US6602303B2 — Composition for the oxidation dyeing of keratinou…

Claim 1

Independent Claim 80 words

A composition for oxidation dyeing of keratinous fibers comprising, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent having a molecular weight of less than 250, wherein the weight ratio of (I) to (II) is greater than 1:1.

Claim 2

Dependent Claim 80 words

A composition for oxidation dyeing of keratinous fibers comprising, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent having a molecular weight of less than 250, wherein the weight ratio of (I) to (II) is greater than 1:1.

Claim 3

Dependent Claim 64 words

A composition according to claim 1 , wherein said oxyalkylenated fatty alcohols are chosen from formula (IAA): wherein: R is chosen from optionally saturated, linear and branched groups containing from 8 to 40 carbon atoms, Z is chosen from oxyethylenated groups and oxypropylenated groups of formulae (i), (ii) 1 , and (ii) 2 : and m is a number ranging from 1 to 250.

Claim 4

Dependent Claim 17 words

A composition according to claim 2 , wherein m is a number ranging from 2 to 100.

Claim 5

Dependent Claim 37 words

A composition according to claim 1 , wherein said oxyalkylenated fatty alcohols are chosen from optionally saturated, linear and branched fatty alcohols containing from 10 to 20 carbon atoms and from 2 to 40 ethylene oxide groups.

Claim 6

Dependent Claim 54 words

A composition according to claim 1 , wherein said glycerolated fatty alcohols are chosen from formula (IBB): wherein: R is chosen from optionally saturated, linear and branched groups containing from 8 to 40 carbon atoms, Z is chosen from glycerolated groups of formula (iii): and n is a number ranging from 1 to 30.

Claim 7

Dependent Claim 17 words

A composition according to claim 5 , wherein n is a number ranging from 1 to 10.

Claim 8

Dependent Claim 42 words

A composition according to claim 1 , wherein said at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols is present in an amount ranging from 0.05% to 50% by weight relative to the total weight of the composition.

Claim 9

Dependent Claim 42 words

A composition according to claim 7 , wherein said at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols is present in an amount ranging from 2% to 40% by weight relative to the total weight of the composition.

Claim 10

Dependent Claim 21 words

A composition according to claim 1 , wherein said at least one hydroxylated solvent comprises from 2 to 12 carbon atoms.

Claim 11

Dependent Claim 21 words

A composition according to claim 9 , wherein said at least one hydroxylated solvent comprises from 2 to 8 carbon atoms.

Claim 12

Dependent Claim 21 words

A composition according to claim 10 , wherein said at least one hydroxylated solvent comprises from 2 to 3 carbon atoms.

Claim 13

Dependent Claim 31 words

A composition according to claim 1 , wherein said at least one hydroxylated solvent is chosen from ethyl alcohol, propyl alcohol, n-butyl alcohol, polyol ethers and (C 2 -C 6 )polyols.

Claim 14

Dependent Claim 24 words

A composition according to claim 12 , wherein said (C 2 -C 6 )polyols are chosen from 2-methyl-1,3-butanediol, 2,2-dimethyl-1,3-propanediol, 2-methyl-1,3-propanediol, 2-methyl-2,4-pentanediol, 1,5-pentanediol, and 3-methyl-1,5-pentanediol.

Claim 15

Dependent Claim 24 words

A composition according to claim 12 , wherein said (C 2 -C 6 )polyols are chosen from glycerol, propylene glycol, dipropylene glycol and 1,3-propanediol.

Claim 16

Dependent Claim 26 words

A composition according to claim 12 , wherein said at least one hydroxylated solvent is chosen from polyol ethers comprising at least one free hydroxyl function.

Claim 17

Dependent Claim 25 words

A composition according to claim 15 , wherein said polyol ethers are chosen from (C 1 -C 8 )ethers of (C 2 -C 9 )glycols.

Claim 18

Dependent Claim 67 words

A composition according to claim 16 , wherein said polyol ethers are chosen from ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monobenzyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, propylene glycol monophenyl ether, propylene glycol monobenzyl ether, diethylene glycol monophenyl ether, and diethylene glycol monobenzyl ether.

Claim 19

Dependent Claim 37 words

A composition according to claim 1 , wherein said at least one hydroxylated solvent is present in said composition in an amount ranging from 0.01% to 25% by weight relative to the total weight of the composition.

Claim 20

Dependent Claim 37 words

A composition according to claim 18 , wherein said at least one hydroxylated solvent is present in said composition in an amount ranging from 0.1% to 20% by weight relative to the total weight of the composition.

Claim 21

Dependent Claim 27 words

A composition according to claim 1 , wherein the at least one hydroxylated solvent is chosen from linear and branched compounds bearing at least one —OH function.

Claim 22

Dependent Claim 40 words

A composition according to claim 1 , wherein the weight ratio of said at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and said at least one hydroxylated solvent ranges from greater than 1:1 to 30:1.

Claim 23

Dependent Claim 38 words

A composition according to claim 21 , wherein the weight ratio of said at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and said at least one hydroxylated solvent ranges from 1.5:1 to 20:1.

Claim 24

Dependent Claim 22 words

A composition according to claim 1 , wherein said at least one oxidation dye is chosen from oxidation bases and oxidation couplers.

Claim 25

Dependent Claim 27 words

A composition according to claim 23 , wherein said oxidation bases are chosen from ortho-phenylenediamines, para-phenylenediamines, double bases, ortho-para-aminophenols, para-aminophenols, heterocyclic bases, and their acid addition salts.

Claim 26

Dependent Claim 229 words

A composition according to claim 24 , wherein said para-phenylenediamines are chosen from compounds of formula (I), and their acid addition salts: wherein: R 1 is chosen from hydrogen, C 1 -C 4 alkyl groups, monohydroxy(C 1 -C 4 alkyl) groups, polyhydroxy(C 2 -C 4 alkyl) groups, (C 1 -C 4 )alkoxy(C 1 -C 4 )alkyl groups, phenyl groups, 4′-aminophenyl groups, and C 1 -C 4 alkyl groups substituted with at least one group chosen from nitrogen-containing groups, R 2 is chosen from hydrogen, C 1 -C 4 alkyl groups, monohydroxy(C 1 -C 4 alkyl) groups, polyhydroxy(C 2 -C 4 alkyl) groups, (C 1 -C 4 )alkoxy(C 1 -C 4 )alkyl groups, and C 1 -C 4 alkyl groups substituted with a substituent chosen from nitrogen-containing groups; R 1 and R 2 may also form, together with the nitrogen to which they are bonded, a 5- or 6-membered nitrogen-containing heterocycle ring, optionally substituted with at least one group chosen from alkyl groups, hydroxyl groups and ureido groups; R 3 is chosen from hydrogen, halogens, C 1 -C 4 alkyl groups, sulfo groups, carboxyl groups, monohydroxy(C 1 -C 4 alkyl) groups, hydroxy(C 1 -C 4 alkyoxy) groups, acetylamino(C 1 -C 4 alkoxy) groups, mesylamino(C 1 -C 4 alkoxy) groups, and carbamoylamino(C 1 -C 4 alkoxy) groups; R 4 is chosen from hydrogen, halogens, and C 1 -C 4 alkyl groups.

Claim 27

Dependent Claim 44 words

A composition according to claim 24 , wherein said para-phenylenediamines are chosen from para-phenylenediamine, para-toluylenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,5-dimethyl-para-phenylenediamine, N,N-dimethyl-para-phenylenediamine, N,N-diethyl-para-phenylenediamine, N,N-dipropyl-para-phenylenediamine, 4-amino-N,N-diethyl-3-methylaniline, N,N-bis(β-hydroxyethyl)-para-phenylenediamine, 4-amino-N,N-bis(β-hydroxyethyl)-3-methylaniline, 4-amino-3-chloro-N,N-bis(β-hydroxyethyl)aniline, 2-β-hydroxyethyl-para-phenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N-(β-hydroxypropyl)-para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N,N-dimethyl-3-methyl-para-phenylenediamine, N,N-(ethyl-β-hydroxyethyl)-para-phenylenediamine, N-(β,γ-dihydroxypropyl)-para-phenylenediamine, N-(4′-aminophenyl)-para-phenylenediamine, N-phenyl-para-phenylenediamine and 2-β-hydroxyethyloxy-para-phenylenediamine, and their acid addition salts.

Claim 28

Dependent Claim 40 words

A composition according to claim 25 , wherein said nitrogen-containing groups are chosen from amino, mono(C 1 -C 4 )alkylamino, di(C 1 -C 4 )alkylamino, tri(C 1 -C 4 )alkylamino, monohydroxy(C 1 -C 4 )alkylamino, imidazolinium groups and ammonium groups.

Claim 29

Dependent Claim 214 words

A composition according to claim 24 , wherein said double bases are chosen from the compounds of formula (II) and their acid addition salts: wherein: Z 1 and Z 2 , which may be identical or different, are each chosen from hydroxyl groups, and —NH 2 groups, optionally substituted with a group chosen from C 1 -C 4 alkyl groups, and linkers Y linker Y is chosen from linear and branched, divalent alkylene groups comprising from 1 to 14 carbon atoms, optionally interrupted by, or optionally terminating with, at least one entity chosen from nitrogen-containing groups and heteroatoms, and optionally substituted with at least one group chosen from hydroxyl groups, and C 1 -C 6 alkoxy groups; R 5 and R 6 , which may be identical or different, are each chosen from hydrogen, halogens, C 1 -C 4 alkyl groups, monohydroxy(C 1 -C 4 alkyl) groups, polyhydroxy(C 2 -C 4 alkyl) groups, amino(C 1 -C 4 alkyl) groups, and linkers Y; R 7 , R 8 , R 9 , R 10 , R 11 and R 12 , which may be identical or different, are each chosen from hydrogen, linkers Y, and C 1 -C 4 alkyl groups; provided that said compounds of formula (II) comprise only one linker Y per molecule.

Claim 30

Dependent Claim 40 words

A composition according to claim 28 , wherein said nitrogen-containing groups are chosen from amino, mono(C 1 -C 4 )alkylamino, di(C 1 -C 4 )alkylamino, tri(C 1 -C 4 )alkylamino, monohydroxy(C 1 -C 4 )alkylamino, imidazolinium groups and ammonium groups.

Claim 31

Dependent Claim 26 words

A composition according to claim 24 , wherein said double bases are chosen from N,N′-bis(β-hydroxyethyl)-N,N′-bis(4′-aminophenyl)-1,3-diaminopropanol, N,N′-bis(β-hydroxyethyl)-N,N′-bis(4′-aminophenyl)ethylenediamine, N,N′-bis(4-aminophenyl)tetramethylenediamine, N,N′-bis(β-hydroxyethyl)-N,N′-bis(4-aminophenyl)tetramethylenediamine, N,N′-bis(4-methylaminophenyl)tetramethylenediamine, N,N′-bis(ethyl)-N,N′-bis(4′-amino-3′-methylphenyl)ethylenediamine, 1,8-bis(2,5-diaminophenoxy)-3,5-dioxaoctane, and their acid addition salts.

Claim 32

Dependent Claim 116 words

A composition according to claim 24 , wherein said para-aminophenols are chosen from compounds of formula (III), and their acid addition salts: wherein: R 13 is chosen from hydrogen, halogens, C 1 -C 4 alkyl groups, monohydroxy(C 1 -C 4 alkyl) groups, (C 1 -C 4 )alkoxy(C 1 -C 4 )alkyl groups, amino(C 1 -C 4 alkyl), and hydroxy(C 1 -C 4 )alkylamino(C 1 -C 4 alkyl) groups; R 14 is chosen from hydrogen, halogens, C 1 -C 4 alkyl groups, monohydroxy(C 1 -C 4 alkyl) groups, polyhydroxy(C 2 -C 4 alkyl) groups, amino(C 1 -C 4 alkyl) groups, cyano(C 1 -C 4 alkyl) groups, and (C 1 -C 4 )alkoxy(C 1 -C 4 )alkyl groups.

Claim 33

Dependent Claim 27 words

A composition according to claim 24 , wherein said para-aminophenols are chosen from para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2-(-hydroxyethylaminomethyl)phenol, and their acid addition salts.

Claim 34

Dependent Claim 21 words

A composition according to claim 24 , wherein said heterocyclic bases are chosen from pyridine derivatives, pyrimidine derivatives, and pyrazole derivatives.

Claim 35

Dependent Claim 23 words

A composition according to claim 24 , wherein said ortho-aminophenols are chosen from from 2-aminophenol, 2-amino-1-hydroxy-5-methylbenzene, 2-amino-6-methylbenzene, 5-acetamido-2-aminophenol, and their acid addition salts.

Claim 36

Dependent Claim 31 words

A composition according to claim 24 , wherein said oxidation bases are present in an amount ranging from 0.0005% to 12% by weight relative to the total weight of the composition.

Claim 37

Dependent Claim 31 words

A composition according to claim 35 , wherein said oxidation bases are present in an amount ranging from 0.005% to 8% by weight relative to the total weight of the composition.

Claim 38

Dependent Claim 29 words

A composition according to claim 23 , wherein said oxidation couplers are chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthols, sesamol and its derivatives, heterocyclic couplers, and their acid addition salts.

Claim 39

Dependent Claim 30 words

A composition according to claim 23 , wherein said oxidation couplers are present in amounts ranging from 0.0001% to 10% by weight relative to the total weight of the composition.

Claim 40

Dependent Claim 30 words

A composition according to claim 38 , wherein said oxidation couplers are present in amounts ranging from 0.005% to 5% by weight relative to the total weight of the composition.

Claim 41

Dependent Claim 22 words

A composition according to claim 24 , wherein said acid addition salts are chosen from hydrochlorides, hydrobromides, sulfates, tartrates, lactates and acetates.

Claim 42

Dependent Claim 144 words

A composition according to claim 1 , wherein said at least one cationic amphiphilic polymer comprising at least one fatty chain is chosen from: (i) quaternized celluloses modified with at least one group comprising at least one fatty chain, wherein said at least one group is chosen from alkyl groups, arylalkyl groups, and alkylaryl groups and contains at least 8 carbon atoms; (ii) quaternized hydroxyethylcelluloses modified with at least one group comprising at least one fatty chain, wherein said at least one group is chosen from alkyl groups, arylalkyl groups, and alkylaryl groups and contains at least 8 carbon atoms; (iii) cationic amphiphilic polyurethanes with at least one hydrophobic group comprising from 10 to 30 carbon atoms, (iv) cationic amphiphilic polyvinyllactams, and (v) an acrylic terpolymer formed from (C 10 -C 30 )alkyl acrylates, amino(meth)acrylates and itaconate polyoxyethylenated with 20 mol of ethylene oxide.

Claim 43

Dependent Claim 25 words

A composition according to claim 41 , wherein the alkyl groups of said quaternized celluloses and quaternized hydroxyethylcelluloses comprise from 8 to 30 carbon atoms.

Claim 44

Dependent Claim 27 words

A composition according to claim 41 , wherein the alkyl groups of said quaternized hydroxyethylcelluloses are chosen from C 12 alkyl groups and C 18 alkyl groups.

Claim 45

Dependent Claim 180 words

A composition according to claim 1 , wherein said at least one cationic amphiphilic polyurethane is chosen from polymers of formula (Ia): R—X—(P) n —[L—(Y) m ] r —L′—(P′) p —X′—R′ (Ia) wherein: R and R′, which may be identical or different, are each chosen from hydrophobic groups and hydrogen atoms; X and X′, which may be identical or different, represent a group comprising an amine function optionally comprising a hydrophobic group, and a group L″; L, L″, and L′ which may be identical or different, are each chosen from derivatives of diisocyanates; P and P′, which may be identical or different, are each chosen from groups comprising an amine function optionally bearing at least one hydrophobic group; Y is chosen from hydrophilic groups; r is an integer from 1 to 100; n, m and p which may be identical or different, are chosen from numbers ranging from 0 to 1000; provided that said cationic amphiphilic polyurethanes comprise at least one group chosen from protonated amine functions, and quaternized amine functions, and at least one group chosen from hydrophobic groups.

Claim 46

Dependent Claim 41 words

A composition according to claim 1 , wherein said at least one cationic amphiphilic polymer comprising at least one fatty chain is present in an amount ranging from 0.01% to 3% by weight relative to the total weight of the composition.

Claim 47

Dependent Claim 41 words

A composition according to claim 45 , wherein said at least one cationic amphiphilic polymer comprising at least one fatty chain is present in an amount ranging from 0.02% to 0.5% by weight relative to the total weight of the composition.

Claim 48

Dependent Claim 14 words

A composition according to claim 1 , further comprising at least one direct dye.

Claim 49

Dependent Claim 34 words

A composition according to claim 47 , wherein said at least one direct dye is present in an amount ranging from 0.001% to 20% by weight relative to the total weight of the composition.

Claim 50

Dependent Claim 19 words

A composition according to claim 1 , further comprising at least one agent chosen from reducing agents and antioxidants.

Claim 51

Dependent Claim 39 words

A composition according to claim 49 , wherein said at least one agent is present in the composition of the invention in an amount ranging from 0.05% to 3% by weight relative to the total weight of the composition.

Claim 52

Dependent Claim 95 words

A composition according to claim 1 , further comprising at least one adjuvant chosen from sequestering agents, UV screening agents, waxes, volatile and non-volatile, cyclic, linear and branched silicones, optionally organomodified with amine groups, nonionic polymers, anionic polymers, cationic surfactants, anionic surfactants, and amphoteric surfactants, nonionic surfactants other than said oxyalkylenated fatty alcohols and said glycerolated fatty alcohols, amphiphilic polymers containing a fatty chain other than said at least one cationic amphiphilic polymers with a fatty chain, thickeners containing sugar units, preserving agents, ceramides, pseudoceramides, plant oils, mineral oils, synthetic oils, vitamins, provitamins, and opacifiers.

Claim 53

Dependent Claim 89 words

A ready-to-use composition for the oxidation dyeing of keratinous fibers comprising, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent having a molecular weight of less than 250, wherein the weight ratio of (I) to (II) is greater than 1:1; and (d) at least one oxidizing agent.

Claim 54

Dependent Claim 89 words

A ready-to-use composition for the oxidation dyeing of keratinous fibers comprising, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent having a molecular weight of less than 250, wherein the weight ratio of (I) to (II) is greater than 1:1; and (d) at least one oxidizing agent.

Claim 55

Dependent Claim 47 words

A ready-to-use composition according to claim 52 , wherein said at least one oxidizing agent is chosen from hydrogen peroxide, urea peroxide, alkali metal bromates, alkali metal ferricyanides, persalts, and oxidation-reduction enzymes, wherein said oxidation-reduction enzymes may be in the presence of their corresponding donor or cofactor.

Claim 56

Dependent Claim 18 words

A ready-to-use composition according to claim 53 , wherein said at least one oxidizing agent is hydrogen peroxide.

Claim 57

Dependent Claim 30 words

A ready-to-use composition according to claim 54 , wherein said at least one oxidizing agent is an aqueous hydrogen peroxide solution with a titre ranging from 1 to 40 volumes.

Claim 58

Dependent Claim 18 words

A composition according to claim 1 , wherein said composition has a pH ranging from 4 to 12.

Claim 59

Dependent Claim 19 words

A ready-to-use composition according to claim 52 , wherein said composition has a pH ranging from 4 to 12.

Claim 60

Dependent Claim 36 words

A ready-to-use composition according to claim 52 , further comprising at least one polymer chosen from amphoteric polymers and cationic polymers other than said at least one cationic amphiphilic polymer comprising at least one fatty chain.

Claim 61

Dependent Claim 24 words

A ready-to-use composition according to claim 58 , wherein said cationic polymers are chosen from poly(quaternary ammonium) polymers comprising repeating units of formula (W):

Claim 62

Dependent Claim 24 words

A ready-to-use composition according to claim 58 , wherein said cationic polymers are chosen from poly(quaternary ammonium) polymers comprising repeating units of formula (U):

Claim 63

Dependent Claim 25 words

A ready-to-use composition according to claim 58 , wherein said amphoteric polymers are copolymers comprising at least one acrylic acid monomer and a dimethyldiallylammonium salt.

Claim 64

Dependent Claim 34 words

A ready-to-use composition according to claim 58 , wherein said at least one polymer is present in an amount ranging from 0.01% to 10% by weight relative to the total weight of the composition.

Claim 65

Dependent Claim 34 words

A ready-to-use composition according to claim 62 , wherein said at least one polymer is present in an amount ranging from 0.05% to 5% by weight relative to the total weight of the composition.

Claim 66

Dependent Claim 34 words

A ready-to-use composition according to claim 63 , wherein said at least one polymer is present in an amount ranging from 0.1% to 3% by weight relative to the total weight of the composition.

Claim 67

Dependent Claim 169 words

A process for dyeing keratinous fibers comprising: (1) storing a composition (A) comprising, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent having a molecular weight of less than 250, wherein the weight ratio of (I) to (II) is greater than 1:1; (2) storing, separately from said composition (A), a composition (B) comprising, in a medium suitable for dyeing, at least one oxidizing agent; (3) applying said composition (A) and said composition (B) to keratinous fibers, and (4) developing a color on keratinous fibers; wherein said composition (A) is combined at the time of use with said composition (B) and applied to the keratinous fibers, or wherein said composition (A) and said composition (B) are applied sequentially to said at least one dyeing composition without intermediate rinsing.

Claim 68

Dependent Claim 169 words

A process for dyeing keratinous fibers comprising: (1) storing a composition (A) comprising, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent having a molecular weight of less than 250, wherein the weight ratio of (I) to (II) is greater than 1:1; (2) storing, separately from said composition (A), a composition (B) comprising, in a medium suitable for dyeing, at least one oxidizing agent; (3) applying said composition (A) and said composition (B) to keratinous fibers, and (4) developing a color on keratinous fibers; wherein said composition (A) is combined at the time of use with said composition (B) and applied to the keratinous fibers, or wherein said composition (A) and said composition (B) are applied sequentially to said at least one dyeing composition without intermediate rinsing.

Claim 69

Independent Claim 110 words

A device or kit for the oxidation dyeing of keratinous fibers, comprising at least two compartments, wherein: (1) a first compartment comprises, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent having a molecular weight of less than 250, wherein the weight ratio of (I) to (II) is greater than 1:1; and (2) a second compartment comprising, in a medium suitable for dyeing, at least one oxidizing agent.

Claim 70

Independent Claim 110 words

A device or kit for the oxidation dyeing of keratinous fibers, comprising at least two compartments, wherein: (1) a first compartment comprises, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent having a molecular weight of less than 250, wherein the weight ratio of (I) to (II) is greater than 1:1; and (2) a second compartment comprising, in a medium suitable for dyeing, at least one oxidizing agent.

Claim 71

Dependent Claim 72 words

A composition for oxidation dyeing of keratinous fibers comprising, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent, wherein the weight ratio of (I) to (II) is greater than 1:1.

Claim 72

Dependent Claim 72 words

A composition for oxidation dyeing of keratinous fibers comprising, in a medium suitable for dyeing: (a) at least one oxidation dye, (b) at least one cationic amphiphilic polymer comprising at least one fatty chain, and (c) a combination comprising: (I) at least one compound chosen from oxyalkylenated fatty alcohols and glycerolated fatty alcohols, and (II) at least one hydroxylated solvent, wherein the weight ratio of (I) to (II) is greater than 1:1.

Claim 73

Dependent Claim 45 words

A composition according to claim 1 , wherein said oxyalkylenated fatty alcohols are chosen from linear and branched, saturated and unsaturated oxyalkylenated fatty alcohols comprising from 8 to 40 carbon atoms and from 1 to 250 groups chosen from ethylene oxide and propylene oxide groups.

Claim 74

Dependent Claim 24 words

A composition according to claim 2 wherein R is chosen from optionally saturated, linear and branched groups containing from 8 to 30 carbon atoms.

Claim 75

Dependent Claim 24 words

A composition according to claim 5 wherein R is chosen from optionally saturated, linear and branched groups containing from 8 to 30 carbon atoms.

Claim 76

Dependent Claim 38 words

A composition according to claim 1 , wherein said glycerolated fatty alcohols are chosen from linear and branched, saturated and unsaturated glycerolated fatty alcohols comprising from 8 to 40 carbon atoms and from 1 to 30 glycerol groups.

Claim 77

Dependent Claim 25 words

A composition according to claim 1 , wherein said at least one oxidation dye comprises at least one oxidation base and at least one coupler.

Claim 78

Dependent Claim 30 words

A composition according to claim 72 , wherein said at least one oxidation base is chosen from ortho-phenylenediamines, para-phenylenediamines, double bases, ortho-para-aminophenols, para-aminophenols, heterocyclic bases, and their acid addition salts.

Claim 79

Dependent Claim 22 words

A composition according to claim 25 wherein for R 3 and R 4 , said halogens are chosen from chlorine and fluorine.

Claim 80

Dependent Claim 20 words

A composition according to claim 28 , wherein for linker Y, said heteroatoms are chosen from oxygen, sulfur, and nitrogen.

Claim 81

Dependent Claim 21 words

A composition according to claim 31 , wherein for R 13 and R 14 , said halogens are chosen from fluorine.

Claim 82

Dependent Claim 20 words

A composition according to claim 37 , wherein said naphthols are chosen from monohydroxylated naphthalene derivatives and polyhydroxylated naphthalene derivatives.

Claim 83

Dependent Claim 16 words

A composition according to claim 44 , wherein r is an integer from 1 to 50.

Claim 84

Dependent Claim 16 words

A composition according to claim 44 , wherein r is an integer from 1 to 25.

Claim 85

Dependent Claim 13 words

A process according to claim 65 , wherein said keratinous fibers are hair.

Claim 86

Dependent Claim 13 words

A process according to claim 80 , wherein said hair is human hair.

Claim 87

Dependent Claim 158 words

A composition according to claim 1 , wherein said at least one cationic amphiphilic polymer comprising at least one fatty chain is chosen from the cationic amphiphilic polyurethanes of formula (Ia): R—X—(P) n —[L—(Y) m ] r —L′—(P′) p —X′—R′ (Ia) wherein: R and R′ which may be identical or different, are each chosen from hydrophobic groups, X and X′ which may be identical or different, are each chosen from a group L″; n and p which may be identical or different, are each chosen from numbers ranging from 1 to 1000; L, L″, and L′ which may be identical or different, are each chosen from derivatives of diisocyanates; P and P′, which may be identical or different, are each chosen from groups comprising an amine function optionally comprising at least one hydrophobic group; Y is chosen from hydrophilic groups; r is an integer from 1 to 100; and m is a number ranging from 0 to 1000.

Claim 88

Dependent Claim 147 words

A composition according to claim 1 , wherein said at least one cationic amphiphilic polymer comprising at least one fatty chain is chosen from the cationic amphiphilic polyurethanes of formula (Ia): R—X—(P) n —[L—(Y) m ] r —L′—(P′) p —X′—R′ (Ia) wherein: R and R′ which may be identical or different, are each chosen from hydrophobic groups, X and X′ which may be identical or different, are each chosen from a group L″, n and p are each equal to zero; L, L″, and L′ which may be identical or different, are each chosen from derivatives of diisocyanates; P and P′, which may be identical or different, are each chosen from groups comprising an amine function optionally bearing at least one hydrophobic group; Y is chosen from hydrophilic groups; r is an integer from 1 to 100; and m is a number ranging from 0 to 1000.

Claim 89

Dependent Claim 149 words

A composition according to claim 1 , wherein said at least one cationic amphilic polymer comprising at least one fatty chain is chosen from the cationic amphiphilic polyurethanes of formula (Ia): R—X—(P) n —[L—(Y) m ] r —L′—(P′) p —X′—R′ (Ia) wherein: R and R′ which may be identical or different, are each chosen from hydrophobic groups, X and X′ which may be identical or different, are each chosen from groups comprising a quaternary amine, n and p are each equal to 0, L, L″, and L′ which may be identical or different, are each chosen from derivatives of diisocyanates; P and P′, which may be identical or different, are each chosen from groups comprising an amine function optionally bearing at least one hydrophobic group; Y is chosen from hydrophilic groups; r is an integer from 1 to 100; and m is a number ranging from 0 to 1000.

Claim 90

Dependent Claim 22 words

A composition according to claim 44 , wherein said hydrophobic groups are chosen from hydrocarbon-based groups comprising at least 10 carbon atoms.

Claim 91

Dependent Claim 156 words

A composition according to claim 44 , wherein X and X′ are chosen from amines of following formulae: wherein: R 2 which may be identical or different, are each chosen from linear and branched, alkylene groups containing from 1 to 20 carbon atoms, wherein said linear and branched alkylene groups optionally comprise a unit chosen from saturated rings and unsaturated rings, and further wherein at least one carbon atom is optionally replaced with a hetero atom chosen from N, S, O and P; R 1 and R 3 , which may be identical or different, are each chosen from linear and branched (C 1 -C 30 )alkyl groups, linear and branched (C 1 -C 30 )alkenyl groups, and an aryl group, wherein at least one carbon atom is optionally replaced with a hetero atom chosen from N, S, O and P; and A− which may be identical or different, are each chosen from physiologically acceptable counterions.

Claim 92

Dependent Claim 88 words

A composition according to claim 44 , wherein the groups L, L′, and L″ represent a group of formula: wherein: Z is a group chosen from —O—, —S—, and —NH—; and R 4 is chosen from linear and branched, alkylene groups containing from 1 to 20 carbon atoms, wherein said linear and branched alkylene groups optionally comprise a unit chosen from saturated rings and unsaturated rings, and further wherein at least one carbon atom is optionally replaced with a hetero atom chosen from N, S, O and P.

Claim 93

Dependent Claim 204 words

A composition according to claim 44 , wherein P and P′, which may be identical or different, are each chosen from groups of the following formulae: wherein: R 5 and R 7 , which may be identical or different, are each chosen from linear and branched, alkylene groups containing from 1 to 20 carbon atoms, wherein said linear and branched alkylene groups optionally comprise a unit chosen from saturated rings and unsaturated rings, and further wherein at least one carbon atom is optionally replaced with a hetero atom chosen from N, S, O and P; R 6 , R 8 and R 9 , which may be identical or different, are each chosen from linear and branched (C 1 -C 30 )alkyl groups, linear and branched (C 1 -C 30 )alkenyl and an aryl group, wherein at least one carbon atom is optionally replaced with a hetero atom chosen from N, S, O and P; R 10 , which may be identical or different, are each chosen from optionally unsaturated, linear and branched, alkylene groups, optionally comprising at least one hetero atom chosen from N, O, S and P, and A- which may be identical or different, are each chosen from physiologically acceptable counterions.

Claim 94

Dependent Claim 357 words

A composition according to claim 1 , wherein said at least one cationic amphiphilic polymer comprising at least one fatty chain is chosen from cationic poly(vinyllactam) polymers formed from at least one monomer chosen from: a) vinyllactam monomers and alkylvinyllactam monomers; b) monomers chosen from formulae (Ib) and (IIb): wherein: X which may be identical or different, are each chosen from oxygen and NR 6 groups, R 1 and R 6 which may be identical or different, are each chosen from hydrogen and linear and branched (C 1 -C 5 )alkyl groups, R 2 which may be identical or different, are each chosen from linear and branched (C 1 -C 4 )alkyl groups, R 3 , R 4 , and R 5 which may be identical or different, are each chosen from hydrogen, linear and branched (C 1 -C 30 )alkyl groups and groups chosen from formula (IIIb): —(Y 2 ) r —(CH 2 —CH(R 7 )—O) x —R 8 (IIIb) wherein: Y, Y 1 , and Y 2 which are identical or different, are each chosen from linear and branched (C 2 -C 16 )alkylene groups, R 7 is chosen from hydrogen, linear and branched (C 1 -C 4 )alkyl groups, and linear and branched (C 1 -C 4 )hydroxyalkyl groups, R 8 is chosen from hydrogen and linear and branched (C 1 -C 30 )alkyl groups, p, q, and r which are identical or different, are each a number chosen from 0 and 1, m and n which are identical or different, are each an integer ranging from 0 to 100, x is an integer ranging from 1 to 100, Z is an anion chosen from organic acid anions and inorganic acid anions, provided that: at least one of R 3 , R 4 , R 5 , and R 8 is chosen from linear and branched (C 9 -C 30 )alkyl groups, if at least one of m and n is other than zero, then q is equal to 1, if at least one of m and n are equal to zero, then at least one of p and q is equal to 0.

Claim 95

Dependent Claim 363 words

A composition according to claim 1 , wherein said at at least one cationic amphiphilic polymer comprising at least one fatty chain is chosen from acrylic terpolymers formed from: (a) an acrylate monomer (a) chosen from (C 1 -C 6 )alkyl acrylates and (C 1 -C 6 )alkyl methacrylates, wherein said acrylate monomer (a) ranges from 5% to 80% by weight; (b) a monomer (b) chosen from heterocyclic vinyl compounds containing at least one atom chosen from nitrogen and sulfur, (meth)acrylamides, mono(C 1 -C 4 )alkylamino(C 1 -C 4 )alkyl (meth)acrylates, di(C 1 -C 4 )alkylamino(C 1 -C 4 )alkyl (meth)acrylates, mono(C 1 -C 4 )alkylamino(C 1 -C 4 )alkyl(meth)acrylamides and di(C 1 -C 4 )alkylamino(C 1 -C 4 )alkyl(meth)acrylamides, wherein said monomer (b) ranges from 5% to 80% by weight; a monomer (c) chosen from: (i) a urethane formed from a monoethylenic unsaturated isocyanate and a nonionic surfactant with a (C 1-6 )alkoxy end, (ii) a block copolymer formed from 1,2-butylene oxide and of 1,2-ethylene oxide, (iii) a copolymerizable ethylenic unsaturated surfactant monomer obtained by condensation of a nonionic surfactant with an α,β-ethylenic unsaturated carboxylic acid or its anhydride, (iv) a surfactant monomer (iv) chosen from the products formed from a monoethylenic unsaturated monoisocyanate with a nonionic surfactant containing an amine function, (v) a monomer chosen from (meth)allyl ethers of formula CH 2 ═CR 1 CH 2 OA m B n A p R 2 , wherein R 1 is chosen from a hydrogen atom and a methyl group, A is chosen from a propylenoxy group and a butylenoxy group, B is an ethylenoxy group, n is chosen from zero and integers less than or equal to 200, m and p, which are identical or different are each chosen from zero and integers less than n, and R 2 is a hydrophobic group of at least 8 carbon atoms, and (vi) a nonionic monomer of urethane type formed from a monohydric nonionic surfactant with a monoethylenic unsaturated isocyanate, wherein said monomer (c) ranges from 0.1% to 30% by weight; further wherein the weight percentages of said above defined monomers are based on the total weight of said monomers forming the acrylic terpolymer.

Claim 96

Dependent Claim 22 words

A composition according to claim 37 , wherein said acid addition salts are chosen from hydrochlorides, hydrobromides, sulfates, tartrates, lactates and acetates.

Claim 97

Dependent Claim 35 words

A composition according to claim 1 , further comprising at least one polymer chosen from amphoteric polymers and cationic polymers other than said at least one cationic amphiphilic polymer comprising at least one fatty chain.

Claim 98

Dependent Claim 23 words

A composition according to claim 92 , wherein said cationic polymers are chosen from poly(quaternary ammonium) polymers comprising repeating units of formula (W):

Claim 99

Dependent Claim 23 words

A composition according to claim 92 , wherein said cationic polymers are chosen from poly(quaternary ammonium) polymers comprising repeating units of formula (U):

Claim 100

Dependent Claim 24 words

A composition according to claim 92 , wherein said amphoteric polymers are copolymers comprising at least one acrylic acid monomer and a dimethyldiallylammonium salt.

Claim 101

Dependent Claim 33 words

A composition according to claim 92 , wherein said at least one polymer is present in an amount ranging from 0.01% to 10% by weight relative to the total weight of the composition.

Claim 102

Dependent Claim 33 words

A composition according to claim 96 , wherein said at least one polymer is present in an amount ranging from 0.05% to 5% by weight relative to the total weight of the composition.

Claim 103

Dependent Claim 33 words

A composition according to claim 97 , wherein said at least one polymer is present in an amount ranging from 0.1% to 3% by weight relative to the total weight of the composition.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	2006-08-04	2007-02-03	2007-08-05	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	2010-08-04	2011-02-03	2011-08-05	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	2014-08-04	2015-02-03	2015-08-05	$7700.00	Window Closed / Lapsed

Composition for the oxidation dyeing of keratinous fibers comprising at least one oxidation dye and at least one cationic amphiphilic polymer, and dyeing methods

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