US4078131A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Ept elastomers
Assignee: Compagnie Generale des Etablissements Michelin SCA
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Filing: 1976-08-06
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Granted: 1978-03-07
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Expires: 1996-08-06
Abstract
Abstract Elastomers of the ethylene-propylene-termonomer type. In accordance with the invention these elastomers have a bimodal distribution of the molecular weights, each principal fraction having, on the one hand, a wide distribution of the molecular weights and a monomer composition which is different from that of the other principal fraction, but, on the other hand, a distribution of composition as a function of the molecular weights which is very narrow around the average value contemplated for the fraction.
Inventors
- 👤 Yves de Zarauz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 16:48
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/16; C08F210/18
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
268 words
Elastomers of the ethylene-propylene-termonomer type consisting essentially of (a) a first principal fraction of low molecular weight comprising from about 30% to about 85% by weight (referred to the total weight of elastomers) of molecular fractions having: an intrinsic viscosity distribution extending from about 0.2 to about 3, an average intrinsic viscosity between about 0.8 and about 1.5, an average propylene content of between about 36% and about 52% by weight, and a termonomer content of between about 0% and about 5% by weight; (b) a second principal fraction of high molecular weight comprising from about 70% to about 15% by weight (referred to the total weight of elastomers) of molecular fractions having: an intrinsic viscosity distribution extending from about 3 to about 15, an average intrinsic viscosity between about 3.5 and about 7, an average propylene content of between about 26% and about 32% by weight, and a termonomer content of between about 0% and about 5% by weight; and (c) less than about 5% by weight (referred to the total weight of elastomers) of molecular fractions having a propylene content of less than about 25% by weight and a crystallization temperature of more than 35° C.; said termonomer being a linear nonconjugated diene; said elastomers having a wide bimodal distribution of the molecular weights; and each of the two said principal fractions having a wide distribution of the molecular weights, a propylene and ethylene content which is different from that of the other principal fraction, and a distribution of propylene and ethylene which is very narrow (± 2%) around the average value contemplated for the fraction.
Claim 2
Dependent Claim
268 words
Elastomers of the ethylene-propylene-termonomer type consisting essentially of (a) a first principal fraction of low molecular weight comprising from about 30% to about 85% by weight (referred to the total weight of elastomers) of molecular fractions having: an intrinsic viscosity distribution extending from about 0.2 to about 3, an average intrinsic viscosity between about 0.8 and about 1.5, an average propylene content of between about 36% and about 52% by weight, and a termonomer content of between about 0% and about 5% by weight; (b) a second principal fraction of high molecular weight comprising from about 70% to about 15% by weight (referred to the total weight of elastomers) of molecular fractions having: an intrinsic viscosity distribution extending from about 3 to about 15, an average intrinsic viscosity between about 3.5 and about 7, an average propylene content of between about 26% and about 32% by weight, and a termonomer content of between about 0% and about 5% by weight; and (c) less than about 5% by weight (referred to the total weight of elastomers) of molecular fractions having a propylene content of less than about 25% by weight and a crystallization temperature of more than 35° C.; said termonomer being a linear nonconjugated diene; said elastomers having a wide bimodal distribution of the molecular weights; and each of the two said principal fractions having a wide distribution of the molecular weights, a propylene and ethylene content which is different from that of the other principal fraction, and a distribution of propylene and ethylene which is very narrow (± 2%) around the average value contemplated for the fraction.
Claim 3
Dependent Claim
37 words
Elastomers according to claim 1 wherein the amount of molecular fractions having a propylene content of less than about 25% by weight is less than about 3% by weight (referred to the total weight of the elastomers).
Claim 4
Dependent Claim
10 words
Elastomers according to claim 1 wherein the termonomer is hexadiene-1,4.
Claim 5
Dependent Claim
25 words
Vulcanizable mixes having an improved compromise between their raw adhesive power and their raw cohesion comprising as the principal component elastomers according to claim 1.
Claim 6
Dependent Claim
15 words
Vulcanizable mixes according to claim 4 which are free of any adhesive or cohesion agent.
Claim 7
Dependent Claim
17 words
Unvulcanized rubber articles which are formed in whole or in part of elastomers according to claim 1.
Claim 8
Dependent Claim
17 words
Vulcanized rubber articles which are formed in whole or in part of elastomers according to claim 1.
References Cited (Backward Citations)
US3718632A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-06 | 1981-09-05 | 1982-03-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-06 | 1985-09-05 | 1986-03-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-06 | 1989-09-05 | 1990-03-07 | $7700.00 | Window Closed / Lapsed |