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US5196189A Expired / Lapsed US ⏱️ 0.0 years remaining

Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin

Assignee: L'Oréal SA
•
Filing: 1992-06-12
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Granted: 1993-03-23
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Expires: 2012-06-12
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Abstract

Abstract A quaternized polymer for use as a cosmetic agent, has recurring units of the formula <IMAGE> wherein R is lower alkyl or -CH2-CH2OH; R' is an aliphatic, alicyclic or arylaliphatic radical containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen; A is a divalent group selected from o-, m- or p-xylylidene of the formula (1) <IMAGE> <IMAGE> (2) wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms, -(CH2)n -S-(CH2)n-, (3) -(CH2)n-O-(CH2)n-, (4) -(CH2)n-S-S-(CH2)n-, (5) -(CH2)n-SO-(CH2)n-, (6) -(CH2)n-SO2-(CH2)n-and (7) <IMAGE> (8) wherein n is equal to 2 or 3; B represents a divalent group selected from o-, m- or p-xylylidene of the formula (1) <IMAGE> <IMAGE> (2) wherein D and G represent hydrogen or an aliphatic radical having less than 18 carbon atoms and v, z and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, such that the sum (v+z+u) is greater than or equal to 1 and lower than 18 and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, <IMAGE> (3) (CH2)nO(CH2)n (4) - wherein n is 2 or 3; and X(-)is an anion derived from an organic or mineral acid. The quaternized polymer is employed in cosmetic compositions for the hair and skin.

Inventors

  • 👤 Bernard Jacquet
  • 👤 Gerard Lang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 03:40
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/02; C08G73/0206; C08G73/0213; C08G73/0226; A; A01; A01N; A01N33/00; A01N33/02; A01N33/12; A61; A61K; A61K8/00; A61K8/02; A61K8/04; A61K8/046; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/416; A61K8/72; A61K8/84; A61Q; A61Q15/00; A61Q5/00; A61Q5/02; A61Q5/04; A61Q5/06; A61Q5/08; A61Q5/10; C08G73/024; C08G73/0246; C08G73/0253; A61K2800/00; A61K2800/40; A61K2800/54; A61K2800/542; A61K2800/5426

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 315 words
A process for treating the skin comprising applying to the skin a cosmetic composition in an amount sufficient to impart a soft feeling to the skin and to assist in the hydration thereof, said cosmetic composition comprising in gel or emulsion form an aqueous phase and an emulsified oil phase, said aqueous phase containing in solution a quaternized polymer having recurring units of the formula ##STR74## wherein R is lower alkyl or --CH 2 --CH 2 OH; R' is alkyl, cycloalkyl or aralkyl containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen; A is a divalent group selected from ##STR75## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or alkyl having less than 18 carbon atoms, --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --, (3) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --, (4) --(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --, (5) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --, (6) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.n -- and (7) ##STR76## wherein n is equal to 2 or 3; B represents a divalent group selected from ##STR77## wherein D and G represent hydrogen or alkyl having less than 18 carbon atoms and v, z and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, such that the sum (v+z+u) is greater than or equal to 1 and lower than 18 and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, ##STR78## wherein n is 2 or 3; and X.sup.⊖ is an anion derived from an organic or mineral acid, said polymer being present in an amount between 0.25 and 10 percent by weight of said composition.
Claim 2
Dependent Claim 315 words
A process for treating the skin comprising applying to the skin a cosmetic composition in an amount sufficient to impart a soft feeling to the skin and to assist in the hydration thereof, said cosmetic composition comprising in gel or emulsion form an aqueous phase and an emulsified oil phase, said aqueous phase containing in solution a quaternized polymer having recurring units of the formula ##STR74## wherein R is lower alkyl or --CH 2 --CH 2 OH; R' is alkyl, cycloalkyl or aralkyl containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen; A is a divalent group selected from ##STR75## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or alkyl having less than 18 carbon atoms, --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --, (3) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --, (4) --(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --, (5) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --, (6) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.n -- and (7) ##STR76## wherein n is equal to 2 or 3; B represents a divalent group selected from ##STR77## wherein D and G represent hydrogen or alkyl having less than 18 carbon atoms and v, z and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, such that the sum (v+z+u) is greater than or equal to 1 and lower than 18 and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, ##STR78## wherein n is 2 or 3; and X.sup.⊖ is an anion derived from an organic or mineral acid, said polymer being present in an amount between 0.25 and 10 percent by weight of said composition.
Claim 3
Dependent Claim 45 words
The process of claim 1 wherein A is selected from ##STR79## wherein E, K, x, y and t have the meanings given in claim 1 and B is selected from ##STR80## wherein D, G, v, z and u have the meanings given in claim 1.
Claim 4
Dependent Claim 163 words
The process of claim 1 wherein R is methyl or hydroxyethyl, R' is alkyl having 1-16 carbon atoms, benzyl or cyclohexyl, or R and R' represent a polymethylene having 2-6 carbon atoms or --(CH 2 ) 2 --O--(CH 2 ) 2 ; A is xylylidene, polymethylene having 2-12 carbon atoms, polymethylene having 2-12 carbon and being branched by one or two alkyl substituents having 1-12 carbon atoms, ##STR81## --(CH 2 ) n --S--(CH 2 ) n --, --(CH 2 ) n --O--(CH 2 ) n , --(CH 2 ) n --S--S--(CH 2 ) n , --(CH 2 ) n --SO--(CH 2 ) n or --(CH 2 ) n --SO 2 --(CH 2 ) n ; B is polymethylene having 3-10 carbon atoms, polymethylene having 3-10 carbon atoms and being branched by one or two alkyl substituents having 1-12 carbon atoms, xylylidene, --CH 2 --CHOH--CH 2 -- or --(CH 2 ) n --O--(CH 2 ) n ; and x is chlorine, bromine or iodine.
Claim 5
Dependent Claim 98 words
The process of claim 1 wherein R is methyl; R' is alkyl having 1-16 carbon atoms, benzyl or cyclohexyl, or R and R' together represent --(CH 2 ) 2 --O--(CH 2 ) 2 ; A is xylylidene, polymethylene having 2-12 carbon atoms, or polymethylene having 2-12 carbon and being branched by one or two alkyl substituents having 1-12 carbon atoms, B is polymethylene having 3 to 10 carbon atoms, polymethylene having 3 to 10 carbon atoms and being branched by one or two alkyl substituents having 1-12 carbon atoms or xylylidene; and X is chlorine, bromine or iodine.
Claim 6
Dependent Claim 137 words
The process of claim 1 wherein R=R'=CH 3 , X=Br and A and B are selected from the combinations of (1) A represents ##STR82## B represents (CH 2 ) 3 ; (2) A represents (CH 2 ) 2 and B represents (CH 2 ) 4 , (CH 2 ) 6 , (CH 2 ) 10 or ##STR83## (3) A represents (CH 2 ) 6 and B represents (CH 2 ) 3 , (CH 2 ) 4 , (CH 2 ) 5 , (CH 2 ) 6 , (CH 2 ) 10 , ##STR84## o-xylylidene or p-xylylidene; (4) A represents (CH 2 ) 5 and B represents (CH 2 ) 7 or (CH 2 ) 9 ; and (5) A represents (CH 2 ) 10 and B represents (CH 2 ) 4 or (CH 2 ) 10 .
Claim 7
Dependent Claim 69 words
The process of claim 1 wherein R and R' together represent --(CH 2 ) 2 --O--(CH 2 ) 2 --, X represents Br and A and B are selected from the combinations of (1) A represents (CH 2 ) 6 or (CH 2 ) 10 and B represents (CH 2 ) 3 ; and (2) A represents (CH 2 ) 3 and B represents (CH 2 ) 6 .
Claim 8
Dependent Claim 80 words
The process of claim 1 wherein R=R'=CH 3 , X=Cl and A and B are selected from the combinations of (1) A represents (CH 2 ) 6 and B represents --CH 2 --CHOH--CH 2 -- or --(CH 2 ) 2 --o--(CH 2 ) 2 --, (2) A represents (CH 2 ) 3 and B represents --(CH 2 ) 2 --O--(CH 2 ) 2 --, and (3) A represents (CH 2 ) 3 and B represents (CH 2 ) 6 .
Claim 9
Dependent Claim 210 words
The process of claim 1 wherein R=R'=CH 3 , X=Br and A and B are selected from the combinations of (1) A represents (CH 2 ) 2 --S--S--(CH 2 ) 2 -- and B represents (CH 2 ) 3 , (CH 2 ) 4 , (CH 2 ) 5 , (CH 2 ) 6 , (CH 2 ) 10 , CH 2 --CHOH--CH 2 , (CH 2 ) 2 --O--(CH 2 ) 2 or p-xylylidene; (2) A represents (CH 2 ) 3 --O--(CH 2 ) 3 , (CH 2 ) 3 --S--S--(CH 2 ) 3 , (CH 2 ) 2 --S--(CH 2 ) 2 , (CH 2 ) 2 --SO--(CH 2 ) 2 or ##STR85## B represents (CH 2 ) 3 ; (3) A represents (CH 2 ) 2 --O--(CH 2 ) 2 and B represents p-xylylidene, (CH 2 ) 2 --O--(CH 2 ) 2 or --CH 2 --CHOH--CH 2 ; (4) A represents (CH 2 ) 3 , (CH 2 ) 4 , CH 2 ) 5 , (CH 2 ) 6 , (CH 2 ) 10 or p-xylylidene, and B represents CH 2 --CHOH--CH 2 ; and (5) A represents (CH 2 ) 2 --SO 2 --(CH 2 ) 2 and B represents (CH 2 ) 6 .
Claim 10
Dependent Claim 70 words
The process of claim 1 wherein R=CH 3 , R'=C 4 H 9 and A and B are selected from the combinations of (1) A represents (CH 2 ) 2 --S--S--(CH 2 ) 2 and B represents m-xylylidene; (2) A represents (CH 2 ) 10 and B represents CH 2 --CHOH--CH 2 ; and (3) A represents p-xylylidene and B represents (CH 2 ) 2 --O--(CH 2 ) 2 .
Claim 11
Dependent Claim 61 words
The process of claim 1 wherein R=CH 3 , R'=C 8 H 17 and A and B are selected from the combinations of (1) A represents (CH 2 ) 2 --S--S--(CH 2 ) 2 and B represents (CH 2 ) 3 ; (2) A represents (CH 2 ) 6 and B represents (CH 2 ) 2 --O--(CH 2 ) 2 .
Claim 12
Dependent Claim 62 words
The process of claim 1 wherein R=CH 3 , R'=C 12 H 25 and A and B are selected from the combinations of (1) A represents (CH 2 ) 2 --S--S--(CH 2 ) 2 and B represents (CH 2 ) 6 ; and (2) A represents (CH 2 ) 3 and B represents (CH 2 ) 2 --O--(CH 2 ) 2 .
Claim 13
Dependent Claim 61 words
The process of claim 1 wherein R=--CH 2 --CH 2 OH, R'=CH 3 and A and B are selected from the combinations of (1) A represents (CH 2 ) 3 and B represents (CH 2 ) 6 , (CH 2 ) 10 or --CH 2 --CHOH--CH 2 --; and (2) A represents m-xylylidene, and B represents (CH 2 ) 6 .
Claim 14
Dependent Claim 28 words
The process of claim 1 wherein R=--CH 2 --CHOH, R'=C 4 H 9 , A=(CH 2 ) 6 and B=(CH 2 ) 2 --o--(CH 2 ) 2 .
Claim 15
Dependent Claim 26 words
The process of claim 1 wherein R=--CH 2 --CHOH, R'=C 8 H 17 , A=(CH 2 ) 3 and B=p-xylylidene or --CH 2 --CHOH--CH 2 --.
Claim 16
Dependent Claim 24 words
The process of claim 1 wherein R=--CH 2 --CHOH, R'=C 12 H 25 , A=(CH 2 ) 6 and B=(CH 2 ) 3 .
Claim 17
Dependent Claim 36 words
The process of claim 1 wherein R and R' together represent --(CH 2 ) 2 --o--(CH 2 ) 2 -- or --(CH 2 ) 5 --, A=(CH 2 ) 6 and B=--CH 2 --CHOH--CH 2 --.
Claim 18
Dependent Claim 104 words
The process of claim 1 wherein R=R'=CH 3 , X=Br and A and B are selected from the combinations of (1) A represents (CH 2 ) 4 and B represents (CH 2 ) 7 , (CH 2 ) 9 or o-xylylidene; (2) A represents (CH 2 ) 5 and B represents ##STR86## (3) A represents (CH 2 ) 2 --O--(CH 2 ) 2 and B represents (CH 2 ) 3 ; (4) A represents ##STR87## and B represents (CH 2 ) 2 --o--(CH 2 ) 2 or --CH 2 --CHOH--CH 2 and (5) A represents p-xylylidene, and B represents CH 2 --CHOH--CH 2 .
Claim 19
Dependent Claim 67 words
The process of claim 1 wherein R=CH 3 , R'=n-propyl, x=Br and A and B are selected from the combinations of (1) A represents (CH 2 ) 3 and B represents (CH 2 ) 4 ; (2) A represents (CH 2 ) 6 and B represents ##STR88## o-xylylidene or (CH 2 ) 4 ; and (3) A represents m-xylylidene, and B represents (CH 2 ) 10 .
Claim 20
Dependent Claim 26 words
The process of claim 1 wherein R=CH 3 , R'=isopropyl, X=Br, A=(CH 2 ) 3 and B=(CH 2 ) 3 or (CH 2 ) 7 .
Claim 21
Dependent Claim 28 words
The process of claim 1 wherein R=CH 3 , R'=benzyl, B=CH 2 --CHOH--CH 2 and A=(CH 2 ) 3 when X=Br or A=(CH 2 ) 6 when X=Cl.
Claim 22
Dependent Claim 22 words
The process of claim 1 wherein R=CH 3 , R'=C 4 H 9 , X=Br, A=m-xylylidene and B=CH 2 --CHOH--CH 2 .
Claim 23
Dependent Claim 29 words
The process of claim 1 wherein R and R' together represent --(CH 2 ) 5 --, X=Br, B=CH 2 --CHOH--CH 2 and A=(CH 2 ) 2 ##STR89## or m-xylylidene.
Claim 24
Dependent Claim 292 words
A process for treating the skin comprising applying to the skin a composition comprising in a cosmetically acceptable vehicle suitable for application to the skin a quaternized polymer having recurring units of the formula ##STR90## wherein R is lower alkyl or --CH 2 --CH 2 OH; R' is alkyl, cycloalkyl or aralkyl containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen; A is a divalent group selected from ##STR91## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or alkyl having less than 18 carbon atoms, --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --, (3) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --, (4) --(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --, (5) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --, (6) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.n -- and (7) ##STR92## wherein n is equal to 2 or 3; B represents a divalent group selected from ##STR93## ##STR94## wherein D and G represent hydrogen or alkyl having less than 18 carbon atoms and v, z and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, such that the sum (v+z+u) is greater than or equal to 1 and lower than 18 and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, ##STR95## wherein n is 2 or 3; and X.sup.⊖ is an anion derived from an organic or mineral acid, said quaternized polymer being present in an amount sufficient to impart a soft feeling to the skin and to assist in the hydration thereof.
Claim 25
Dependent Claim 292 words
A process for treating the skin comprising applying to the skin a composition comprising in a cosmetically acceptable vehicle suitable for application to the skin a quaternized polymer having recurring units of the formula ##STR90## wherein R is lower alkyl or --CH 2 --CH 2 OH; R' is alkyl, cycloalkyl or aralkyl containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen; A is a divalent group selected from ##STR91## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or alkyl having less than 18 carbon atoms, --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --, (3) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --, (4) --(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --, (5) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --, (6) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.n -- and (7) ##STR92## wherein n is equal to 2 or 3; B represents a divalent group selected from ##STR93## ##STR94## wherein D and G represent hydrogen or alkyl having less than 18 carbon atoms and v, z and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, such that the sum (v+z+u) is greater than or equal to 1 and lower than 18 and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, ##STR95## wherein n is 2 or 3; and X.sup.⊖ is an anion derived from an organic or mineral acid, said quaternized polymer being present in an amount sufficient to impart a soft feeling to the skin and to assist in the hydration thereof.
Claim 26
Dependent Claim 16 words
The process of claim 23 wherein said quaternized polymer has recurring units of the formula ##STR96##

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3.5 Years (Year 4) 1996-03-22 1996-09-21 1997-03-23 $2000.00 Window Closed / Lapsed
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