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US4861512A Expired / Lapsed US ⏱️ 0.0 years remaining

Sulfonated block polyesters useful as soil release agents in detergent compositions

Assignee: Procter and Gamble Co
•
Filing: 1988-08-02
•
Granted: 1989-08-29
•
Expires: 2008-08-02
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Abstract

Abstract Block polyesters useful as soil release agents in detergent compositions are disclosed. Preferred polyesters have the formula: <IMAGE> +TR <IMAGE> wherein each R1 is a 1,4-phenylene moiety; the R2 consist essentially of ethylene moieties, 1,2-propylene moieties or a mixture thereof; each X is ethyl or preferably methyl; each n is from about 12 to about 43; u is from about 3 to about 10.

Inventors

  • 👤 Eugene P. Gosselink

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 03:23
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/0005; C11D3/0036; C08; C08G; C08G63/00; C08G63/66; C08G63/68; C08G63/688; C11D3/16; C11D3/37; C11D3/3703; C11D3/3715

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 312 words
A detergent composition which comprises: (a) from about 1 to about 75% by weight of a nonionic, anionic, ampholytic, zwitterionic, or cationic detergent surfactant, or mixture thereof; and (b) a soil release component which comprises an effective amount of a sulfonated soil release compound of formula: X--(OCH.sub.2 CH.sub.2).sub.n (OR.sup.5).sub.m ][(A--R.sup.1 --A--R.sup.2).sub.u (A--R.sup.3 --A--R.sup.2).sub.v -- --A--R.sup.4 --A--(R.sup.5 O).sub.m (CH.sub.2 CH.sub.2 O).sub.n --X wherein the A moieties are essentially ##STR27## moieties; the R 1 moieties are essentially 1,4-phenylene moieties; the R 2 moieties are essentially substituted ethylene moieties having C 1 -C 4 alkyl or alkoxy substituents, or are combinations thereof with ethylene moieties; the R 3 moieties are substituted C 2 -C 18 hydrocarbylene moieties having at least one --SO 3 M substituent; the R 4 moieties are R 1 or R 3 moieties, or a mixture thereof; each R 5 is C 3 -C 4 alkylene, or the moiety --R 2 --A--R 6 --, wherein R 6 is a C 1 -C 12 alkylene, alkenylene, arylene or alkarylene moiety; each M is H or a water-soluble cation; each X is H, C 1 -C 4 alkyl or ##STR28## wherein R 7 is C 1 -C 4 alkyl; m and n are numbers such that the moiety --(CH 2 CH 2 O)-- comprises at least about 50% by weight of the moiety --(R 5 O) m (CH 2 CH 2 O) n --, provided that when R 5 is the moiety --R 2 --A--R 6 --, m is 1; each n is at least about 6; u and v are numbers such that v is greater than 0 and the sum of u+v is from about 3 to about 25; w is 0 or at least 1; and when w is at least 1, u, v and w are numbers such that the sum of u+v+w is from about 3 to about 25.
Claim 2
Dependent Claim 312 words
A detergent composition which comprises: (a) from about 1 to about 75% by weight of a nonionic, anionic, ampholytic, zwitterionic, or cationic detergent surfactant, or mixture thereof; and (b) a soil release component which comprises an effective amount of a sulfonated soil release compound of formula: X--(OCH.sub.2 CH.sub.2).sub.n (OR.sup.5).sub.m ][(A--R.sup.1 --A--R.sup.2).sub.u (A--R.sup.3 --A--R.sup.2).sub.v -- --A--R.sup.4 --A--(R.sup.5 O).sub.m (CH.sub.2 CH.sub.2 O).sub.n --X wherein the A moieties are essentially ##STR27## moieties; the R 1 moieties are essentially 1,4-phenylene moieties; the R 2 moieties are essentially substituted ethylene moieties having C 1 -C 4 alkyl or alkoxy substituents, or are combinations thereof with ethylene moieties; the R 3 moieties are substituted C 2 -C 18 hydrocarbylene moieties having at least one --SO 3 M substituent; the R 4 moieties are R 1 or R 3 moieties, or a mixture thereof; each R 5 is C 3 -C 4 alkylene, or the moiety --R 2 --A--R 6 --, wherein R 6 is a C 1 -C 12 alkylene, alkenylene, arylene or alkarylene moiety; each M is H or a water-soluble cation; each X is H, C 1 -C 4 alkyl or ##STR28## wherein R 7 is C 1 -C 4 alkyl; m and n are numbers such that the moiety --(CH 2 CH 2 O)-- comprises at least about 50% by weight of the moiety --(R 5 O) m (CH 2 CH 2 O) n --, provided that when R 5 is the moiety --R 2 --A--R 6 --, m is 1; each n is at least about 6; u and v are numbers such that v is greater than 0 and the sum of u+v is from about 3 to about 25; w is 0 or at least 1; and when w is at least 1, u, v and w are numbers such that the sum of u+v+w is from about 3 to about 25.
Claim 3
Dependent Claim 28 words
The composition of claim 1, wherein each A is ##STR29## and wherein said soil release compound comprises from about 0.1 to about 10% by weight of the composition.
Claim 4
Dependent Claim 17 words
The composition of claim 1, wherein each R 3 moiety is a sodium or potassium 5-sulfo-1,3-phenylene moiety.
Claim 5
Dependent Claim 287 words
A detergent composition which comprises: (a) from about 1% to about 75% by weight of a nonionic, anionic, ampholytic, zwitterionic, or cationic detergent surfactant, or mixture thereof; and (b) from about 0.1% to about 10% by weight of a sulfonated soil release compound of formula: X--(OCH.sub.2 CH.sub.2).sub.n (OR.sup.5).sub.m ][(A--R.sup.1 --A--R.sup.2).sub.u (A--R.sup.3 --A--R.sup.2).sub.v -- A--R.sup.4 --A--(R.sup.5 O).sub.m (CH.sub.2 CH.sub.2 O).sub.n --X wherein the A moieties are ##STR30## the R 1 moieties are 1,4-phenylene moieties; the R 2 moieties are essentially 1,2-propylene moieties or mixtures thereof with ethylene moieties; the R 3 moieties are sodium 5-sulfo-1,3-phenylene or potassium 5-sulfo-1,3-phenylene; the R 4 moieties are R 1 or R 3 moieties, or a mixture thereof; each R 5 is C 3 -C 4 alkylene, or the moiety --R 2 --A--R 6 --, wherein R 6 is a C 1 -C 12 alkylene, alkenylene, arylene or alkarylene moiety; each M is H or a water-soluble cation; each X is H, C 1 -C 4 alkyl or ##STR31## wherein R 7 is C 1 -C 4 alkyl; m and n are numbers such that the moiety --(CH 2 CH 2 O)-- comprises at least about 50% by weight of the moiety [(R 5 O) m (CH 2 CH 2 O) n ], provided that when R 5 is the moiety --R 2 --A--R 6 --, m is 1; each n is at least about 6; u and v are numbers such that v is greater than 0 and the sum of u+v is from about 3 to about 25; w is 0 or at least 1; and when w is at least 1, u, v and w are numbers such that the sum of u+v+w is from about 3 to about 25.
Claim 6
Dependent Claim 287 words
A detergent composition which comprises: (a) from about 1% to about 75% by weight of a nonionic, anionic, ampholytic, zwitterionic, or cationic detergent surfactant, or mixture thereof; and (b) from about 0.1% to about 10% by weight of a sulfonated soil release compound of formula: X--(OCH.sub.2 CH.sub.2).sub.n (OR.sup.5).sub.m ][(A--R.sup.1 --A--R.sup.2).sub.u (A--R.sup.3 --A--R.sup.2).sub.v -- A--R.sup.4 --A--(R.sup.5 O).sub.m (CH.sub.2 CH.sub.2 O).sub.n --X wherein the A moieties are ##STR30## the R 1 moieties are 1,4-phenylene moieties; the R 2 moieties are essentially 1,2-propylene moieties or mixtures thereof with ethylene moieties; the R 3 moieties are sodium 5-sulfo-1,3-phenylene or potassium 5-sulfo-1,3-phenylene; the R 4 moieties are R 1 or R 3 moieties, or a mixture thereof; each R 5 is C 3 -C 4 alkylene, or the moiety --R 2 --A--R 6 --, wherein R 6 is a C 1 -C 12 alkylene, alkenylene, arylene or alkarylene moiety; each M is H or a water-soluble cation; each X is H, C 1 -C 4 alkyl or ##STR31## wherein R 7 is C 1 -C 4 alkyl; m and n are numbers such that the moiety --(CH 2 CH 2 O)-- comprises at least about 50% by weight of the moiety [(R 5 O) m (CH 2 CH 2 O) n ], provided that when R 5 is the moiety --R 2 --A--R 6 --, m is 1; each n is at least about 6; u and v are numbers such that v is greater than 0 and the sum of u+v is from about 3 to about 25; w is 0 or at least 1; and when w is at least 1, u, v and w are numbers such that the sum of u+v+w is from about 3 to about 25.
Claim 7
Dependent Claim 20 words
The composition of claim 1 wherein said R 2 moieties comprise from about 20 to 100% of said 1,2-propylene moieties.
Claim 8
Dependent Claim 20 words
The composition of claim 5, wherein said R 2 moieties comprise from about 80 to 100% of said 1,2-propylene moieties.
Claim 9
Dependent Claim 14 words
The compositions of claim 5, wherein u is from about 3 to about 10.
Claim 10
Dependent Claim 19 words
The compositions of claim 7, wherein m is 0 and each n is from about 12 to about 43.
Claim 11
Dependent Claim 10 words
The composition of claim 8, which is an isotropic liquid.
Claim 12
Dependent Claim 22 words
The composition of claim 9, wherein said soil release component further comprises an organic solvent or hydrotrope for said soil release compound.
Claim 13
Dependent Claim 22 words
The composition of claim 8, wherein said soil release compound comprises from about 0.1 to about 5% by weight of the composition.
Claim 14
Dependent Claim 21 words
The composition of claim 8, wherein said detergent surfactant comprises from about 10 to about 50% by weight of the composition.
Claim 15
Dependent Claim 20 words
The composition of claim 12, wherein said detergent surfactant comprises a nonionic surfactant, an anionic surfactant or a mixture thereof.
Claim 16
Dependent Claim 23 words
The composition of claim 12, which further comprises from about 3 to about 20% by weight of the composition of a detergent builder.
Claim 17
Dependent Claim 23 words
The composition of claim 12, which further comprises from about 20 to about 30% by weight of the composition of a detergent builder.
Claim 18
Dependent Claim 11 words
The composition of claim 12, which further comprises an optical brightener.

References Cited (Backward Citations)

US3033824A Cited
US3416952A Cited
US3563942A Cited
US4104262A Cited
US4427557A Cited
US4713194A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-08-28 1993-02-27 1993-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-08-28 1997-02-27 1997-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-08-28 2001-02-27 2001-08-29 $7700.00 Window Closed / Lapsed

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