US5503704A
Expired / Lapsed
US
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Nitrogen based low temperature direct bonding
Assignee: Epir Technologies Inc
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Filing: 1994-06-08
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Granted: 1996-04-02
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Expires: 2014-06-08
Abstract
Abstract A process for direct bonding similar or dissimilar materials at low temperatures in which a material surface is rendered hydrophilic and reactive by creating nitrogen based radicals on the surface, the surface is direct bonded to a second surface, and the bonded surfaces are annealed at a temperature below approximately 500° C. A nitrogen based constituent is combined with an activator to render the surface hydrophilic and reactive through ammonia plasma activation or activation by use of hydrofluoric acid.
Inventors
- 👤 Robert W. Bower
- 👤 Mohd S. Ismail
- 👤 Brian E. Roberds
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 21:32
CPC Classifications
C; C04; C04B; C04B37/00; C04B37/001; A; A61; A61B; A61B18/00; A61B2018/00053; A61B2018/00107; A61B2018/00119; Y; Y10; Y10S; Y10S438/00; Y10S438/974; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31536
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
133 words
A method for direct bonding nitrogen based materials at low temperatures, comprising the steps of: (a) creating nitrogen-based radicals on the surface of a material to be bonded, said surface being rendered hydrophilic by the creating of said nitrogen-based radicals, said step of creating nitrogen-based radicals comprising the steps of placing the surface of a nitrogen based material in a solution of dilute unbuffered hydrofluoric acid, said solution including less than approximately five percent HF, whereby said surface is rendered hydrophilic and reactive; (b) removing said surface from said solution of dilute hydrofluoric acid after approximately ten seconds; (c) bringing said surface into physical contact with a second hydrophilic and reactive surface to form an initial bond at room temperature; and annealing said initially bonded surfaces at a temperature below approximately 500° C.
Claim 2
Independent Claim
133 words
A method for direct bonding nitrogen based materials at low temperatures, comprising the steps of: (a) creating nitrogen-based radicals on the surface of a material to be bonded, said surface being rendered hydrophilic by the creating of said nitrogen-based radicals, said step of creating nitrogen-based radicals comprising the steps of placing the surface of a nitrogen based material in a solution of dilute unbuffered hydrofluoric acid, said solution including less than approximately five percent HF, whereby said surface is rendered hydrophilic and reactive; (b) removing said surface from said solution of dilute hydrofluoric acid after approximately ten seconds; (c) bringing said surface into physical contact with a second hydrophilic and reactive surface to form an initial bond at room temperature; and annealing said initially bonded surfaces at a temperature below approximately 500° C.
Claim 3
Dependent Claim
68 words
A method as recited in claim 1, said step of placing said nitrogen based surface in a solution of dilute unbuffered hydrofluoric acid is preceded by the step of cleaning said surface in a base bath solution at a temperature of approximately 75 ° C. for approximately 10 minutes, said base bath solution comprising approximately a 20:4:1 solution of H 2 O:H 2 O 2 :NH 4 OH.
Claim 4
Dependent Claim
61 words
A method as recited in claim 2, wherein said step of cleaning said surface in said base bath solution is followed by the step of cleaning said surface in an acid bath solution at a temperature of approximately 75 degrees centigrade for approximately minutes, said acid bath solution comprising approximately a 6:1:1 solution of H 2 O:H 2 O 2 :HCL.
Claim 5
Independent Claim
109 words
A method for nitrogen based low temperature direct bonding, comprising the steps of: (a) creating nitrogen-based radicals on the surface of a material to be bonded by placing said surface in a solution of dilute unbuffered hydrofluoric acid, said solution including less than approximately five percent HF, and thereby rendering said surface rendered hydrophilic and reactive by the creating of said nitrogen-based radicals, said surface including a nitrogen based material; (b) bringing said surface into physical contact with a second said hydrophilic and reactive surface to form an initial bond at room temperature; and (c) annealing said initially bonded surfaces at a temperature of less than approximately 500° C.
Claim 6
Independent Claim
109 words
A method for nitrogen based low temperature direct bonding, comprising the steps of: (a) creating nitrogen-based radicals on the surface of a material to be bonded by placing said surface in a solution of dilute unbuffered hydrofluoric acid, said solution including less than approximately five percent HF, and thereby rendering said surface rendered hydrophilic and reactive by the creating of said nitrogen-based radicals, said surface including a nitrogen based material; (b) bringing said surface into physical contact with a second said hydrophilic and reactive surface to form an initial bond at room temperature; and (c) annealing said initially bonded surfaces at a temperature of less than approximately 500° C.
Claim 7
Dependent Claim
20 words
A method as recited in claim 4, wherein said solution of dilute unbuffered hydrofluoric acid includes approximately one percent HF.
Claim 8
Dependent Claim
24 words
A method as recited in claim 5, wherein said surface is removed from said solution of dilute unbuffered hydrofluoric acid after approximately ten seconds.
Claim 9
Dependent Claim
53 words
A method as recited in claim 4, wherein said step of rendering said surface hydrophilic and reactive by creating nitrogen based radicals on said surface is preceded by the step of cleaning said surface in a base bath comprising approximately a 20:4:1 solution of H 2 O:H 2 O 2 :NH 4 OH.
Claim 10
Dependent Claim
25 words
A method as recited in claim 7, further comprising the step of heating said base bath solution to a temperature of approximately 75 degrees centigrade.
Claim 11
Dependent Claim
21 words
A method as recited in claim 8, wherein said surface is cleaned in said base bath solution for approximately ten minutes.
Claim 12
Dependent Claim
33 words
A method as recited in claim 7, wherein said step of cleaning said surface in a base bath solution is followed by the step of cleaning said surface in an acid bath solution.
Claim 13
Dependent Claim
25 words
A method as recited in claim 10, wherein said acid bath solution comprises approximately a 6:1:1 solution of H 2 O:H 2 O 2 :HCL.
Claim 14
Dependent Claim
25 words
A method as recited in claim 11, further comprising the step of heating said acid bath solution to a temperature of approximately 75 degrees centigrade.
Claim 15
Dependent Claim
21 words
A method as recited in claim 12, wherein said surface is cleaned in said acid bath solution for approximately ten minutes.
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