one nucleus both an alkenyl group and a phenolic, optionally etherified, OH group.
Claim 14
Dependent Claim 25 words
A mixture according to claim 12, which contain as alkenylphenol a bivalent compound of the formula V ##STR20## wherein R 1 has the above meaning.
Claim 15
Dependent Claim 11 words
A mixture according to claim 13, which contain as alkenylphenol o,o'-diallylbisphenol-A.
Claim 16
Dependent Claim 17 words
A mixture according to claim 1, which additionally contain phenols and/or phenol ethers having no alkenyl groups.
Claim 17
Dependent Claim 16 words
A mixture according to claim 1, which contain as curing accelerator for epoxide resin mixtures 2-phenylimidazole.
Claim 18
Dependent Claim 47 words
Process for producing cross-linked polymers containing imide groups, which process comprises bringing to reaction and 9 curing mixture according to claim 1 at temperatures of 50 to 250° C., preferably at 100° to 250° C., whereby an initial part of the reaction can be performed in solution.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-11-27 1982-05-29 1982-11-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-11-27 1986-05-29 1986-11-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-11-27 1990-05-29 1990-11-28 $7700.00 Window Closed / Lapsed

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