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Methods, complexes, and systems for forming metal-containing films

Assignee: Micron Technology Inc
•
Filing: 1998-08-25
•
Granted: 2000-02-01
•
Expires: 2018-08-25
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Abstract

Abstract A method of forming a film on a substrate using, Group III metal complexes, including Group IIIA metals and Group IIIB metals, which include the lanthanides. The complexes and methods are particularly suitable for the preparation of semiconductor structures using chemical vapor deposition techniques and systems.

Inventors

  • 👤 Brian A. Vaartstra
  • 👤 Brenda D. Wanner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:38
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/20; H10P14/29; H10P14/2901; H10P14/2922; C; C07; C07F; C07F5/00; C07F5/003; C07F5/06; C07F5/069; C23; C23C; C23C16/00; C23C16/06; C23C16/18; C23C16/20; H10P14/24; H10P14/2902; H10P14/2905; H10P14/34; H10P14/3402; H10P14/3414; H10P14/3421; H10P14/3438; H10P14/3441; H10P14/3442; H10P14/3444; H10P14/40; H10P14/42; H10P14/43

Claims Analysis

Total Claims: 32
Claim 1
Independent Claim 37 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)]MH (Formula III) wherein: M is a Group IIIB metal; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 2
Dependent Claim 37 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)]MH (Formula III) wherein: M is a Group IIIB metal; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 3
Dependent Claim 37 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)]MH.sub.2 (Formula IV) wherein: M is a Group IIIA metal; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 4
Dependent Claim 37 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)]MH.sub.2 (Formula IV) wherein: M is a Group IIIA metal; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 5
Dependent Claim 43 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)]MHR.sup.5 (Formula V); wherein: M is a Group IIIA metal; R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group; and R 5 is an organic group.
Claim 6
Dependent Claim 43 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)]MHR.sup.5 (Formula V); wherein: M is a Group IIIA metal; R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group; and R 5 is an organic group.
Claim 7
Dependent Claim 38 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)].sub.2 MH (Formula VI) wherein: M is a Group IIIA metal; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 8
Dependent Claim 38 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)].sub.2 MH (Formula VI) wherein: M is a Group IIIA metal; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 9
Dependent Claim 44 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)].sub.2 MHR.sup.5 (Formula VII) wherein: M is a Group IIIA metal; R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group; and R 5 is an organic group.
Claim 10
Dependent Claim 44 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)].sub.2 MHR.sup.5 (Formula VII) wherein: M is a Group IIIA metal; R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group; and R 5 is an organic group.
Claim 11
Dependent Claim 38 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)].sub.3 MH (Formula VIII) wherein: M is a Group IIIA metal; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 12
Dependent Claim 38 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)].sub.3 MH (Formula VIII) wherein: M is a Group IIIA metal; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 13
Dependent Claim 47 words
A complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)].sub.x ML.sub.y (Formula I) wherein: M is a Group IIIB metal; each R 1 , R 2 , R 3 , and R 4 group is independently an organic group; L is an organic group; x=1 to 4; and y=1 to 4.
Claim 14
Dependent Claim 47 words
A complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)].sub.x ML.sub.y (Formula I) wherein: M is a Group IIIB metal; each R 1 , R 2 , R 3 , and R 4 group is independently an organic group; L is an organic group; x=1 to 4; and y=1 to 4.
Claim 15
Dependent Claim 12 words
The complex of claim 7 wherein M is Sc, Y, or La.
Claim 16
Dependent Claim 11 words
The complex of claim 7 wherein L is an alkyl moiety.
Claim 17
Dependent Claim 34 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)]MH (Formula III) wherein: M is Al; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 18
Dependent Claim 34 words
A hydride complex of the formula: [(R.sup.1)NC(R.sup.2)C(R.sup.3)N(R.sup.4)]MH (Formula III) wherein: M is Al; and R 1 , R 2 , R 3 , and R 4 are each independently H or an organic group.
Claim 19
Dependent Claim 33 words
The hydride complex of claim 1 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 30 ) organic group.
Claim 20
Dependent Claim 33 words
The hydride complex of claim 1 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 4 ) alkyl moiety.
Claim 21
Dependent Claim 33 words
The hydride complex of claim 2 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 30 ) organic group.
Claim 22
Dependent Claim 33 words
The hydride complex of claim 2 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 4 ) alkyl moiety.
Claim 23
Dependent Claim 45 words
The hydride complex of claim 3 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 30 ) organic group and R 5 is a (C 1 -C 30 ) organic group.
Claim 24
Dependent Claim 45 words
The hydride complex of claim 3 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 4 ) alkyl moiety and R 5 is a (C 1 -C 4 ) alkyl moiety.
Claim 25
Dependent Claim 33 words
The hydride complex of claim 4 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 30 ) organic group.
Claim 26
Dependent Claim 33 words
The hydride complex of claim 4 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 4 ) alkyl moiety.
Claim 27
Dependent Claim 45 words
The hydride complex of claim 5 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 30 ) organic group and R 5 is a (C 1 -C 30 ) organic group.
Claim 28
Dependent Claim 45 words
The hydride complex of claim 5 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 4 ) alkyl moiety and R 5 is a (C 1 -C 4 ) alkyl moiety.
Claim 29
Dependent Claim 33 words
The hydride complex of claim 6 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 30 ) organic group.
Claim 30
Dependent Claim 33 words
The hydride complex of claim 6 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 4 ) alkyl moiety.
Claim 31
Dependent Claim 33 words
The hydride complex of claim 7 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 30 ) organic group.
Claim 32
Dependent Claim 33 words
The hydride complex of claim 7 wherein each R 1 , R 2 , R 3 , and R 4 group is independently H or a (C 1 -C 4 ) alkyl moiety.

References Cited (Backward Citations)

DE295876C Cited
US5151305A Cited
US5552181A Cited
US5492725A Cited

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