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US6100193A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of manufacturing a semiconductor device

Assignee: Toshiba Corp
•
Filing: 1997-09-24
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Granted: 2000-08-08
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Expires: 2017-09-24
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Abstract

Abstract A MOSFET in which the gate electrode is formed of a polycrystalline silicon film, a silicon nitride film having a nitrogen surface density of lens than 8×10 14 cm -2 , and a tungsten film--these films formed one upon another in the order mentioned. The gate electrode thus formed, serves to shorten the delay time of the MOSFET.

Inventors

  • 👤 Shintaro Suehiro
  • 👤 Yasushi Akasaka
  • 👤 Kyoichi Suguro
  • 👤 Kazuaki Nakajima
  • 👤 Tadashi Iijima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 04:12
CPC Classifications
H; H10; H10D; H10D64/00; H10D64/01; H10D64/013; H10D64/01302; H10D64/01304; H10D64/01306; H10D64/01308; H10D64/01312; H10D30/00; H10D30/01; H10D30/021; H10D30/0223; H10D30/0227; H10D62/00; H10D62/80; H10D62/83; H10D64/01354; H10D64/20; H10D64/27; H10D64/311; H10D64/411; H10D64/511; H10D64/517; H10D64/518; H10D64/60; H10D64/62; H10D64/66; H10D64/661; H10D64/662; H10D64/664; H10W; H10W20/00; H10W20/01

Claims Analysis

Total Claims: 30
Claim 1
Independent Claim 169 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a semiconductor film consisting essentially of a semiconductor containing a semiconductor element on a substrate; depositing a first conductive film containing a metal and nitrogen on said semiconductor film, said metal being of such a type that a decrease in Gibbs free energy occurring in forming a nitride of said metal from said metal is smaller than a decrease in Gibbs free energy occurring in forming a nitride of said semiconductor element from said semiconductor element; and heating said first conductive film, thereby changing all or part of said first conductive film to a second conductive film consisting essentially of said metal, and thereby forming a third conductive film containing nitrogen and said semiconductor element and positioned in contact with said semiconductor film between said second conductive film and said semiconductor film to form at least one of an electrode and a wiring which includes said semiconductor film, said second conductive film, and said third conductive film.
Claim 2
Independent Claim 169 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a semiconductor film consisting essentially of a semiconductor containing a semiconductor element on a substrate; depositing a first conductive film containing a metal and nitrogen on said semiconductor film, said metal being of such a type that a decrease in Gibbs free energy occurring in forming a nitride of said metal from said metal is smaller than a decrease in Gibbs free energy occurring in forming a nitride of said semiconductor element from said semiconductor element; and heating said first conductive film, thereby changing all or part of said first conductive film to a second conductive film consisting essentially of said metal, and thereby forming a third conductive film containing nitrogen and said semiconductor element and positioned in contact with said semiconductor film between said second conductive film and said semiconductor film to form at least one of an electrode and a wiring which includes said semiconductor film, said second conductive film, and said third conductive film.
Claim 3
Dependent Claim 42 words
The method according claim 1, further comprising a step of depositing a metal film consisting essentially of a metal on said first conductive film, between said step of depositing said first conductive film and said step of heating said first conductive film.
Claim 4
Dependent Claim 20 words
The method according to claim 2, wherein said first conductive film and said metal film consist of the same metal.
Claim 5
Dependent Claim 37 words
The method according to claim 1, wherein said semiconductor element consists of silicon, and said metal of said first conductive film consists of a metal selected from the group consisting of tungsten, molybdenum, niobium, tantalum, and copper.
Claim 6
Dependent Claim 13 words
The method according to claim 4, wherein said semiconductor consists essentially of silicon.
Claim 7
Dependent Claim 21 words
The method according to claim 1, wherein said at least one of an electrode and a wiring comprises a gate electrode.
Claim 8
Independent Claim 145 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a semiconductor film consisting essentially of a semiconductor containing a semiconductor element on a substrate; depositing a first conductive film containing a metal and nitrogen on said semiconductor film, said metal being of such a type that a decrease in Gibbs free energy occurring in forming a nitride of said metal from said metal is smaller than a decrease in Gibbs free energy occurring in forming a nitride of said semiconductor element from said semiconductor element; and heating said first conductive film, thereby changing all or part of said first conductive film to a second conductive film containing nitrogen, said metal, and said semiconductor element, and positioned in contact with said semiconductor film to form at least one of an electrode and a wiring which includes said semiconductor film and second conductive film.
Claim 9
Independent Claim 145 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a semiconductor film consisting essentially of a semiconductor containing a semiconductor element on a substrate; depositing a first conductive film containing a metal and nitrogen on said semiconductor film, said metal being of such a type that a decrease in Gibbs free energy occurring in forming a nitride of said metal from said metal is smaller than a decrease in Gibbs free energy occurring in forming a nitride of said semiconductor element from said semiconductor element; and heating said first conductive film, thereby changing all or part of said first conductive film to a second conductive film containing nitrogen, said metal, and said semiconductor element, and positioned in contact with said semiconductor film to form at least one of an electrode and a wiring which includes said semiconductor film and second conductive film.
Claim 10
Dependent Claim 43 words
The method according to claim 7, further comprising a step of depositing a metal film consisting essentially of a metal on said first conductive film, between said step of depositing said first conductive film and said step of heating said first conductive film.
Claim 11
Dependent Claim 20 words
The method according to claim 8, wherein said first conductive film and said metal film consist of the same metal.
Claim 12
Dependent Claim 37 words
The method according to claim 7, wherein said semiconductor element consists of silicon, and said metal of said first conductive film consists of a metal selected from the group consisting of tungsten, molybdenum, niobium, tantalum, and copper.
Claim 13
Dependent Claim 13 words
The method according to claim 10, wherein said semiconductor consists essentially of silicon.
Claim 14
Dependent Claim 21 words
The method according to claim 7, wherein said at least one of an electrode and a wiring comprises a gate electrode.
Claim 15
Dependent Claim 21 words
The method according to claim 1 or 7, wherein said semiconductor film is a silicon film or a silicon germanium film.
Claim 16
Independent Claim 82 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a silicon film on a semiconductor substrate; forming a silicon carbide film on said silicon film, said silicon carbide film having a ratio of carbon atoms ranging from 50 to 75 atomic %; forming a metal film on said silicon carbide film; and performing selective anisotropic etching on said silicon film, said silicon carbide film and said metal film to form at least one of an electrode and a wiring.
Claim 17
Independent Claim 82 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a silicon film on a semiconductor substrate; forming a silicon carbide film on said silicon film, said silicon carbide film having a ratio of carbon atoms ranging from 50 to 75 atomic %; forming a metal film on said silicon carbide film; and performing selective anisotropic etching on said silicon film, said silicon carbide film and said metal film to form at least one of an electrode and a wiring.
Claim 18
Dependent Claim 52 words
The method according to claim 14, wherein said step of forming said silicon carbide film comprises the steps of: forming a carbon film on said silicon film; and implanting ions into said carbon film to mix carbon atoms and silicon atoms at an interface between said carbon film and said silicon film.
Claim 19
Dependent Claim 16 words
The method according to claim 15, wherein said ions are those of an electrically active impurity.
Claim 20
Dependent Claim 18 words
The method according to claim 14, further comprising a step of oxidizing a part of said silicon film.
Claim 21
Independent Claim 116 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a semiconductor film consisting essentially of a semiconductor containing silicon on a substrate; depositing a first conductive film containing tungsten and nitrogen on said semiconductor film; and heating said first conductive film, thereby changing all or part of said first conductive film to a second conductive film consisting essentially of tungsten, and thereby forming a third conductive film containing nitrogen and silicon and positioned in contact with said semiconductor film between said second conductive film and said semiconductor film to form at least one of an electrode and a wiring which includes said semiconductor film, said second conductive film, and said third conductive film.
Claim 22
Independent Claim 116 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a semiconductor film consisting essentially of a semiconductor containing silicon on a substrate; depositing a first conductive film containing tungsten and nitrogen on said semiconductor film; and heating said first conductive film, thereby changing all or part of said first conductive film to a second conductive film consisting essentially of tungsten, and thereby forming a third conductive film containing nitrogen and silicon and positioned in contact with said semiconductor film between said second conductive film and said semiconductor film to form at least one of an electrode and a wiring which includes said semiconductor film, said second conductive film, and said third conductive film.
Claim 23
Dependent Claim 42 words
The method according to claim 18, further comprising a step of depositing a metal film consisting essentially of tungsten on said first conductive film, between said step of depositing said first conductive film and said step of heating said first conductive film.
Claim 24
Dependent Claim 13 words
Tho method according to claim 18, wherein said semiconductor consists essentially of silicon.
Claim 25
Dependent Claim 21 words
The method according to claim 18, wherein said at least one of an electrode and a wiring comprises a gate electrode.
Claim 26
Independent Claim 92 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a semiconductor film consisting essentially of a semiconductor containing silicon on a substrate; depositing a first conductive film containing tungsten and nitrogen on said semiconductor film; and heating said first conductive film, thereby changing all or part of said first conductive film to a second conductive film containing nitrogen, tungsten, and silicon, and positioned in contact with said semiconductor film to form at least one of an electrode and a wiring which includes said semiconductor film and second conductive film.
Claim 27
Independent Claim 92 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a semiconductor film consisting essentially of a semiconductor containing silicon on a substrate; depositing a first conductive film containing tungsten and nitrogen on said semiconductor film; and heating said first conductive film, thereby changing all or part of said first conductive film to a second conductive film containing nitrogen, tungsten, and silicon, and positioned in contact with said semiconductor film to form at least one of an electrode and a wiring which includes said semiconductor film and second conductive film.
Claim 28
Dependent Claim 42 words
The method according to claim 22, further comprising a step of depositing a metal film consisting essentially of tungsten on said first conductive film, between said step of depositing said first conductive film and said stop of heating said first conductive film.
Claim 29
Dependent Claim 13 words
The method according to claim 22, wherein said semiconductor consists essentially of silicon.
Claim 30
Dependent Claim 21 words
The method according to claim 23, wherein said at least one of an electrode and a wiring comprises a gate electrode.

References Cited (Backward Citations)

US5976975A Cited
US5529954A Cited
US5503704A Cited
US5668394A Cited
US5593924A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-08-08 2004-02-07 2004-08-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-08-08 2008-02-07 2008-08-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-08-08 2012-02-07 2012-08-08 $7700.00 Window Closed / Lapsed

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