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Indenyl compounds and catalyst components for the polymerization of olefins

Assignee: ROYAL DSM NV
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Filing: 1997-03-10
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Granted: 1999-11-23
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Expires: 2017-03-10
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Abstract

Abstract The invention relates to an indenyl compound of the general formulaR'Ind-M-(Cp)Qkin which the symbols have the following meanings: Ind: an indenyl group R': a substituent, other than hydrogen, to the Ind group, Cp: a cyclopentadienyl group M: a transition metal from group 3, 4, 5 or 6 of the Periodic System of Elements Q: a ligand to M and k is an integer linked to the valence of M. The invention is characterized in that the R' group is bound to the Ind group at the 2-position. The indenyl compound is a catalyst component for the polymerization of olefins. The invention also relates to polymers obtainable with such indenyl compounds.

Inventors

  • 👤 Johannus A. M. van Beek
  • 👤 Johannes G. de Vries
  • 👤 Henricus J. Arts
  • 👤 Radjindrakumar Persad
  • 👤 Gerardus H. J. van Doremaele

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 16:49
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/16; C07; C07F; C07F17/00; C08F10/00; C08F10/02; C08F110/00; C08F110/02; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/639; C08F4/63912; C08F4/6392; C08F4/63922; Y; Y10; Y10S; Y10S526/00; Y10S526/943

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 188 words
A process for polymerizing an olefin which comprises contacting at least one olefin with a 2-indenyl compound having an unsaturated aromatic six-membered ring, in the presence of a cocatalyst, under effective polymerization conditions, wherein said 2-indenyl compound is represented by the general formula R'Ind--M--(CP)--Q.sub.k ( 1) wherein Ind represents an indenyl group, R' represents a substituent, other than hydrogen, bound to the Ind group at the 2-position, Cp represents a cyclopentadienyl group, M represents a transition metal from group 4, 5, or 6 of the Periodic System of Elements, Q represents a ligand to M, and k is an integer linked to the valence of M, wherein k equals the valence of M minus two divided by the valence of Q, and wherein in said process for polymerizing an olefin, processes utilizing compounds in which the Cp-group is an indenyl group and in which either: a) the Ind- and the Cp-groups are bridged over the respective 1-positions, b) the indenyl compound is bis(2,3-dimethyl-1-indenyl)-zirconiumdichloride, or c) the indenyl compound is either ethylene-1-(3-but-3-enyl) inden-1-yl-2-((1-but-3-enyl)-inden-2-yl)-zirconiumdichloride, or ethylene-1-((3-allyldimethylsilyl) inden-1-yl)-2-((1-allyldimethylsilyl)inden-2-yl)zirconium-dichloride, are disclaimed as the process for polymerizing an olefin with a 2-indenyl compound.
Claim 2
Dependent Claim 12 words
A process according to claim 1, wherein R' is an alkyl group.
Claim 3
Dependent Claim 34 words
A process according to claim 1 wherein the Cp group is a 2-indenyl group represented by the formula: R"Ind wherein R" represents a substituent other than hydrogen at the 2-position of the Ind group.
Claim 4
Dependent Claim 12 words
A process according to claim 3, wherein R" is an alkyl group.
Claim 5
Dependent Claim 14 words
A process according to claim 4, wherein said alkyl group contains 1-4 carbon atoms.
Claim 6
Dependent Claim 22 words
A process according to claim 1, wherein R' forms a bridge between the Ind group and the Cp group in formula (1).
Claim 7
Dependent Claim 53 words
A process according to claim 6, wherein said indenyl compound is represented by the formula: ##STR3## wherein R is bound at the 2-position to both 2-Ind groups, wherein R is a hydrocarbon group or a group with at least one heteroatom from group 14, 15 or 16 of the Periodic System of Elements.
Claim 8
Dependent Claim 41 words
A process according to claim 7, wherein R is selected from the group consisting of a methylidene group, an ethylidene group and a group having at least one heteroatom from group 14, 15 or 16 of the Periodic System of Elements.
Claim 9
Dependent Claim 23 words
A process according to claim 8, wherein R contains a heteroatom selected from the group consisting of silicon, nitrogen, phosphorus, oxygen and sulphur.
Claim 10
Dependent Claim 47 words
A process according to claim 8, wherein said R-group is a sulphur atom, --(CH 2 ) 2 --S--(CH 2 ) 2 --, an oxygen atom, (CH 3 ) 2 Si═, --Si(CH 3 ) 2 --Si(CH 3 ) 2 --, Ge(CH 3 ) 2 --, (phenyl)P═, or (phenyl)N═.
Claim 11
Dependent Claim 14 words
A process according to claim 8, wherein said R group is a hydrocarbon group.
Claim 12
Dependent Claim 25 words
A process according to claim 1, wherein said at least one olefin is selected from the group consisting of ethylene, α-olefin, internal olefin, and diolefin.
Claim 13
Dependent Claim 26 words
A process according to claim 1, wherein said at least one olefin is selected from the group consisting of ethylene, propylene, butene, pentene, heptene, and octene.
Claim 14
Dependent Claim 27 words
A process according to claim 1, wherein said polymerization yields a polymer based on at least one of olefin selected from the group consisting ethylene and propylene.
Claim 15
Dependent Claim 21 words
A process according to claim 13, wherein said polymerization yields a rubbery polymer based on ethylene, propylene and, optionally, a diene.
Claim 16
Dependent Claim 36 words
A process for polymerizing at least one olefin which comprises contacting at least one olefin with a 2,2'-bridged bisindenyl Group 4, 5, or 6 metallocene compound, in the presence of a cocatalyst, under effective polymerization conditions.
Claim 17
Dependent Claim 36 words
A process for polymerizing at least one olefin which comprises contacting at least one olefin with a 2,2'-bridged bisindenyl Group 4, 5, or 6 metallocene compound, in the presence of a cocatalyst, under effective polymerization conditions.
Claim 18
Dependent Claim 29 words
A process for polymerizing at least one olefin which comprises contacting at least one olefin with a 2,2'-bridged bisindenyl Group 3 or lanthanide metallocene compound under effective polymerization conditions.
Claim 19
Dependent Claim 29 words
A process for polymerizing at least one olefin which comprises contacting at least one olefin with a 2,2'-bridged bisindenyl Group 3 or lanthanide metallocene compound under effective polymerization conditions.
Claim 20
Dependent Claim 116 words
A process for polymerizing an olefin which comprises contacting at least one olefin with a 2-indenyl compound, optionally in the presence of a cocatalyst, under effective polymerization conditions, wherein said 2-indenyl compound is represented by the general formula R'Ind--M--(Cp)--Q.sub.k ( 1) wherein Ind represents an indenyl group, R' represents a substituent, other than hydrogen, bound to the Ind group at the 2-position, Cp represents a cyclopentadienyl group, M represents a transition metal from group 3 and the lanthanides of the Periodic System of Elements, Q represents a ligand to M, and k is an integer linked to the valence of M, wherein k equals the valence of M minus two divided by the valence of Q.
Claim 21
Dependent Claim 116 words
A process for polymerizing an olefin which comprises contacting at least one olefin with a 2-indenyl compound, optionally in the presence of a cocatalyst, under effective polymerization conditions, wherein said 2-indenyl compound is represented by the general formula R'Ind--M--(Cp)--Q.sub.k ( 1) wherein Ind represents an indenyl group, R' represents a substituent, other than hydrogen, bound to the Ind group at the 2-position, Cp represents a cyclopentadienyl group, M represents a transition metal from group 3 and the lanthanides of the Periodic System of Elements, Q represents a ligand to M, and k is an integer linked to the valence of M, wherein k equals the valence of M minus two divided by the valence of Q.

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