Patent US5535708A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5535708A Expired / Lapsed US ⏱️ 0.0 years remaining

Reduction of nitrogen oxides emissions from diesel engines

Assignee: Platinum Plus Inc
•
Filing: 1994-08-29
•
Granted: 1996-07-16
•
Expires: 2014-08-29
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract The present invention relates to a process for reducing nitrogen oxides emissions from a diesel engine, which comprises preparing an emulsion of an aqueous urea solution in diesel fuel, and supplying said emulsion to a diesel engine for combusting therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.

Inventors

  • 👤 James M. Valentine

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 08:51
CPC Classifications
C; C10; C10L; C10L10/00; C10L10/02; B; B01; B01F; B01F23/00; B01F23/40; B01F23/41; C10L1/00; C10L1/10; F; F02; F02B; F02B47/00; F02B47/04; F02M; F02M25/00; F02M25/022; F02M25/0221; F02M25/0224; F02M25/0228; B01F2101/00; B01F2101/505; C10L1/12; C10L1/1216; C10L1/1266; C10L1/14; C10L1/22; C10L1/222; C10L1/2227; C10L1/224; C10L1/234; C10L1/238; C10L1/2381; C10L1/30; C10L1/305; F01; F01N; F01N2430/00; F01N2430/04; F01N3/00; F01N3/02; F01N3/021; F01N3/023; F02B3/00; F02B3/06; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 160 words
A process for reducing nitrogen oxides emissions from a diesel engine comprising forming an emulsion of an aqueous solution in diesel fuel which comprises (a) about 5% to about 70% solution by weight of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these, and (b) a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese, wherein at least about 70% of the water droplets in the emulsion have a particle size below about 5 microns Sauter mean diameter, and supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Claim 2
Dependent Claim 160 words
A process for reducing nitrogen oxides emissions from a diesel engine comprising forming an emulsion of an aqueous solution in diesel fuel which comprises (a) about 5% to about 70% solution by weight of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these, and (b) a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese, wherein at least about 70% of the water droplets in the emulsion have a particle size below about 5 microns Sauter mean diameter, and supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Claim 3
Dependent Claim 19 words
The process of claim 1, wherein said aqueous urea solution comprises about 5% to about 35% urea by weight.
Claim 4
Dependent Claim 25 words
The process of claim 1, wherein at least about 85% of the water droplets have a particle size below about 5 microns Sauter mean diameter.
Claim 5
Dependent Claim 27 words
The process of claim 1, wherein said catalyst comprises a water soluble or water dispersible platinum group metal composition present in the aqueous phase of said emulsion.
Claim 6
Dependent Claim 32 words
The process of claim 1, wherein said catalyst comprises a fuel soluble platinum group metal composition present in the fuel phase of said emulsion or in said emulsion after it is formed.
Claim 7
Dependent Claim 143 words
A process for reducing nitrogen oxides emissions from a diesel engine comprising: a. preparing a solution of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these in water to form an aqueous solution; b. emulsifying said aqueous solution with diesel fuel to form an emulsion; and c. incorporating into the emulsion a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese; d. supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Claim 8
Dependent Claim 143 words
A process for reducing nitrogen oxides emissions from a diesel engine comprising: a. preparing a solution of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these in water to form an aqueous solution; b. emulsifying said aqueous solution with diesel fuel to form an emulsion; and c. incorporating into the emulsion a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese; d. supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Claim 9
Dependent Claim 13 words
The process of claim 6, wherein said urea solution further comprises an emulsifier.
Claim 10
Dependent Claim 19 words
The process of claim 7, wherein said emulsifier is selected from the group consisting of alkanolamides and phenolic surfactants.
Claim 11
Dependent Claim 18 words
The process of claim 6, wherein said aqueous solution comprises about 5% to about 35% urea by weight.
Claim 12
Dependent Claim 18 words
The process of claim 6, wherein said emulsion comprises about 15% to about 45% aqueous solution by weight.
Claim 13
Dependent Claim 49 words
The process of claim 6, wherein said aqueous solution is prepared by first forming a concentrated solution of urea comprising about 30% to about 50% urea by weight and then diluting said concentrated solution with water until the concentration of urea is about 5% to about 25% by weight.
Claim 14
Dependent Claim 27 words
The process of claim 6, wherein said catalyst comprises a water soluble or water dispersible platinum group metal composition present in the aqueous phase of said emulsion.
Claim 15
Dependent Claim 29 words
The process of claim 6, wherein said catalyst comprises a fuel soluble platinum group metal composition present in the fuel phase or in said emulsion after it is formed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-07-16 2000-01-15 2000-07-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-07-16 2004-01-15 2004-07-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-07-16 2008-01-15 2008-07-16 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag