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US4233344A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of improving the adhesion of electroless metal deposits employing colloidal copper activator

Assignee: Shipley Co Inc
•
Filing: 1978-07-20
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Granted: 1980-11-11
•
Expires: 1998-07-20
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Abstract

Abstract The present invention relates to a method for promoting and improving the adhesion of an electroless metal deposit to the metal surface of a composite substrate having both a conductive metal area and an activated non-conductive surface. The process comprises treating such a substrate, subsequent to catalyzation or activation of the substrate, and prior to electroless metal deposition thereon, with an adhesion promotor compound or mixture of compounds.

Inventors

  • 👤 William Brasch

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 16:48
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C23C18/28

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 77 words
A method for promoting and improving the adhesion of an electroless metal deposit to the metal portion and a non-conductive portion which comprises treating the composite substrate with a copper type colloidal system to cause activation of the non-conductive portion thereof for electroless metal deposition, and thereafter treating the activated substrate, including the metal portions thereof, with an adhesion promoter compound selected from hydrazine hydrate, ammonium persulfate, or alkali hydroxide prior to the step of electroless deposition.
Claim 2
Independent Claim 77 words
A method for promoting and improving the adhesion of an electroless metal deposit to the metal portion and a non-conductive portion which comprises treating the composite substrate with a copper type colloidal system to cause activation of the non-conductive portion thereof for electroless metal deposition, and thereafter treating the activated substrate, including the metal portions thereof, with an adhesion promoter compound selected from hydrazine hydrate, ammonium persulfate, or alkali hydroxide prior to the step of electroless deposition.
Claim 3
Dependent Claim 55 words
The method of claim 1 wherein the adhesion promoter is in solution and the concentration of the hydrazine hydrate is about 0.1% by volume to saturation, the concentration of the ammonium persulfate is about 0.5-10 gms per liter of solution and the concentration of the alkali hydroxide is about 0.1-5 grams per liter of solution.
Claim 4
Dependent Claim 49 words
The method of claim 2 wherein the substrate is treated with hydrazine hydrate for a period of time of about 1-3 minutes, with ammonium persulfate for a period of time not exceeding about 15 seconds and with sodium hydroxide for a period of time not exceeding about 30 seconds.
Claim 5
Dependent Claim 16 words
The method of claim 1 wherein the hydrazine hydrate is at a pH of about 7.
Claim 6
Dependent Claim 17 words
The method of claim 1 wherein the substrate is subsequently electroless plated with an electroless copper solution.

References Cited (Backward Citations)

US3962494A Cited
DE2335497A1 Cited
US3884704A Cited
US4002778A Cited
US4020197A Cited
US3993799A Cited
US3982045A Cited
US3962496A Cited
US4042730A Cited
US4096043A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-11 1984-05-12 1984-11-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-11 1988-05-12 1988-11-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-11 1992-05-12 1992-11-11 $7700.00 Window Closed / Lapsed

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