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Radiation detector employing solid-state scintillator material and preparation methods therefor

Assignee: General Electric Co
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Filing: 1991-02-01
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Granted: 1996-05-28
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Expires: 2011-02-01
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Abstract

Abstract A polycrystalline ceramic scintillator exhibiting reduced afterglow includes between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of either Eu 2 O 3 or Nd 2 O 3 as a rare earth activator oxide, and between about 0.003 and 0.5 mole percent of either Pr 2 O 3 and Tb 2 O 3 as an afterglow reducer. The remainder of the scintillator composition is Y 2 O 3 . The resulting scintillator is especially useful for a radiation detector of the type having a plurality of radiation receiving channels. A scintillator body is disposed in each channel so that radiation being received therein is incident on the scintillator body and causes the body to convert the incident radiation to light energy of a predetermined wavelength. The radiation detector also includes means for converting the light energy from the scintillator into electrical signals which are proportional to the amount of radiation incident on the scintillator body. Methods for preparing the scintillator of the present invention include sintering, sintering combined with gas hot isostatic pressing, and vacuum hot pressing.

Inventors

  • 👤 Robert J. Riedner
  • 👤 Robert J. Lyons
  • 👤 Dominic A. Cusano
  • 👤 Charles D. Greskovich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 04:58
CPC Classifications
G; G01; G01T; G01T1/00; G01T1/16; G01T1/20; G01T1/202; C; C04; C04B; C04B35/00; C04B35/50; C04B35/505; C04B35/622; C04B35/64; C04B35/645; C04B35/6455; C09; C09K; C09K11/00; C09K11/08; C09K11/77; C09K11/7766; C09K11/7767; C09K11/7769; G01T1/161; G01T1/164; G01T1/1641; G01T1/1644; G01T1/2023; H; H04; H04N; H04N7/00; H04N7/04; H01; H01R; H01R13/00; H01R13/46; H01R13/52; H01R13/5205

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 226 words
A radiation detector for a computerized tomography scanner exhibiting improved afterglow characteristics when used with a source of penetrating x-ray radiation, said radiation detector comprising: a detector array housing; a plurality of channels defined in said housing, for receiving said radiation; a polycrystalline ceramic scintillator body disposed in each said channel so that x-ray radiation being received by said channel is incident on said scintillator body, and so that said incident radiation causes said body to scintillate at a wavelength, the composition of said scintillator body consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.5 mole percent of at least one afterglow reducer selected from the group consisting of Pr 2 O 3 and Tb 2 O 3 , the remainder of said composition being Y 2 O 3 ; and means for detecting said wavelength scintillator energy emitted from each said scintillator body and for generating electrical signals in response thereto, said detecting means being coupled to each said scintillator body so as to produce a set of signals related to the x-ray radiation received in the respective channels of said detector array housing.
Claim 2
Dependent Claim 226 words
A radiation detector for a computerized tomography scanner exhibiting improved afterglow characteristics when used with a source of penetrating x-ray radiation, said radiation detector comprising: a detector array housing; a plurality of channels defined in said housing, for receiving said radiation; a polycrystalline ceramic scintillator body disposed in each said channel so that x-ray radiation being received by said channel is incident on said scintillator body, and so that said incident radiation causes said body to scintillate at a wavelength, the composition of said scintillator body consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.5 mole percent of at least one afterglow reducer selected from the group consisting of Pr 2 O 3 and Tb 2 O 3 , the remainder of said composition being Y 2 O 3 ; and means for detecting said wavelength scintillator energy emitted from each said scintillator body and for generating electrical signals in response thereto, said detecting means being coupled to each said scintillator body so as to produce a set of signals related to the x-ray radiation received in the respective channels of said detector array housing.
Claim 3
Dependent Claim 23 words
The detector of claim 1 wherein Gd 2 O 3 is present in an amount of between about 20 and 40 mole percent.
Claim 4
Dependent Claim 28 words
The detector of claim 1 wherein said rare earth activator oxide is Eu 2 O 3 present in an amount of between about 1 and 6 mole percent.
Claim 5
Dependent Claim 28 words
The detector of claim 1 wherein said rare earth activator oxide is Nd 2 O 3 present in an amount of between about 0.05 and 1.5 mole percent.
Claim 6
Dependent Claim 26 words
The detector of claim 1 wherein said afterglow reducer is Pr 2 O 3 present in an amount of between about 0.008 and 0.04 mole percent.
Claim 7
Dependent Claim 26 words
The detector of claim 1 wherein said afterglow reducer is Tb 2 O 3 present in an amount of between about 0.008 and 0.035 mole percent.
Claim 8
Dependent Claim 26 words
The detector of claim 1 wherein said afterglow reducer is Pr 2 O 3 present in an amount of between about 0.004 and 0.016 mole percent.
Claim 9
Dependent Claim 26 words
The detector of claim 1 wherein said afterglow reducer is Tb 2 O 3 present in an amount of between about 0.008 and 0.014 mole percent.
Claim 10
Dependent Claim 98 words
A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.5 mole percent of at least one afterglow reducer selected from the group consisting of Pr 2 O 3 and Tb 2 O 3 , the remainder of said composition being Y 2 O 3 .
Claim 11
Dependent Claim 98 words
A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.5 mole percent of at least one afterglow reducer selected from the group consisting of Pr 2 O 3 and Tb 2 O 3 , the remainder of said composition being Y 2 O 3 .
Claim 12
Dependent Claim 23 words
The scintillator of claim 9 wherein Gd 2 O 3 is present in an amount of between about 20 and 40 mole percent.
Claim 13
Dependent Claim 27 words
The scintillator of claim 9 wherein said rare earth activator is Eu 2 O 3 present in an amount of between about 1 and 6 mole percent.
Claim 14
Dependent Claim 27 words
The scintillator of claim 9 wherein said rare earth activator is Nd 2 O 3 present in an amount of between about 0.05 and 1.5 mole percent.
Claim 15
Dependent Claim 22 words
The scintillator of claim 9 wherein said afterglow reducer is present in an amount of between about 0.008 and 0.04 mole percent.
Claim 16
Dependent Claim 98 words
A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of E 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.016 mole percent of at least one afterglow reducer selected from the group consisting of Pr 2 O 3 and Tb 2 O 3 , the remainder of said composition being Y 2 O 3 .
Claim 17
Dependent Claim 98 words
A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of E 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.016 mole percent of at least one afterglow reducer selected from the group consisting of Pr 2 O 3 and Tb 2 O 3 , the remainder of said composition being Y 2 O 3 .
Claim 18
Dependent Claim 23 words
The scintillator of claim 14 wherein Gd 2 O 3 is present in an amount of between about 20 and 40 mole percent.
Claim 19
Dependent Claim 27 words
The scintillator of claim 14 wherein said rare earth activator is Eu 2 O 3 present in an amount of between about 1 and 6 mole percent.
Claim 20
Dependent Claim 27 words
The scintillator of claim 14 wherein said rare earth activator is Nd 2 O 3 present in an amount of between about 0.05 and 1.5 mole percent.
Claim 21
Dependent Claim 41 words
The scintillator of claim 14 wherein Gd 2 O 3 is present in an amount of about 30 mole percent, and wherein said rare earth activator oxide is Eu 2 O 3 present in an amount of about 3 mole percent.
Claim 22
Dependent Claim 22 words
The scintillator of claim 18 wherein said afterglow reducer is present in an amount of between about 0.01 and 0.012 mole percent.
Claim 23
Dependent Claim 207 words
A radiation detector exhibiting improved afterglow characteristics when used with a source of penetrating radiation, said radiation detector comprising: a detector array housing; a plurality of channels defined in said housing, for receiving said radiation; a polycrystalline ceramic scintillator body disposed in each said channel so that radiation being received by said channel is incident on said scintillator body, and so that said incident radiation causes said body to scintillate at a wavelength, the composition of said scintillator body consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.5 mole percent of an afterglow reducer consisting of Pr 2 O 3 , the remainder of said composition being Y 2 O 3 ; and means for detecting said wavelength scintillator energy emitted from each said scintillator body and for generating electrical signals in response thereto, said detecting means being coupled to each said scintillator body so as to produce a set of signals related to the radiation received in the respective channels of said detector array housing.
Claim 24
Dependent Claim 207 words
A radiation detector exhibiting improved afterglow characteristics when used with a source of penetrating radiation, said radiation detector comprising: a detector array housing; a plurality of channels defined in said housing, for receiving said radiation; a polycrystalline ceramic scintillator body disposed in each said channel so that radiation being received by said channel is incident on said scintillator body, and so that said incident radiation causes said body to scintillate at a wavelength, the composition of said scintillator body consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.5 mole percent of an afterglow reducer consisting of Pr 2 O 3 , the remainder of said composition being Y 2 O 3 ; and means for detecting said wavelength scintillator energy emitted from each said scintillator body and for generating electrical signals in response thereto, said detecting means being coupled to each said scintillator body so as to produce a set of signals related to the radiation received in the respective channels of said detector array housing.
Claim 25
Dependent Claim 87 words
A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.016 mole percent of an afterglow reducer consisting of Pr 2 O 3 , the remainder of said composition being Y 2 O 3 .
Claim 26
Dependent Claim 87 words
A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd 2 O 3 , between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu 2 O 3 and Nd 2 O 3 , and between about 0.008 and 0.016 mole percent of an afterglow reducer consisting of Pr 2 O 3 , the remainder of said composition being Y 2 O 3 .

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-05-28 1999-11-27 2000-05-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-05-28 2003-11-27 2004-05-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-05-28 2007-11-27 2008-05-28 $7700.00 Window Closed / Lapsed

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