US5738818A — Compression/injection molding of polymer-derived …

Claim 1

Independent Claim 231 words

A method of making a fiber reinforced ceramic matrix composite (FRCMC) part comprising the steps of: (a) injecting a quantity of bulk molding compound comprising a pre-ceramic resin and fibers into a mold having a cavity with walls which form the exterior surfaces of the FRCMC part being molded and at least one resin outlet port connecting the mold cavity to the exterior of the mold, wherein the quantity of said fibers injected corresponds to the maximum percent by volume of fibers capable of being packed within the mold cavity, and the quantity of pre-ceramic resin injected exceeds that necessary to fill the mold cavity in conjunction with the fibers and is sufficient to cause the fibers to flow with the resin and thereafter pack together within the mold cavity, and wherein excess resin exceeding that needed in conjunction with the fibers to fill the mold cavity, flows through the packed fibers and is expelled through the at least one resin outlet port; (b) heating the mold at a temperature and for a time associated with the pre-ceramic resin which polymerizes the resin remaining in the mold cavity to form a fiber-reinforced polymer composite structure; (c) removing the polymerized composite structure from the mold; and (d) heating the polymerized composite structure at a temperature and for a time associated with the polymerized resin which pyrolizes it to form a FRCMC structure.

Claim 2

Independent Claim 231 words

A method of making a fiber reinforced ceramic matrix composite (FRCMC) part comprising the steps of: (a) injecting a quantity of bulk molding compound comprising a pre-ceramic resin and fibers into a mold having a cavity with walls which form the exterior surfaces of the FRCMC part being molded and at least one resin outlet port connecting the mold cavity to the exterior of the mold, wherein the quantity of said fibers injected corresponds to the maximum percent by volume of fibers capable of being packed within the mold cavity, and the quantity of pre-ceramic resin injected exceeds that necessary to fill the mold cavity in conjunction with the fibers and is sufficient to cause the fibers to flow with the resin and thereafter pack together within the mold cavity, and wherein excess resin exceeding that needed in conjunction with the fibers to fill the mold cavity, flows through the packed fibers and is expelled through the at least one resin outlet port; (b) heating the mold at a temperature and for a time associated with the pre-ceramic resin which polymerizes the resin remaining in the mold cavity to form a fiber-reinforced polymer composite structure; (c) removing the polymerized composite structure from the mold; and (d) heating the polymerized composite structure at a temperature and for a time associated with the polymerized resin which pyrolizes it to form a FRCMC structure.

Claim 3

Dependent Claim 48 words

The method of claim 1, wherein the viscosity of the pre-ceramic resin is chosen such that it is high enough to ensure the fibers flow therewith inside the cavity of the mold, but low enough to ensure the resin readily flows through the fibers once packed into position.

Claim 4

Dependent Claim 18 words

The method of claim 2, wherein the chosen viscosity of the pre-ceramic resin is greater for longer fibers.

Claim 5

Dependent Claim 41 words

The method of claim 3, wherein said fibers are approximately the same length, said fiber length being with a range of about 0.125 inch to 12 inches, and wherein the viscosity of the pre-ceramic resin is between 5000 and 30,000 centipoise.

Claim 6

Dependent Claim 36 words

The method of claim 1, wherein each resin outlet port has a cross-sectional area small enough to substantially ensure the fibers cannot flow through the port, yet large enough to allow the flow of resin therethrough.

Claim 7

Dependent Claim 35 words

The method of claim 1 wherein the bulk molding compound further comprises a quantity of filler material which corresponds to the percent by volume of filler material desired to be dispersed throughout the FRCMC part.

Claim 8

Dependent Claim 49 words

The method of claim 6, wherein the maximum percent by volume of fibers capable of being dispersed throughout the FRCMC part is between about 15 and 50 percent dependent on the length of the fibers employed, the shape of the part being molded, and the quantity of filler material.

Claim 9

Dependent Claim 88 words

The method of claim 1, further comprising the steps of: (e) after the completion of step (d), immersing the FRCMC part containing pores formed during step (d), into a bath of a pre-ceramic resin to fill the pores; (f) heating the FRCMC part at a temperature and for a time associated with the resin filling said pores so as to transform it to a ceramic material; (g) repeating steps (e) and (f) until the pore density within the FRCMC part is less than a prescribed percentage by volume.

Claim 10

Dependent Claim 12 words

The method of claim 8, wherein the resin has a water-like viscosity.

Claim 11

Dependent Claim 28 words

The method of claim 8, wherein step (f) further comprises the step of placing the FRCMC part in a vacuum environment to facilitate the filling of the pores.

Claim 12

Dependent Claim 28 words

The method of claim 8, wherein the prescribed percentage by volume of the pore density of the FRCMC part is such that the part exhibits a repeatable strength.

Claim 13

Dependent Claim 69 words

The method of claim 1 wherein said at least one resin outlet port comprises a first outlet port set and said bulk molding compound is input into the cavity of the mold through at least one sprue channel, and wherein each outlet port of said first set is disposed at a location in the cavity of the mold which is as far away from each sprue channel as possible.

Claim 14

Dependent Claim 54 words

The method of claim 12 wherein said mold comprises additional resin outlet port sets each having at least one resin outlet port, each one of the additional port sets being disposed at a different location in the cavity of the mold between the first set of ports and the at least one sprue channel.

Claim 15

Dependent Claim 38 words

The method of claim 13 wherein each of said resin outlet port sets is capable of being opened so as to allow the flow of resin therethrough, or closed so as to prevent the flow of resin therethrough.

Claim 16

Dependent Claim 88 words

The method of claim 14 wherein step (a) of claim 1 further comprises the steps of: initially closing all the resin outlet ports associated with every outlet port set with the exception of the first set wherein each of its ports is opened; opening the resin outlet ports of a next set of outlet ports whenever said fiber has packed into the cavity of the mold from the locations of the first set of outlet ports to a point just adjacent to the next set of outlet ports.

Claim 17

Dependent Claim 34 words

The method of claim 15, further comprising the step of closing all open ports in other sets of resin outlet ports when opening the resin outlet ports of the next set of outlet ports.

Claim 18

Independent Claim 409 words

A method of making a fiber reinforced ceramic matrix composite (FRCMC) part comprising the steps of: (a) injecting a quantity of bulk molding compound comprising a pre-ceramic resin and fibers into a mold having a cavity with walls which form the exterior surfaces of the FRCMC part being molded and at least one resin outlet port connecting the cavity of the mold to the exterior of the mold, wherein the quantity of said fibers injected corresponds to the maximum percent by volume of fibers capable of being packed within a first portion of the the mold cavity and the quantity of pre-ceramic resin injected exceeds that necessary to fill the mold cavity in conjunction with the fibers and is sufficient to cause the fibers to flow with the resin and thereafter pack together within the first portion of the mold cavity, and wherein excess resin exceeding that needed in conjunction with the fibers to fill the mold cavity, flows through the packed fibers and is expelled through the at least one resin outlet port; (b) sequentially injecting at least one additional quantity of bulk molding compound into the mold, wherein each additional quantity of bulk molding compound comprises an additional amount of the pre-ceramic resin and an additional amount of fibers, wherein the quantity of each additional amount of fibers injected corresponds to the maximum percent by volume of fibers capable of being packed within a respective additional portion of the mold cavity located adjacent a previous filled portion of the mold cavity, and wherein the quantity of each additional amount of pre-ceramic resin injected exceeds that necessary to fill the mold cavity in conjunction with the fibers and is sufficient to cause the associated additional amount of fibers to flow with the resin and thereafter pack together within the corresponding additional portion of the mold cavity, and wherein excess resin exceeding that needed in conjunction with all the fibers to fill the mold cavity, flows through the packed fibers and is expelled through the at least one resin outlet port; (b) heating the mold at a temperature and for a time associated with the pre-ceramic resin which polymerizes the resin remaining in the mold cavity to form a fiber-reinforced polymer composite structure; (c) removing the polymerized composite structure from the mold; and (d) heating the polymerized composite structure at a temperature and for a time associated with the polymerized resin which pyrolizes it to form a FRCMC structure.

Claim 19

Independent Claim 409 words

A method of making a fiber reinforced ceramic matrix composite (FRCMC) part comprising the steps of: (a) injecting a quantity of bulk molding compound comprising a pre-ceramic resin and fibers into a mold having a cavity with walls which form the exterior surfaces of the FRCMC part being molded and at least one resin outlet port connecting the cavity of the mold to the exterior of the mold, wherein the quantity of said fibers injected corresponds to the maximum percent by volume of fibers capable of being packed within a first portion of the the mold cavity and the quantity of pre-ceramic resin injected exceeds that necessary to fill the mold cavity in conjunction with the fibers and is sufficient to cause the fibers to flow with the resin and thereafter pack together within the first portion of the mold cavity, and wherein excess resin exceeding that needed in conjunction with the fibers to fill the mold cavity, flows through the packed fibers and is expelled through the at least one resin outlet port; (b) sequentially injecting at least one additional quantity of bulk molding compound into the mold, wherein each additional quantity of bulk molding compound comprises an additional amount of the pre-ceramic resin and an additional amount of fibers, wherein the quantity of each additional amount of fibers injected corresponds to the maximum percent by volume of fibers capable of being packed within a respective additional portion of the mold cavity located adjacent a previous filled portion of the mold cavity, and wherein the quantity of each additional amount of pre-ceramic resin injected exceeds that necessary to fill the mold cavity in conjunction with the fibers and is sufficient to cause the associated additional amount of fibers to flow with the resin and thereafter pack together within the corresponding additional portion of the mold cavity, and wherein excess resin exceeding that needed in conjunction with all the fibers to fill the mold cavity, flows through the packed fibers and is expelled through the at least one resin outlet port; (b) heating the mold at a temperature and for a time associated with the pre-ceramic resin which polymerizes the resin remaining in the mold cavity to form a fiber-reinforced polymer composite structure; (c) removing the polymerized composite structure from the mold; and (d) heating the polymerized composite structure at a temperature and for a time associated with the polymerized resin which pyrolizes it to form a FRCMC structure.

Claim 20

Dependent Claim 48 words

The method of claim 17, wherein the viscosity of the pre-ceramic resin is chosen such that it is high enough to ensure the fibers flow therewith inside the cavity of the mold, but low enough to ensure the resin readily flows through the fibers once packed into position.

Claim 21

Dependent Claim 38 words

The method of claim 17, wherein each quantity of bulk molding compound further comprises a quantity of filler material which corresponds to the percent by volume of filler material desired within an associated portion of the FRCMC part.

Claim 22

Dependent Claim 71 words

The method of claim 17 wherein said at least one resin outlet port comprises a first outlet port set and each quantity of bulk molding compound is input into the cavity of the mold through at least one sprue channel, and wherein each outlet port of said first set is disposed at a location in the cavity of the mold which is as far away from each sprue channel as possible.

Claim 23

Dependent Claim 78 words

The method of claim 20 wherein said mold comprises additional resin outlet port sets each having at least one resin outlet port, each one of the additional port sets being disposed at a different location in the cavity of the mold between the first set of ports and the at least one sprue channel, said different locations corresponding to the end of one of said portions of the mold cavity furthest from the at least one sprue channel.

Claim 24

Dependent Claim 38 words

The method of claim 21 wherein each of said resin outlet port sets is capable of being opened so as to allow the flow of resin therethrough, or closed so as to prevent the flow of resin therethrough.

Claim 25

Dependent Claim 87 words

The method of claim 22 wherein step (a) of claim 17 further comprises the steps of: initially closing all the resin outlet ports associated with every outlet port set with the exception of the first set wherein each of its ports is opened; opening the resin outlet ports of a closed set of outlet ports whenever fiber has packed into the cavity of the mold from the locations of the first set of outlet ports to a point just adjacent to the closed set of outlet ports.

Claim 26

Dependent Claim 34 words

The method of claim 23, further comprising the step of closing all open ports in other sets of resin outlet ports when opening the resin outlet ports of the closed set of outlet ports.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	2001-04-13	2001-10-13	2002-04-14	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	2005-04-13	2005-10-13	2006-04-14	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	2009-04-13	2009-10-13	2010-04-14	$7700.00	Window Closed / Lapsed

Compression/injection molding of polymer-derived fiber reinforced ceramic matrix composite materials

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