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US4208386A Expired / Lapsed US ⏱️ 0.0 years remaining

Urea reduction of NOx in combustion effluents

Assignee: Electric Power Research Institute
•
Filing: 1976-03-03
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Granted: 1980-06-17
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Expires: 1996-03-03
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Abstract

Abstract Method for reducing NOx in combustion effluents comprising introducing urea at elevated temperatures in the presence of oxygen, either as a solid or solution in amounts sufficient to reduce the NOx concentration. Conveniently, the urea may be introduced as a solid powder or as a solution in a hydroxylic solvent, at temperatures in excess of 1300 DEG F. and in the presence of at least 0.1 volume percent oxygen. This invention was made under contract with or supported by the Electric Power Research Institute.

Inventors

  • 👤 John K. Arand
  • 👤 Lawrence J. Muzio
  • 👤 John G. Sotter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 01:00
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/54; B01D53/56; F; F01; F01N; F01N2610/00; F01N2610/02; F01N2610/03; F01N2610/04; F01N3/00; F01N3/08; F01N3/10; F01N3/18; F01N3/20; F01N3/206; F01N3/2066

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 87 words
A process for selectively reducing NO x in a combustion effluent containing NO x comprising: contacting a NO x containing effluent stream in the presence of oxygen with urea, wherein said urea is present in an amount of about 0.1 to 10 moles per moles NO x at a temperature in the range of about 1600° to 2000° F. with the proviso that when an ancillary reducing material is introduced concurrently with the said urea, said temperature is in the range of about 1300° to 2000° F.
Claim 2
Dependent Claim 87 words
A process for selectively reducing NO x in a combustion effluent containing NO x comprising: contacting a NO x containing effluent stream in the presence of oxygen with urea, wherein said urea is present in an amount of about 0.1 to 10 moles per moles NO x at a temperature in the range of about 1600° to 2000° F. with the proviso that when an ancillary reducing material is introduced concurrently with the said urea, said temperature is in the range of about 1300° to 2000° F.
Claim 3
Dependent Claim 30 words
A method according to claim 1, wherein an ancillary reducing material is introduced concurrently with said urea and said temperature is in the range of about 1300° to 2000° F.
Claim 4
Dependent Claim 12 words
A method according to claim 2, wherein said ancillary material is methanol.
Claim 5
Dependent Claim 17 words
A method according to claim 2, wherein said effluent contains 0.1 to 10 volume percent of oxygen.
Claim 6
Dependent Claim 27 words
A method according to claim 1, wherein said urea is present in an amount of from about 0.5 to 2 moles per mole of NO x .
Claim 7
Dependent Claim 20 words
A method according to claim 1, wherein said urea is introduced as a fine molten spray into said effluent stream.
Claim 8
Dependent Claim 14 words
A method according to claim 1, wherein said urea is introduced as a solution.
Claim 9
Dependent Claim 11 words
A method according to claim 7, wherein said solution is aqueous.
Claim 10
Dependent Claim 11 words
A method according to claim 7, wherein said solution is alkanolic.

References Cited (Backward Citations)

SU186985A1 Cited
US3565575A Cited
US3846981A Cited
GB1388669A Cited
US3801696A Cited
US3867507A Cited
US3900554A Cited
US4061597A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-06-17 1983-12-17 1984-06-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-06-17 1987-12-17 1988-06-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-06-17 1991-12-17 1992-06-17 $7700.00 Window Closed / Lapsed

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