US5593924A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Use of a capping layer to attain low titanium-silicide sheet resistance and uniform silicide thickness for sub-micron silicon and polysilicon lines
Assignee: Texas Instruments Inc
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Filing: 1995-06-02
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Granted: 1997-01-14
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Expires: 2015-06-02
Abstract
Abstract A titanium-silicide process using a capping layer to reduce the silicide sheet resistance. A layer of titanium (20) is deposited. A react capping layer (22) may then be deposited to prevent contaminants from entering the titanium layer (20)during the subsequent react step. The layer of titanium (20) is then reacted to form titanium-silicide (32). The react capping layer (22) is then removed and an anneal capping layer (36) is deposited to prevent contaminants from entering the silicide layer (32) during the subsequent anneal step. Then, the silicide anneal is performed to accomplish to transformation to a lower resistivity phase of silicide. An advantage of the invention is providing a silicide process having reduced silicide sheet resistance for narrow polysilicon lines.
Inventors
- 👤 Pushkar P. Apte
- 👤 Ajit P. Paranjpe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 03:07
CPC Classifications
H; H10; H10D; H10D64/00; H10D64/01; H10D64/013; H10D64/01302; H10D64/01304; H10D64/01306; H10D64/01308; H10D64/0131; H10D30/00; H10D30/01; H10D30/021; H10D30/0212; H10D64/011; H10D64/0111; H10D64/0112; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/064; H10W20/066; Y; Y10; Y10S; Y10S438/00; Y10S438/902
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
96 words
A silicide process for a polysilicon line, comprising the steps of: depositing a layer of titanium over said polysilicon line; reacting said layer of titanium with said polysilicon line to create a silicide layer with an overlying titanium nitride layer; removing said titanium nitride layer; depositing an anneal capping barrier layer on said silicide layer, said anneal capping barrier layer comprising a material selected from the group consisting of titanium-nitride, titanium-tungsten, silicon-nitride, and metal carbides; and annealing said silicide layer at a temperature greater than 600° C. after said depositing an anneal capping barrier layer step.
Claim 2
Dependent Claim
96 words
A silicide process for a polysilicon line, comprising the steps of: depositing a layer of titanium over said polysilicon line; reacting said layer of titanium with said polysilicon line to create a silicide layer with an overlying titanium nitride layer; removing said titanium nitride layer; depositing an anneal capping barrier layer on said silicide layer, said anneal capping barrier layer comprising a material selected from the group consisting of titanium-nitride, titanium-tungsten, silicon-nitride, and metal carbides; and annealing said silicide layer at a temperature greater than 600° C. after said depositing an anneal capping barrier layer step.
Claim 3
Dependent Claim
23 words
The silicide process of claim 1, wherein said anneal capping barrier layer is deposited to a thickness on the order of 200-2000 Å.
Claim 4
Dependent Claim
26 words
The silicide process of claim 1, further comprising the step of depositing a react capping layer over said layer of titanium prior to said reacting step.
Claim 5
Dependent Claim
33 words
The silicide process of claim 1, further comprising the step of performing a pre-anneal amorphization implant of said silicide layer prior to said annealing step to amorphize a surface of said silicide layer.
Claim 6
Dependent Claim
33 words
The silicide process of claim 4, further comprising the step of performing a pre-react amorphization implant of said polysilicon line prior to said reacting step to amorphize a surface of said polysilicon line.
Claim 7
Dependent Claim
131 words
A silicide process for a semiconductor body having a polysilicon line, comprising the steps of: depositing a layer of titanium over said polysilicon line; depositing a react capping layer over said polysilicon line; reacting said layer of titanium with said polysilicon line after said step of depositing said react capping layer to create a silicide layer and a layer of titanium nitride, wherein said react capping layer prevents contaminants from entering said silicide layer during said reacting step; stripping said layer of titanium nitride and said capping layer; depositing an anneal capping layer over said silicide layer after said stripping step; and annealing said silicide layer at a temperature on the order of 850° C., wherein said anneal capping layer prevents contaminants from entering said silicide layer during said annealing step.
Claim 8
Dependent Claim
131 words
A silicide process for a semiconductor body having a polysilicon line, comprising the steps of: depositing a layer of titanium over said polysilicon line; depositing a react capping layer over said polysilicon line; reacting said layer of titanium with said polysilicon line after said step of depositing said react capping layer to create a silicide layer and a layer of titanium nitride, wherein said react capping layer prevents contaminants from entering said silicide layer during said reacting step; stripping said layer of titanium nitride and said capping layer; depositing an anneal capping layer over said silicide layer after said stripping step; and annealing said silicide layer at a temperature on the order of 850° C., wherein said anneal capping layer prevents contaminants from entering said silicide layer during said annealing step.
Claim 9
Dependent Claim
47 words
The silicide process of claim 6, further comprising the step of performing a pre-react amorphization implant of said polysilicon line prior to said reacting step by implanting a species selected from the group consisting of arsenic, antimony, and germanium to amorphize a surface of said polysilicon line.
Claim 10
Dependent Claim
47 words
The silicide process of claim 7, further comprising the step of performing a pre-anneal amorphization implant of said silicide layer prior to said annealing step by implanting a species selected from the group consisting of arsenic, antimony, and germanium to amorphize a surface of said silicide layer.
Claim 11
Dependent Claim
67 words
A silicide process comprising the steps of: depositing a titanium layer over a polysilicon layer; depositing a first layer of titanium nitride over said titanium layer; reacting said titanium layer with said polysilicon layer to form a silicide layer; removing said first titanium nitride layer; depositing a second layer of titanium nitride over said silicide layer; annealing said silicide layer; and removing the second titanium nitride layer.
Claim 12
Dependent Claim
67 words
A silicide process comprising the steps of: depositing a titanium layer over a polysilicon layer; depositing a first layer of titanium nitride over said titanium layer; reacting said titanium layer with said polysilicon layer to form a silicide layer; removing said first titanium nitride layer; depositing a second layer of titanium nitride over said silicide layer; annealing said silicide layer; and removing the second titanium nitride layer.
Claim 13
Dependent Claim
23 words
The silicide process of claim 9, wherein said first and second titanium nitride layers have a thickness on the order of 200-2000 Å.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2000-01-14 | 2000-07-15 | 2001-01-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2004-01-14 | 2004-07-15 | 2005-01-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2008-01-14 | 2008-07-15 | 2009-01-14 | $7700.00 | Window Closed / Lapsed |