Patent US5451341A successfully refreshed from Google Patents.
US5451341A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Soil release polymer in detergent compositions containing dye transfer inhibiting agents to improve cleaning performance
Assignee: Procter and Gamble Co
•
Filing: 1993-09-10
•
Granted: 1995-09-19
•
Expires: 2013-09-10
Abstract
Abstract A granular detergent composition containing a mixture of dye transfer inhibiting agents in combination with a soil release agent is provided. The detergent composition overcomes cleaning deficiencies experienced as a result of the inclusion of dye transfer inhibiting agents. The granular detergent composition having comprises, by weight: (a) from about 1% to about 50% of a detersive surfactant; (b) from about 1% to about 80% of a builder; (c) from about 0.01% to about 10% of a polyamine N-oxide polymer; (d) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (e) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer.
Inventors
- 👤 Chiquita V. White
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 20:18
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3746; C11D3/3769; C11D3/3776; C11D3/0005; C11D3/0021; C11D3/0036; C11D3/3703; C11D3/3715; C11D3/3792
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
335 words
A granular detergent composition comprising, by weight: (A) from about 1% to about 50% of a detersive surfactant (B) from about 1% to about 80% of a builder (C) from about 0.01% to about 10% of a polyamine N-oxide polymer; (D) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (E) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer comprising (i) from about 1 to about 2 moles of sulfonated poly-ethoxy/propoxy end-capping units of the formula (MO 3 S)(CH 2 ) m (CH 2 CH 2 O)(RO) n -- wherein M is a salt forming cation selected from the group consisting of sodium and tetraalkylammonium, m is 0 or 1, R is ethylene, propylene or a mixture thereof, and n is from 0 to 2; (ii) from about 0.5 to about 66 moles of units selected from the group consisting of: a) oxyethyleneoxy units; b) a mixture of oxyethyleneoxy and oxy-1,2-propyleneoxy units wherein said oxyethyleneoxy units are present in an oxyethyleneoxy to oxy-1,2-propyleneoxy mole ratio ranging from 0.5:1 to about 10:1; and c) a mixture of a) or b) with poly(oxyethylene)oxy units wherein said oligomer; poly(oxyethylene)oxy units have a degree of polymerization of from 2 to 4; provided that when said poly(oxyethylene)oxy units have a degree of polymerization of 2, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.33:1; and when said poly(oxyethylene)oxy units have a degree of polymerization of 3, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.22:1; and when said poly(oxyethylene oxy units have a degree of polymerization of 4, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.14:1; (iii) from about 1.5 to about 40 moles of terephthaloyl units; and iv) from 0 to about 26 moles of 5-sulfoisophthaloyl units of the formula --(O)C(C 6 H 3 )(SO 3 M)C(O)-- wherein M is a salt forming cation.
Claim 2
Dependent Claim
335 words
A granular detergent composition comprising, by weight: (A) from about 1% to about 50% of a detersive surfactant (B) from about 1% to about 80% of a builder (C) from about 0.01% to about 10% of a polyamine N-oxide polymer; (D) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (E) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer comprising (i) from about 1 to about 2 moles of sulfonated poly-ethoxy/propoxy end-capping units of the formula (MO 3 S)(CH 2 ) m (CH 2 CH 2 O)(RO) n -- wherein M is a salt forming cation selected from the group consisting of sodium and tetraalkylammonium, m is 0 or 1, R is ethylene, propylene or a mixture thereof, and n is from 0 to 2; (ii) from about 0.5 to about 66 moles of units selected from the group consisting of: a) oxyethyleneoxy units; b) a mixture of oxyethyleneoxy and oxy-1,2-propyleneoxy units wherein said oxyethyleneoxy units are present in an oxyethyleneoxy to oxy-1,2-propyleneoxy mole ratio ranging from 0.5:1 to about 10:1; and c) a mixture of a) or b) with poly(oxyethylene)oxy units wherein said oligomer; poly(oxyethylene)oxy units have a degree of polymerization of from 2 to 4; provided that when said poly(oxyethylene)oxy units have a degree of polymerization of 2, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.33:1; and when said poly(oxyethylene)oxy units have a degree of polymerization of 3, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.22:1; and when said poly(oxyethylene oxy units have a degree of polymerization of 4, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.14:1; (iii) from about 1.5 to about 40 moles of terephthaloyl units; and iv) from 0 to about 26 moles of 5-sulfoisophthaloyl units of the formula --(O)C(C 6 H 3 )(SO 3 M)C(O)-- wherein M is a salt forming cation.
Claim 3
Dependent Claim
20 words
The granular detergent composition of claim 1 further comprising from about 0.5% to about 20% of a crystallization reducing stabilizer.
Claim 4
Dependent Claim
27 words
The granular detergent composition of claim 2 wherein said crystallization reducing stabilizer is selected from the group consisting of sulfonate-based hydrotropes, alkylbenzenesulfonates, paraffin sulfonates and mixtures thereof.
Claim 5
Dependent Claim
24 words
The granular detergent composition of claim 1 wherein said copolymer of N-vinylpyrrolidone and N-vinylimidazole has a molecular weight from about 5000 to about 1,000,000.
Claim 6
Dependent Claim
24 words
The granular detergent composition of claim 1 wherein said copolymer of N-vinylpyrrolidone and N-vinylimidazole has a molecular weight from about 8000 to about 30,000.
Claim 7
Dependent Claim
25 words
The granular detergent composition of claim 1 wherein said builder is selected from the group consisting of aluminosilicates, crystalline layered silicates, citrates and mixtures thereof.
Claim 8
Dependent Claim
26 words
The granular detergent composition of claim 1 wherein said detersive surfactant is selected from the group consisting of anionics, nonionics, zwitterionics, ampholytics, cationics and mixtures thereof.
Claim 9
Dependent Claim
85 words
A granular detergent composition comprising, by weight: (a) from about 1% to about 50% of a detersive surfactant; (b) from about 1% to about 80% of a builder; (c) from about 0.01% to about 10% of a polyamine N-oxide polymer; (d) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (e) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer of the formula: ##STR10## wherein R is H or CH 3 in a ratio of 1.8:1
Claim 10
Dependent Claim
85 words
A granular detergent composition comprising, by weight: (a) from about 1% to about 50% of a detersive surfactant; (b) from about 1% to about 80% of a builder; (c) from about 0.01% to about 10% of a polyamine N-oxide polymer; (d) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (e) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer of the formula: ##STR10## wherein R is H or CH 3 in a ratio of 1.8:1
Claim 11
Dependent Claim
28 words
A method of laundering soiled clothes comprising the step contacting said clothes with an effective amount of a detergent composition according to claim 1 in an aqueous medium.
Claim 12
Dependent Claim
21 words
The granular detergent composition of claim 1 wherein said ester oligomer has a molecular weight from about 500 to about 5,000.
Claim 13
Dependent Claim
29 words
A method of laundering soiled clothes comprising the step of contacting said clothes with an effective amount of a detergent composition according to claim 8 in an aqueous medium.
Claim 14
Dependent Claim
113 words
A granular detergent composition according to claim 1, which composition comprises by weight: (a) a detersive surfactant selected from the group consisting of anionics, nonionics, zwitterionics, ampholytics, cationics and mixtures thereof; (b) a builder selected from group consisting aluminosilicates, crystalline layered silicates, citrates and mixtures thereof; (c) from about 0.1% to about 1% of a polyvinylpyridine N-oxide polymer; (d) from about 0.1% to about 1% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; (e) from about 0.01% to about 1% of the sulfonated poly-ethoxy/propoxy end-capped ester oligomer; and (f) from about 0.5% to about 20% of a crystallization reducing stabilizer selected from the group consisting of sulfonate-based hydrotropes, alkylbenzenesulfonates, paraffin sulfonates and mixtures thereof.
Claim 15
Dependent Claim
16 words
The granular detergent composition of claim 12 wherein said crystallization reducing stabilizer is a sulfonate-based hydrotrope.
Claim 16
Dependent Claim
29 words
A method of laundering soiled clothes comprising the step of contacting said clothes with an effective amount of a detergent composition according to claim 12 in an aqueous medium.
References Cited (Backward Citations)
US4548744A
Cited
US4702857A
Cited
US4861512A
Cited
US4711730A
Cited
US4721580A
Cited
US4976879A
Cited
EP0327927A2
Cited
US4925577A
Cited
US5041230A
Cited
US4968451A
Cited
US5273676A
Cited
US5182043A
Cited
US5196133A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1998-09-18 | 1999-03-20 | 1999-09-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-09-18 | 2003-03-20 | 2003-09-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-09-18 | 2007-03-20 | 2007-09-19 | $7700.00 | Window Closed / Lapsed |