US6013569A
Expired / Lapsed
US
⏱️ 0.0 years remaining
One step salicide process without bridging
Assignee: United Microelectronics Corp
•
Filing: 1997-07-07
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Granted: 2000-01-11
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Expires: 2017-07-07
Abstract
Abstract Silicidation of a polysilicon line having frcc upper sidewalls is performed so that no stress is applied to the sidewalls of the polysilicon line, resulting in the formation of a reduced stress silicide structure. This is accomplished by forming a polysilicon line having spacers on either side which extend above the upper surface of the polysilicon line but which are spaced from the edge of the polysilicon line. A layer of a metal such as titanium or tungsten is provided in contact with the top surface polysilicon line. The structure is annealed to cause the metal to react with the polysilicon to form a layer of silicide. Since the upper side portions of the polysilicon line are spaced away from the spacers during the silicidation anneal, the growing silicide region has room to expand without being subjected to lateral stresses in the silicidation process. The suicide is formed in a reduced stress condition, as compared to conventional processes, so that the silicide layer produced will be more readily converted to the desired low resistivity phase of silicide.
Inventors
- 👤 Water Lur
- 👤 Tony Lin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 09:10
CPC Classifications
H; H10; H10D; H10D30/00; H10D30/01; H10D30/021; H10D30/0223; H10D30/0227; H10D30/0212; H10D64/00; H10D64/01; H10D64/013; H10D64/01302; H10D64/01354; H10D64/021; H10D64/017
Claims Analysis
Total Claims: 34
Claim 1
Independent Claim
118 words
A method of making a semiconductor device comprising: forming a polysilicon electrode over a substrate; providing spacers on either side of the polysilicon electrode, upper edges of the spacers extending above an upper surface of the polysilicon electrode, upper recesses separating upper edges of the polysilicon electrode from the spacers; providing a liner layer having a portion near the polysilicon electrode separating the spacers from the substrate such that outer edges of the spacers are separated from the substrate by lower recesses; after said providing a liner layer, depositing a metal layer over the polysilicon electrode, the spacers and the substrate; and annealing to form a metal silicide layer on the polysilicon electrode and disposed between the spacers.
Claim 2
Independent Claim
118 words
A method of making a semiconductor device comprising: forming a polysilicon electrode over a substrate; providing spacers on either side of the polysilicon electrode, upper edges of the spacers extending above an upper surface of the polysilicon electrode, upper recesses separating upper edges of the polysilicon electrode from the spacers; providing a liner layer having a portion near the polysilicon electrode separating the spacers from the substrate such that outer edges of the spacers are separated from the substrate by lower recesses; after said providing a liner layer, depositing a metal layer over the polysilicon electrode, the spacers and the substrate; and annealing to form a metal silicide layer on the polysilicon electrode and disposed between the spacers.
Claim 3
Dependent Claim
35 words
The method of claim 1 including separating the polysilicon electrode from the spacers on each side by the liner layer, such that the liner layer extends only part of a height of the polysilicon electrode.
Claim 4
Dependent Claim
18 words
The method of claim 2, wherein the liner layer comprises an oxide and the spacers comprise a nitride.
Claim 5
Dependent Claim
15 words
The method of claim 1, wherein the annealing step consists of a single annealing step.
Claim 6
Dependent Claim
30 words
The method of claim 4, wherein the single annealing step is perfonned at a temperature of at least 700° C. which converts the metal layer to the metal silicide layer.
Claim 7
Dependent Claim
23 words
The method of claim 5, wherein the step of depositing a metal layer consists of depositing a refractory metal in a sputtering process.
Claim 8
Dependent Claim
28 words
The method of claim 1, wherein the step of depositing a metal layer forms a metal layer having a discontinuity adjacent at least one of the lower recesses.
Claim 9
Dependent Claim
36 words
The method of claim 1, further comprising the step of forming a sacrificial layer over the polysilicon electrode, wherein the spacers extend above the height of the polysilicon electrode by a thickness of the sacrificial layer.
Claim 10
Dependent Claim
20 words
The method of claim 8, wherein the sacrificial layer is used as a hard mask for patterning the polysilicon electrode.
Claim 11
Dependent Claim
18 words
The method of claim 9, wherein the sacrificial layer comprises an oxide and the spacers comprise a nitride.
Claim 12
Independent Claim
93 words
A method of making a semiconductor device comprising: forming a polysilicon electrode over a substrate; providing spacers on either side of the polysilicon electrode, lower edges of the spacers separated by a layer of insulating material from the substrate adjacent the polysilicon electrode and the lower edges of the spacers separated from the substrate by lower recesses along outer edges of the spacers; depositing a metal layer over the polysilicon electrode, the spacers and the substrate; and annealing to form a metal silicide layer on the polysilicon electrode and disposed between the spacers.
Claim 13
Independent Claim
93 words
A method of making a semiconductor device comprising: forming a polysilicon electrode over a substrate; providing spacers on either side of the polysilicon electrode, lower edges of the spacers separated by a layer of insulating material from the substrate adjacent the polysilicon electrode and the lower edges of the spacers separated from the substrate by lower recesses along outer edges of the spacers; depositing a metal layer over the polysilicon electrode, the spacers and the substrate; and annealing to form a metal silicide layer on the polysilicon electrode and disposed between the spacers.
Claim 14
Dependent Claim
63 words
The method of claim 11, wherein: the polysilicon electrode is positioned over a channel region in the substrate defined on either side by doped source/drain regions, the spacers are positioned at least partially over the doped source/drain regions, the metal layer is deposited on surfaces of the doped source/drain regions, and the annealing step forms metal silicide layers on the doped source/drain regions.
Claim 15
Dependent Claim
28 words
The method of claim 12, wherein the step of depositing a metal layer forms the metal layer with a discontinuity adjacent at least one of the lower recesses.
Claim 16
Dependent Claim
31 words
The method of claim 13, wherein the spacers are separated from the substrate near the polysilicon electrode by a liner layer that extends only part of a width of each spacer.
Claim 17
Dependent Claim
18 words
The method of claim 14, wherein the liner layer comprises an oxide and the spacers comprise a nitride.
Claim 18
Dependent Claim
28 words
The method of claim 15, wherein the lower recesses are formed in a wet etching process which selectively etches oxide at a higher rate than nitride is etched.
Claim 19
Dependent Claim
32 words
The method of claim 11, wherein upper edges of the spacers extend above an upper surface of the polysilicon electrode, upper recesses separating upper edges of the polysilicon electrode from the spacers.
Claim 20
Dependent Claim
21 words
The method of claim 17, wherein the deposited metal layer has a discontinuity adjacent at least one of the upper recesses.
Claim 21
Dependent Claim
15 words
The method of claim 12, wherein the annealing step consists of a single annealing step.
Claim 22
Dependent Claim
30 words
The method of claim 19, wherein the single annealing step is performed at a temperature of at least 700° C. which converts the metal layer to the metal silicide layer.
Claim 23
Dependent Claim
19 words
The method of claim 20, wherein the single annealing step is performed at a temperature of about 800-850° C.
Claim 24
Dependent Claim
25 words
The method of claim 13, wherein the metal layer in contact with the spacers remains at least partially unreacted metal during the single annealing step.
Claim 25
Dependent Claim
23 words
The method of claim 20, wherein the step of depositing a metal layer consists of depositing a refractory metal in a sputtering process.
Claim 26
Independent Claim
175 words
A method of forming a semiconductor device, the method comprising: providing a polysilicon layer over a substrate; providing a sacrificial layer over the polysilicon layer; patterning the sacrificial layer to form a patterned sacrificial layer and then patterning the polysilicon layer to form a polysilicon electrode; forming a liner layer over edges of the polysilicon electrode; forming spacers spaced from the polysilicon electrode by the liner layer; etching to remove the patterned sacrificial layer from between the spacers so that upper edges of the spacers extend above an upper surface of the polysilicon electrode; etching the liner layer from between the spacers and the polysilicon electrode to form upper recesses; separating the spacers from the substrate by a portion of the liner layer near the polysilicon electrode such that outer edges of the spacers are separated from the substrate by lower recesses; after said separating, depositing a metal layer over the polysilicon electrode, the spacers and the substrate; and annealing to form a metal silicide layer on the polysilicon electrode and disposed between the spacers.
Claim 27
Independent Claim
175 words
A method of forming a semiconductor device, the method comprising: providing a polysilicon layer over a substrate; providing a sacrificial layer over the polysilicon layer; patterning the sacrificial layer to form a patterned sacrificial layer and then patterning the polysilicon layer to form a polysilicon electrode; forming a liner layer over edges of the polysilicon electrode; forming spacers spaced from the polysilicon electrode by the liner layer; etching to remove the patterned sacrificial layer from between the spacers so that upper edges of the spacers extend above an upper surface of the polysilicon electrode; etching the liner layer from between the spacers and the polysilicon electrode to form upper recesses; separating the spacers from the substrate by a portion of the liner layer near the polysilicon electrode such that outer edges of the spacers are separated from the substrate by lower recesses; after said separating, depositing a metal layer over the polysilicon electrode, the spacers and the substrate; and annealing to form a metal silicide layer on the polysilicon electrode and disposed between the spacers.
Claim 28
Dependent Claim
17 words
The method of claim 24, wherein the liner layer is formed by thermally oxidizing the polysilicon electrode.
Claim 29
Dependent Claim
16 words
The method of claim 25, wherein the liner layer is between about 300-500 Å in thickness.
Claim 30
Dependent Claim
21 words
The method of claim 24, wherein the patterned sacrificial layer is used as a hard mask for etching the polysilicon layer.
Claim 31
Dependent Claim
25 words
The method of claim 24, wherein the sacrificial layer is sized to function as a quarter wave plate during the patterning of the sacrificial layer.
Claim 32
Dependent Claim
28 words
The method of claim 24, wherein the step of depositing a metal layer forms a metal layer having a discontinuity adjacent at least one of the lower recesses.
Claim 33
Dependent Claim
32 words
The method of claim 12, wherein the annealing step consists of a single rapid thermal annealing step performed at a temperature in the range of about 800--850° C. for about 20 seconds.
Claim 34
Dependent Claim
31 words
The method of claim 30, wherein the annealing step forms a low resistivity phase titanium silicide layer over the gate electrode and a further titanium silicide layer over the source/drain regions.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2003-01-10 | 2003-07-12 | 2004-01-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2007-01-10 | 2007-07-12 | 2008-01-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2011-01-10 | 2011-07-12 | 2012-01-11 | $7700.00 | Window Closed / Lapsed |