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US5683587A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for treating industrial wastes

Assignee: Individual
•
Filing: 1995-12-29
•
Granted: 1997-11-04
•
Expires: 2015-12-29
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Abstract

Abstract Water to be utilized is reacted with soda ash and lime to produce a less corrosive and foulant water. Reaction sludges are fed to a desulfurization unit, where SO x , NO x and CO 2 abatement occurs; other industrial waste sludges and/or waters and/or gases can also be utilized in such connection. FIG. 1 is one of the possible process schemes of the present invention.

Inventors

  • 👤 Marcello Ferrara
  • 👤 Maria Gabriella Scopelliti

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 15:16
CPC Classifications
C; C02; C02F; C02F5/00; B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/60; B01D53/62; C02F1/00; C02F1/50; C02F1/52; C02F1/5236; C02F1/5263; C02F1/54; C02F1/66; B01D2251/00; B01D2251/40; B01D2251/402; B01D2251/404; B01D2259/00; B01D2259/80; C02F1/02; C02F1/04; C02F1/16; C02F11/00; C02F11/12; C02F2103/00; C02F2103/02; C02F2103/023; C02F2103/08; Y; Y02; Y02A; Y02A20/00; Y02A20/124; Y02A50/00; Y02A50/20; Y02C; Y02C20/00; Y02C20/40; Y10; Y10S; Y10S210/00; Y10S210/918; Y10S210/919; Y10S423/00; Y10S423/08

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 134 words
A process for treating wastes comprising the steps of: producing a waste sludge containing calcium carbonate and magnesium hydroxide by reaction of soda ash and lime with process water; feeding a hot waste gas at a temperature of from about 200° C. to 1000° C. containing 50 to 50000 ppm of pollutants selected from the group consisting of SO x , NO x and CO 2 to a scrubber apparatus containing an adsorbent slurry comprising said waste sludge for removing SO x , NO x and CO 2 ; separating the waste sludge to obtain a dry sludge; injecting the dry sludge into a reaction chamber; reacting a gaseous stream containing said pollutants in the reaction chamber with said dry sludge to substantially reduce sulfur oxide compounds and nitrogen oxides in said reaction chamber.
Claim 2
Dependent Claim 134 words
A process for treating wastes comprising the steps of: producing a waste sludge containing calcium carbonate and magnesium hydroxide by reaction of soda ash and lime with process water; feeding a hot waste gas at a temperature of from about 200° C. to 1000° C. containing 50 to 50000 ppm of pollutants selected from the group consisting of SO x , NO x and CO 2 to a scrubber apparatus containing an adsorbent slurry comprising said waste sludge for removing SO x , NO x and CO 2 ; separating the waste sludge to obtain a dry sludge; injecting the dry sludge into a reaction chamber; reacting a gaseous stream containing said pollutants in the reaction chamber with said dry sludge to substantially reduce sulfur oxide compounds and nitrogen oxides in said reaction chamber.
Claim 3
Dependent Claim 15 words
The process according to claim 1 where the waste sludge is derived from waste water.
Claim 4
Dependent Claim 13 words
The process according to claim 1 where the reaction chamber comprises a boiler.
Claim 5
Dependent Claim 19 words
The process according to claim 3 further comprising the step of adding ammonia to the pollutants in the scrubber.
Claim 6
Dependent Claim 13 words
The process according to claim 1 where the waste sludge has a pH>7.
Claim 7
Dependent Claim 29 words
The process according to claim 5 further comprising the step of adding additive compounds selected from the group consisting of corrosion inhibitors, antifouling agents, antiscaling agents, and biocide agents.
Claim 8
Dependent Claim 41 words
The process according to claim 6 where said additive compounds include Na 2 CO 3 , NaHCO 3 , Ca(OH) 2 , NaOH, Zn, water soluble organic polymers, phosphorus compounds, chromates, nitrates, silicates, molybdates, azoles, chlorinated compounds, ammonium salts and amines.
Claim 9
Dependent Claim 56 words
The process according to claim 7 further including the step of adding to the reaction chamber a sorbent compound selected from the group consisting of CaCO 3 , CaO, Ca(OH) 2 , Na 2 SO 3 , NaOH, NaCl, Na 2 CO 3 , K 2 CO 3 MgO, MgSO 4 , and Mg(OH) 2 .
Claim 10
Dependent Claim 21 words
The process according to claim 7 where the water soluble polymers are selected from the group consisting of polyacrylates and polyacrylamides.
Claim 11
Dependent Claim 40 words
The process according to claim 1 further including the step of alkalinizing the waste sludge with a compound selected from the group consisting of Na 2 CO 3 , NaHCO 3 , Ca(OH) 2 , NaOH and NH 3 .
Claim 12
Dependent Claim 25 words
The process according to claim 10 further including the step of adding lime to regenerate Na 2 SO 4 and NaOH from the waste sludge.
Claim 13
Independent Claim 114 words
A method for treating wastes comprising the steps of: producing a waste sludge containing calcium carbonate and magnesium hydroxide by reaction of soda ash and lime with process water; feeding the waste sludge to a scrubber with a waste gas mixture containing gaseous pollutants where said gaseous pollutants are in a mixture comprising 50 ppm to 50000 ppm each of SO x , NO x and CO 2 ; separating the waste sludge to obtain a dry sludge; injecting the dry sludge into a reaction chamber; reacting a gaseous stream containing said gaseous pollutants in the reaction chamber with said sludge to substantially reduce sulfur oxide compounds and nitrogen oxides in said reaction chamber.
Claim 14
Independent Claim 114 words
A method for treating wastes comprising the steps of: producing a waste sludge containing calcium carbonate and magnesium hydroxide by reaction of soda ash and lime with process water; feeding the waste sludge to a scrubber with a waste gas mixture containing gaseous pollutants where said gaseous pollutants are in a mixture comprising 50 ppm to 50000 ppm each of SO x , NO x and CO 2 ; separating the waste sludge to obtain a dry sludge; injecting the dry sludge into a reaction chamber; reacting a gaseous stream containing said gaseous pollutants in the reaction chamber with said sludge to substantially reduce sulfur oxide compounds and nitrogen oxides in said reaction chamber.
Claim 15
Dependent Claim 31 words
The method of claim 12 where the reaction chamber comprises a boiler and the waste sludge is introduced in the gaseous stream at a temperature from 200° C. to 1300° C.
Claim 16
Dependent Claim 12 words
The method of claim 12 where the waste sludge has a pH>7.
Claim 17
Dependent Claim 32 words
The method of claim 14 further comprising the step of injecting into said waste sludge additive compounds selected from the group consisting of corrosion inhibitors, antifouling agents, antiscaling agents, and biocide agents.
Claim 18
Dependent Claim 41 words
The method according to claim 15 where said additive compounds include Na 2 CO 3 , NaHCO 3 , Ca(OH) 2 , NaOH, Zn, water soluble organic polymers, phosphorus compounds, chromates, nitrates, silicates, molybdates, azoles, chlorinated compounds, ammonium salts and amines.
Claim 19
Dependent Claim 21 words
The method according to claim 16 where the water soluble polymers are selected from the group consisting of polyacrylates and polyacrylamides.
Claim 20
Dependent Claim 59 words
The method according to claim 14 further including the step of adding to the reaction chamber a sorbent compound selected from the group consisting of CaCO 3 , CaO, Ca(OH) 2 , Na 2 SO 3 , NaOH, NaCl, Na 2 CO 2 , NaCO 3 , K 2 CO 3 MgO, MgCO 2 , and Mg(OH) 2 .
Claim 21
Dependent Claim 16 words
The method according to claim 14 further comprising the step of adding ammonia into the scrubber.

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3.5 Years (Year 4) 2000-11-03 2001-05-05 2001-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-11-03 2005-05-05 2005-11-04 $3760.00 Window Closed / Lapsed
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