Patent US5535708A successfully refreshed from Google Patents.
US5535708A
Expired / Lapsed
US
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Reduction of nitrogen oxides emissions from diesel engines
Assignee: Platinum Plus Inc
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Filing: 1994-08-29
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Granted: 1996-07-16
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Expires: 2014-08-29
Abstract
Abstract The present invention relates to a process for reducing nitrogen oxides emissions from a diesel engine, which comprises preparing an emulsion of an aqueous urea solution in diesel fuel, and supplying said emulsion to a diesel engine for combusting therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Inventors
- 👤 James M. Valentine
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 08:51
CPC Classifications
C; C10; C10L; C10L10/00; C10L10/02; B; B01; B01F; B01F23/00; B01F23/40; B01F23/41; C10L1/00; C10L1/10; F; F02; F02B; F02B47/00; F02B47/04; F02M; F02M25/00; F02M25/022; F02M25/0221; F02M25/0224; F02M25/0228; B01F2101/00; B01F2101/505; C10L1/12; C10L1/1216; C10L1/1266; C10L1/14; C10L1/22; C10L1/222; C10L1/2227; C10L1/224; C10L1/234; C10L1/238; C10L1/2381; C10L1/30; C10L1/305; F01; F01N; F01N2430/00; F01N2430/04; F01N3/00; F01N3/02; F01N3/021; F01N3/023; F02B3/00; F02B3/06; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
160 words
A process for reducing nitrogen oxides emissions from a diesel engine comprising forming an emulsion of an aqueous solution in diesel fuel which comprises (a) about 5% to about 70% solution by weight of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these, and (b) a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese, wherein at least about 70% of the water droplets in the emulsion have a particle size below about 5 microns Sauter mean diameter, and supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Claim 2
Dependent Claim
160 words
A process for reducing nitrogen oxides emissions from a diesel engine comprising forming an emulsion of an aqueous solution in diesel fuel which comprises (a) about 5% to about 70% solution by weight of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these, and (b) a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese, wherein at least about 70% of the water droplets in the emulsion have a particle size below about 5 microns Sauter mean diameter, and supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Claim 3
Dependent Claim
19 words
The process of claim 1, wherein said aqueous urea solution comprises about 5% to about 35% urea by weight.
Claim 4
Dependent Claim
25 words
The process of claim 1, wherein at least about 85% of the water droplets have a particle size below about 5 microns Sauter mean diameter.
Claim 5
Dependent Claim
27 words
The process of claim 1, wherein said catalyst comprises a water soluble or water dispersible platinum group metal composition present in the aqueous phase of said emulsion.
Claim 6
Dependent Claim
32 words
The process of claim 1, wherein said catalyst comprises a fuel soluble platinum group metal composition present in the fuel phase of said emulsion or in said emulsion after it is formed.
Claim 7
Dependent Claim
143 words
A process for reducing nitrogen oxides emissions from a diesel engine comprising: a. preparing a solution of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these in water to form an aqueous solution; b. emulsifying said aqueous solution with diesel fuel to form an emulsion; and c. incorporating into the emulsion a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese; d. supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Claim 8
Dependent Claim
143 words
A process for reducing nitrogen oxides emissions from a diesel engine comprising: a. preparing a solution of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these in water to form an aqueous solution; b. emulsifying said aqueous solution with diesel fuel to form an emulsion; and c. incorporating into the emulsion a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese; d. supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.
Claim 9
Dependent Claim
13 words
The process of claim 6, wherein said urea solution further comprises an emulsifier.
Claim 10
Dependent Claim
19 words
The process of claim 7, wherein said emulsifier is selected from the group consisting of alkanolamides and phenolic surfactants.
Claim 11
Dependent Claim
18 words
The process of claim 6, wherein said aqueous solution comprises about 5% to about 35% urea by weight.
Claim 12
Dependent Claim
18 words
The process of claim 6, wherein said emulsion comprises about 15% to about 45% aqueous solution by weight.
Claim 13
Dependent Claim
49 words
The process of claim 6, wherein said aqueous solution is prepared by first forming a concentrated solution of urea comprising about 30% to about 50% urea by weight and then diluting said concentrated solution with water until the concentration of urea is about 5% to about 25% by weight.
Claim 14
Dependent Claim
27 words
The process of claim 6, wherein said catalyst comprises a water soluble or water dispersible platinum group metal composition present in the aqueous phase of said emulsion.
Claim 15
Dependent Claim
29 words
The process of claim 6, wherein said catalyst comprises a fuel soluble platinum group metal composition present in the fuel phase or in said emulsion after it is formed.
References Cited (Backward Citations)
US2086775A
Cited
US2151432A
Cited
US3876391A
Cited
US3615290A
Cited
US3900554A
Cited
US3961609A
Cited
US4208386A
Cited
US4325924A
Cited
US4401439A
Cited
WO1986003492A1
Cited
US4892562A
Cited
US4629472A
Cited
US4795478A
Cited
US4696638A
Cited
JPH01318716A
Cited
WO1990007561A1
Cited
US5104418A
Cited
US4928635A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1999-07-16 | 2000-01-15 | 2000-07-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2003-07-16 | 2004-01-15 | 2004-07-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2007-07-16 | 2008-01-15 | 2008-07-16 | $7700.00 | Window Closed / Lapsed |