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US4078131A Expired / Lapsed US ⏱️ 0.0 years remaining

Ept elastomers

Assignee: Compagnie Generale des Etablissements Michelin SCA
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Filing: 1976-08-06
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Granted: 1978-03-07
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Expires: 1996-08-06
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Abstract

Abstract Elastomers of the ethylene-propylene-termonomer type. In accordance with the invention these elastomers have a bimodal distribution of the molecular weights, each principal fraction having, on the one hand, a wide distribution of the molecular weights and a monomer composition which is different from that of the other principal fraction, but, on the other hand, a distribution of composition as a function of the molecular weights which is very narrow around the average value contemplated for the fraction.

Inventors

  • 👤 Yves de Zarauz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 16:48
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/16; C08F210/18

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 268 words
Elastomers of the ethylene-propylene-termonomer type consisting essentially of (a) a first principal fraction of low molecular weight comprising from about 30% to about 85% by weight (referred to the total weight of elastomers) of molecular fractions having: an intrinsic viscosity distribution extending from about 0.2 to about 3, an average intrinsic viscosity between about 0.8 and about 1.5, an average propylene content of between about 36% and about 52% by weight, and a termonomer content of between about 0% and about 5% by weight; (b) a second principal fraction of high molecular weight comprising from about 70% to about 15% by weight (referred to the total weight of elastomers) of molecular fractions having: an intrinsic viscosity distribution extending from about 3 to about 15, an average intrinsic viscosity between about 3.5 and about 7, an average propylene content of between about 26% and about 32% by weight, and a termonomer content of between about 0% and about 5% by weight; and (c) less than about 5% by weight (referred to the total weight of elastomers) of molecular fractions having a propylene content of less than about 25% by weight and a crystallization temperature of more than 35° C.; said termonomer being a linear nonconjugated diene; said elastomers having a wide bimodal distribution of the molecular weights; and each of the two said principal fractions having a wide distribution of the molecular weights, a propylene and ethylene content which is different from that of the other principal fraction, and a distribution of propylene and ethylene which is very narrow (± 2%) around the average value contemplated for the fraction.
Claim 2
Dependent Claim 268 words
Elastomers of the ethylene-propylene-termonomer type consisting essentially of (a) a first principal fraction of low molecular weight comprising from about 30% to about 85% by weight (referred to the total weight of elastomers) of molecular fractions having: an intrinsic viscosity distribution extending from about 0.2 to about 3, an average intrinsic viscosity between about 0.8 and about 1.5, an average propylene content of between about 36% and about 52% by weight, and a termonomer content of between about 0% and about 5% by weight; (b) a second principal fraction of high molecular weight comprising from about 70% to about 15% by weight (referred to the total weight of elastomers) of molecular fractions having: an intrinsic viscosity distribution extending from about 3 to about 15, an average intrinsic viscosity between about 3.5 and about 7, an average propylene content of between about 26% and about 32% by weight, and a termonomer content of between about 0% and about 5% by weight; and (c) less than about 5% by weight (referred to the total weight of elastomers) of molecular fractions having a propylene content of less than about 25% by weight and a crystallization temperature of more than 35° C.; said termonomer being a linear nonconjugated diene; said elastomers having a wide bimodal distribution of the molecular weights; and each of the two said principal fractions having a wide distribution of the molecular weights, a propylene and ethylene content which is different from that of the other principal fraction, and a distribution of propylene and ethylene which is very narrow (± 2%) around the average value contemplated for the fraction.
Claim 3
Dependent Claim 37 words
Elastomers according to claim 1 wherein the amount of molecular fractions having a propylene content of less than about 25% by weight is less than about 3% by weight (referred to the total weight of the elastomers).
Claim 4
Dependent Claim 10 words
Elastomers according to claim 1 wherein the termonomer is hexadiene-1,4.
Claim 5
Dependent Claim 25 words
Vulcanizable mixes having an improved compromise between their raw adhesive power and their raw cohesion comprising as the principal component elastomers according to claim 1.
Claim 6
Dependent Claim 15 words
Vulcanizable mixes according to claim 4 which are free of any adhesive or cohesion agent.
Claim 7
Dependent Claim 17 words
Unvulcanized rubber articles which are formed in whole or in part of elastomers according to claim 1.
Claim 8
Dependent Claim 17 words
Vulcanized rubber articles which are formed in whole or in part of elastomers according to claim 1.

References Cited (Backward Citations)

US3718632A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-06 1981-09-05 1982-03-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-06 1985-09-05 1986-03-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-06 1989-09-05 1990-03-07 $7700.00 Window Closed / Lapsed

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