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Method for forming a semiconductor device in which an anti reflective layer is formed by varying the composition thereof

Assignee: Sony Corp
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Filing: 1995-04-04
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Granted: 1997-10-07
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Expires: 2015-04-04
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Abstract

Abstract A method for producing a semiconductor device in which dry etching properties are rendered compatible with satisfactory anti-reflection characteristics in far-infrared lithography. An anti-reflective layer 6 is made up of a lower anti-reflective layer 6 L of SiO X having a relatively low Si ratio and an upper anti-reflective layer 6 H of SiO X having a relatively high Si ratio. After forming a resist pattern 7, the upper anti-reflective layer 6 H and the lower anti-reflective layer 6 U are etched using the etching conditions for Si and those for SiO X , respectively. Such variation in the Si ratio along the film thickness is realized by controlling the CVD film-forming conditions or Si + ion implantation. Since the upper anti-reflective layer 6 H has a refractive index higher than that of the lower anti-reflective layer 6 L of SiO X , the standing wave suppression effect is improved. Since the films 6 U , 6 L are etched under respective optimum conditions, shape anisotropy may be realized. Film formation is not difficult to achieve because the elementary composition of the anti-reflective layer 6 on the whole is uniform.

Inventors

  • 👤 Tetsuji Nagayama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 22:24
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/091; H; H10; H10P; H10P95/00; H10P50/00; H10P50/20; H10P50/28; H10P50/282; H10P50/283; H10P76/00; H10P76/20; H10P76/204; H10P76/2041; H10P76/2043; Y; Y10; Y10S; Y10S430/00; Y10S430/151; Y10S438/00; Y10S438/942; Y10S438/948; Y10S438/952

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 94 words
A method for producing a semiconductor device comprising: providing an anti-reflective layer presenting a variation in the composition of a constituent element along the film thickness over a semiconductor substrate, said anti-reflective layer being formed by a vapor phase deposition method and the variation in the composition being achieved by controlling the film forming atmosphere, the anti-reflective layer having a silicone-rich upper layer portion; forming a pattern resist on said anti-reflective layer; and dry-etching said anti-reflective layer under etching conditions conforming to the variation of the composition, using said pattern resist as a mask.
Claim 2
Independent Claim 94 words
A method for producing a semiconductor device comprising: providing an anti-reflective layer presenting a variation in the composition of a constituent element along the film thickness over a semiconductor substrate, said anti-reflective layer being formed by a vapor phase deposition method and the variation in the composition being achieved by controlling the film forming atmosphere, the anti-reflective layer having a silicone-rich upper layer portion; forming a pattern resist on said anti-reflective layer; and dry-etching said anti-reflective layer under etching conditions conforming to the variation of the composition, using said pattern resist as a mask.
Claim 3
Independent Claim 116 words
A method for producing a semiconductor device comprising: providing an anti-reflective layer presenting a variation in composition of a constituent element along the film thickness over a semiconductor substrate, said anti-reflective layer being formed by a vapor phase deposition method and the variation of the composition being achieved by controlling the film forming atmosphere, the anti-reflective layer being a film formed of a silicon compound and having a silicon ratio in the composition thereof which increases proceeding from its lower layer portion towards its upper layer portion; forming a pattern resist on said anti-reflective layer; and dry-etching said anti-reflective layer under conditions conforming to the variation in the composition, using said pattern resist as a mask.
Claim 4
Independent Claim 116 words
A method for producing a semiconductor device comprising: providing an anti-reflective layer presenting a variation in composition of a constituent element along the film thickness over a semiconductor substrate, said anti-reflective layer being formed by a vapor phase deposition method and the variation of the composition being achieved by controlling the film forming atmosphere, the anti-reflective layer being a film formed of a silicon compound and having a silicon ratio in the composition thereof which increases proceeding from its lower layer portion towards its upper layer portion; forming a pattern resist on said anti-reflective layer; and dry-etching said anti-reflective layer under conditions conforming to the variation in the composition, using said pattern resist as a mask.
Claim 5
Dependent Claim 35 words
The method as claimed in claim 1 or 2 wherein the anti-reflective layer has a composition so selected that its upper layer portion has a refractive index higher than that of its lower layer portion.
Claim 6
Dependent Claim 30 words
The method as claimed in claim 1 or 2 wherein the anti-reflective layer is a film formed of a silicon compound and having a composition with a variable silicon ratio.
Claim 7
Dependent Claim 39 words
The method as claimed in claim 1 or 2 wherein the anti-reflective layer is a film of a silicon compound selected from the group consisting of SiO X , SiN x and Si x O y N z .
Claim 8
Dependent Claim 51 words
The method as claimed in claim 1 or 2 wherein the anti-reflective layer is a film having a low refractive index area and a high refractive index area formed on the low refractive index area, said higher refractive index area having a refractive index higher than that of the resist film.
Claim 9
Independent Claim 103 words
A method for producing a semiconductor device comprising: providing an anti-reflective layer presenting a variation in the composition of a constituent element along the film thickness over a semiconductor substrate, said variation in the constituent element being provided by an ion implantation on a previously formed ant-reflective layer, the anti-reflective layer having a composition so selected that its upper layer portion has a refractive index that is higher than that of its lower layer portion; forming a pattern resist on said anti-reflective layer; dry-etching said anti-reflective layer under etching conditions conforming to the variation in composition, using said pattern resist as a mask.
Claim 10
Independent Claim 103 words
A method for producing a semiconductor device comprising: providing an anti-reflective layer presenting a variation in the composition of a constituent element along the film thickness over a semiconductor substrate, said variation in the constituent element being provided by an ion implantation on a previously formed ant-reflective layer, the anti-reflective layer having a composition so selected that its upper layer portion has a refractive index that is higher than that of its lower layer portion; forming a pattern resist on said anti-reflective layer; dry-etching said anti-reflective layer under etching conditions conforming to the variation in composition, using said pattern resist as a mask.
Claim 11
Dependent Claim 32 words
The method as claimed in claim 7, wherein the anti-reflective layer is a film formed of a silicon compound having the same elements but having a composition with a variable silicon ratio.
Claim 12
Independent Claim 85 words
A method for producing a semiconductor device comprising: providing an anti-reflective layer presenting a variation in the composition of a constituent element along the film thickness over a semiconductor substrate said variation in the constituent element being provided by an ion implantation on a previously formed anti-reflective layer, the anti-reflective layer having a silicon-rich upper layer portion; forming a pattern resist on said anti-reflective layer; dry-etching said anti-reflective layer under etching conditions conforming to the variation in composition using said pattern resist as a mask.
Claim 13
Independent Claim 85 words
A method for producing a semiconductor device comprising: providing an anti-reflective layer presenting a variation in the composition of a constituent element along the film thickness over a semiconductor substrate said variation in the constituent element being provided by an ion implantation on a previously formed anti-reflective layer, the anti-reflective layer having a silicon-rich upper layer portion; forming a pattern resist on said anti-reflective layer; dry-etching said anti-reflective layer under etching conditions conforming to the variation in composition using said pattern resist as a mask.
Claim 14
Dependent Claim 39 words
The method as claimed in claim 9 wherein the anti-reflective layer is a film formed of a silicon compound and having a silicon ratio in the composition thereof increased from its lower layer portion towards its upper layer portion.
Claim 15
Dependent Claim 29 words
The method as claimed in claim 7 or 9 wherein the anti-reflective layer is a film of silicon compound having the formula Si x O y N z .
Claim 16
Dependent Claim 49 words
The method as claimed in claim 7 wherein the anti-reflective layer is a film having a low refractive index area and a high refractive index area formed on the low refractive index area, said higher refractive index area having a refractive index higher than that of the resist film.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-10-06 2001-04-07 2001-10-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-10-06 2005-04-07 2005-10-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-10-06 2009-04-07 2009-10-07 $7700.00 Window Closed / Lapsed

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