EP0427697A2
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EP
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Metallocene catalysts with Lewis acids and aluminum alkyls
Assignee: Fina Technology Inc
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Filing: 1990-10-09
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Granted: —
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Expires: 2010-10-09
Abstract
Abstract This invention is for a catalyst system comprising a neutral metallocene compound, an aluminum alkyl and a Lewis acid. The Lewis acid must be of sufficient acidity to ionize a neutral metallocene compound to form a cationic metallocene catalyst. The ligands of the Lewis acid should not be reactive with the metallocene cation. Any metallocene catalyst compound having two cyclopentadienyl rings attached to a transition metal would be useful in this invention. The invention is also for the process of using the catalyst system in polymerization of olefins. The metallocene is contacted with the Lewis acid. The aluminum alkyl is contacted with the olefin. The two mixtures are contacted with each other under polymerization conditions.
Inventors
- 👤 John A. Ewen
- 👤 Michael J. Elder
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-10-28 21:00
CPC Classifications
C; C08; C08F; C08F4/00; C08F10/00; C08F10/04; C08F10/06; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/639; C08F4/63908; C08F4/63912; C08F4/6392; C08F4/63922; C08F4/64; C08F4/659; C08F4/65908; C08F4/6592; C08F4/65922; C08F4/65927; Y; Y10; Y10S; Y10S526/00; Y10S526/901; Y10S526/943
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
158 words
A catalyst system comprising: a) a neutral metallocene compound; b) an aluminum alkyl; and c) a Lewis acid; wherein the aluminum alkyl is of the general formula AlR₃ where R is a halogen, oxygen, hydride, alkyl, alkoxy or aryl, each R being the same of different and at least one R is an alkyl, wherein the neutral metallocene compound is of the general formula: Cp₂MR p wherein Cp is cyclopentadienyl or substituted cyclopentadienyl, each Cp being the same or different, M is a Group III, IV, V or VI metal, R is a hydride, a halogen, an amide or a hydrocarbyl radical, each R being the same or different, except only one R is a hydride and p is from 1 to 4, wherein the Lewis acid is of sufficient acidity to ionize a neutral metallocene compound to form a cationic metallocene catalyst, and wherein the ligands of the Lewis acid are not reactive with the metallocene cation.
Claim 2
Dependent Claim
158 words
A catalyst system comprising: a) a neutral metallocene compound; b) an aluminum alkyl; and c) a Lewis acid; wherein the aluminum alkyl is of the general formula AlR₃ where R is a halogen, oxygen, hydride, alkyl, alkoxy or aryl, each R being the same of different and at least one R is an alkyl, wherein the neutral metallocene compound is of the general formula: Cp₂MR p wherein Cp is cyclopentadienyl or substituted cyclopentadienyl, each Cp being the same or different, M is a Group III, IV, V or VI metal, R is a hydride, a halogen, an amide or a hydrocarbyl radical, each R being the same or different, except only one R is a hydride and p is from 1 to 4, wherein the Lewis acid is of sufficient acidity to ionize a neutral metallocene compound to form a cationic metallocene catalyst, and wherein the ligands of the Lewis acid are not reactive with the metallocene cation.
Claim 3
Dependent Claim
36 words
A catalyst as recited in Claim 1 wherein R is a hydrocarbyl radical selected from the group consisting of an alkyl, an aryl, an alkenyl, an alkylaryl and an arylalkyl having up to 20 carbon atoms.
Claim 4
Dependent Claim
27 words
A catalyst as recited in Claim 2 wherein R is an alkyl or alkoxy of up to six carbons or an aryl of up to 10 carbons.
Claim 5
Dependent Claim
25 words
A catalyst as recited in Claim 1 wherein the M is a Group IV metal selected from the group consisting of titanium, zirconium and hafnium.
Claim 6
Dependent Claim
28 words
A catalyst as recited in Claim 4 wherein the neutral methyl derivative of a metallocene is chosen from the group consisting of ethylenebis(indenyl)zirconium dimethyl and isopropylidene(cyclopentadienyl-1-fluorenyl) zirconium dimethyl.
Claim 7
Dependent Claim
21 words
A catalyst as recited in Claim 1 wherein the aluminum alkyl is selected from the group consisting of triethylaluminum and trimethylaluminum.
Claim 8
Dependent Claim
13 words
A catalyst as recited in Claim 6 wherein the aluminum alkyl is triethylaluminum.
Claim 9
Dependent Claim
26 words
A catalyst as recited in Claim 1 wherein the Lewis acid is chosen from the group consisting of all Lewis acids containing boron and magnesium chloride.
Claim 10
Dependent Claim
13 words
A catalyst as recited in Claim 8 wherein the Lewis acid is tris(pentafluorophenyl)boron.
Claim 11
Dependent Claim
105 words
A process for preparing a catalyst comprising: a) mixing a Lewis acid with a neutral metallocene compound; and b) allowing contact between the ionizing ionic compound and the neutral metallocene cpmpound; wherein the neutral derivative of a metallocene is of the general formula: Cp₂MR p wherein Cp is a cyclopentadienyl or a substituted cyclopentadienyl group, each Cp being the same or different, M is a Group III, IV, V or VI metal, R is a hydride, a halogen, an amide or a hydrocarbyl radical, each R being the same or different, except only one R is a hydride and p is from 1 to 4;
Claim 12
Dependent Claim
105 words
A process for preparing a catalyst comprising: a) mixing a Lewis acid with a neutral metallocene compound; and b) allowing contact between the ionizing ionic compound and the neutral metallocene cpmpound; wherein the neutral derivative of a metallocene is of the general formula: Cp₂MR p wherein Cp is a cyclopentadienyl or a substituted cyclopentadienyl group, each Cp being the same or different, M is a Group III, IV, V or VI metal, R is a hydride, a halogen, an amide or a hydrocarbyl radical, each R being the same or different, except only one R is a hydride and p is from 1 to 4;
Claim 13
Dependent Claim
12 words
A process as recited in Claim 10 wherein the olefin is propylene.
Claim 14
Dependent Claim
36 words
A process as recited in Claim 10 wherein R is a hydrocarbyl radical selected from the group consisting of an alkyl, an aryl, an alkenyl, an alkylaryl and an arylalkyl having up to 20 carbon atoms.
Claim 15
Dependent Claim
25 words
A process as recited in Claim 10 wherein the M is A Group IV metal selected from the group consisting of titanium, zirconium and hafnium.
Claim 16
Dependent Claim
12 words
A process as recited in Claim 13 wherein the M is zirconium.
Claim 17
Dependent Claim
27 words
A process as recited in Claim 14 wherein the neutral derivative of a metallocene is chosen from the group consisting of ethylenebis(indenyl)zirconium dimethyl and isopropylidene (cyclopentadienyl-1-fluorenyl)zirconium dimethyl.
Claim 18
Dependent Claim
26 words
A process as recited in Claim 10 wherein the Lewis acid is chosen from the group consisting of all Lewis acids containing boron and magnesium chloride.
Claim 19
Dependent Claim
13 words
A catalyst as recited in Claim 16 wherein the Lewis acid is tris(pentafluorophenyl)boron.
Claim 20
Dependent Claim
142 words
A process for polymerization of olefins comprising: a) mixing an aluminum alkyl with an olefin; b) mixing a neutral metallocene compound with a Lewis acid; c) mixing the metallocene-Lewis acid mixture with the aluminum alkyl-olefin mixture. wherein the aluminum alkyl is of the general formula AlR₃ where R is a halogen, oxygen, hydride, alkyl, alkoxy or aryl, each R being the same of different and at least one R is an alkyl; and wherein the neutral metallocene compound is of the general formula: CP₂MR p wherein Cp is cyclopentadienyl or substituted cyclopentadienyl, each Cp being the same or different, M is a Group III, IV, V or VI metal, R is a hydride, a halogen, an amide or a hydrocarbyl radical, each R being the same or different, except only one R is a hydride and p is from 1 to 4.
Claim 21
Dependent Claim
142 words
A process for polymerization of olefins comprising: a) mixing an aluminum alkyl with an olefin; b) mixing a neutral metallocene compound with a Lewis acid; c) mixing the metallocene-Lewis acid mixture with the aluminum alkyl-olefin mixture. wherein the aluminum alkyl is of the general formula AlR₃ where R is a halogen, oxygen, hydride, alkyl, alkoxy or aryl, each R being the same of different and at least one R is an alkyl; and wherein the neutral metallocene compound is of the general formula: CP₂MR p wherein Cp is cyclopentadienyl or substituted cyclopentadienyl, each Cp being the same or different, M is a Group III, IV, V or VI metal, R is a hydride, a halogen, an amide or a hydrocarbyl radical, each R being the same or different, except only one R is a hydride and p is from 1 to 4.
Claim 22
Dependent Claim
27 words
A process as recited in Claim 18 wherein R is an alkyl or alkoxy of up to six carbons or an aryl of up to 10 carbons.
Claim 23
Dependent Claim
20 words
A process as recited in Claim 19 wherein the molar ratio for metallocene:Lewis acid:aluminum alkyl ranges from 0.01:1:0.1 to 5:1:350.
Claim 24
Dependent Claim
20 words
A process as recited in Claim 20 wherein the molar ratio for metallocene:Lewis acid:aluminum alkyl ranges from 0.5:1:05 to 4:1:25.
Claim 25
Dependent Claim
17 words
A process as recited in Claim 21 wherein the molar ratio for metallocene:Lewis acid:aluminum alkyl is 0.02:1:1.
Claim 26
Dependent Claim
17 words
A process as recited in Claim 21 wherein the molar ratio for metallocene:Lewis acid:aluminum alkyl is 0.01:1:1.
Claim 27
Dependent Claim
21 words
A process as recited in Claim 16 wherein the aluminum alkyl is selected from the group consisting of triethylaluminum and trimethylaluminum.
Claim 28
Dependent Claim
13 words
A process as recited in Claim 21 wherein the aluminum alkyl is triethylaluminum.
Claim 29
Dependent Claim
26 words
A catalyst as recited in Claim 18 wherein the Lewis acid is chosen from the group consisting of all Lewis acids containing boron and magnesium chloride.
Claim 30
Dependent Claim
13 words
A catalyst as recited in Claim 23 wherein the Lewis acid is tris(pentafluorophenyl)boron.
References Cited (Backward Citations)
No citation records indexed.
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