US4711730A
Expired / Lapsed
US
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Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents
Assignee: Procter and Gamble Co
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Filing: 1986-04-15
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Granted: 1987-12-08
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Expires: 2006-04-15
Abstract
Abstract Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents are disclosed. Preferred polyesters have the formula: <IMAGE> +TR <IMAGE> wherein each R1 is a 1,4-phenylene moiety; the R2 are essentially 1,2-propylene moieties; the R3 are essentially the polyoxyethylene moiety-(CH2CH2O)q-CH2CH2-; each X is ethyl or preferably methyl; each n is from about 12 to about 45; q is from about 12 to about 90; the average value of u is from about 5 to about 20; the average value of v is from about 1 to about 10; the average value of u+v is from about 6 to about 30; the ratio u to v is from about 1 to about 6.
Inventors
- 👤 Eugene P. Gosselink
- 👤 Francis L. Diehl
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 06:40
CPC Classifications
C; C11; C11D; C11D17/00; C11D17/04; C11D17/041; C11D17/047; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/672; C11D3/00; C11D3/0005; C11D3/001; C11D3/0036; C11D3/16; C11D3/37; C11D3/3703; C11D3/3715; Y; Y10; Y10T; Y10T442/00; Y10T442/20; Y10T442/2279; Y10T442/2352; Y10T442/2418; Y10T442/2459
Claims Analysis
Total Claims: 35
Claim 1
Independent Claim
350 words
A capped, substituted-ethylene terephthalate ester compound having oligomeric or polymeric backbone incorporating particular polyoxyethylene moieties, said compound having the formula: X--(OCH.sub.2 CH(Y)).sub.n (OR.sup.4).sub.m ][(A--R.sup.1 --A--R.sup.2).sub.u (A--R.sup.1 --A--R.sup.3).sub.v ] --A--R.sup.1 --A--(R.sup.4 O).sub.m (CH(Y)CH.sub.2 O).sub.n ]X wherein the A moieties are selected from the group consisting of ##STR32## and combinations thereof with either or both of the moieties ##STR33## the R 1 moieties are selected from 1,4-phenylene moieties and combinations thereof with up to 50% of other arylene or alkarylene moieties, alkylene moieties, alkenylene moieties or mixtures thereof; the R 2 moieties are selected from (a) the group consisting of 1,2-propylene, 1,2-butylene, 3-methoxy-1,2-propylene and combinations thereof, and (b) combinations of the foregoing R 2 moieties with up to 20% of other compatible R 2 moieties; the R 3 moieties are selected from moieties (CH 2 CH 2 O) q --CH 2 CH 2 -- wherein q is at least about 9, and from combinations thereof with up to 50% of other compatible R 3 moieties; each R 4 is C 3 -C 4 alkylene, or the moiety --R 2 --A--R 5 --, wherein R 5 is a C 1 -C 12 alkylene, alkenylene, arylene or alkarylene moiety; the Y substituents of each moiety --(R 4 O) m (CH(Y)CH 2 O) n ] are H, the ether moiety --CH.sub. 2 (OCH 2 CH 2 ) p O--X or a mixture of said ether moiety and H; each X is H, C 1 -C 4 alkyl or ##STR34## wherein R 6 is C 1 -C 4 alkyl; m and n are numbers such that the moiety --(CH(Y)CH 2 O)-- comprises at least about 50% by weight of the moiety --(R 5 O) m (CH(Y)CH 2 O) n --, provided that when R 4 is the moiety --R 2 --A--R 5 --, m is 1; each n is at least about 6; p is 0 or at least 1; the average value of u is from about 2 to about 50; the average value of v is from about 1 to about 20; the average value of u+v is from about 3 to about 70.
Claim 2
Dependent Claim
350 words
A capped, substituted-ethylene terephthalate ester compound having oligomeric or polymeric backbone incorporating particular polyoxyethylene moieties, said compound having the formula: X--(OCH.sub.2 CH(Y)).sub.n (OR.sup.4).sub.m ][(A--R.sup.1 --A--R.sup.2).sub.u (A--R.sup.1 --A--R.sup.3).sub.v ] --A--R.sup.1 --A--(R.sup.4 O).sub.m (CH(Y)CH.sub.2 O).sub.n ]X wherein the A moieties are selected from the group consisting of ##STR32## and combinations thereof with either or both of the moieties ##STR33## the R 1 moieties are selected from 1,4-phenylene moieties and combinations thereof with up to 50% of other arylene or alkarylene moieties, alkylene moieties, alkenylene moieties or mixtures thereof; the R 2 moieties are selected from (a) the group consisting of 1,2-propylene, 1,2-butylene, 3-methoxy-1,2-propylene and combinations thereof, and (b) combinations of the foregoing R 2 moieties with up to 20% of other compatible R 2 moieties; the R 3 moieties are selected from moieties (CH 2 CH 2 O) q --CH 2 CH 2 -- wherein q is at least about 9, and from combinations thereof with up to 50% of other compatible R 3 moieties; each R 4 is C 3 -C 4 alkylene, or the moiety --R 2 --A--R 5 --, wherein R 5 is a C 1 -C 12 alkylene, alkenylene, arylene or alkarylene moiety; the Y substituents of each moiety --(R 4 O) m (CH(Y)CH 2 O) n ] are H, the ether moiety --CH.sub. 2 (OCH 2 CH 2 ) p O--X or a mixture of said ether moiety and H; each X is H, C 1 -C 4 alkyl or ##STR34## wherein R 6 is C 1 -C 4 alkyl; m and n are numbers such that the moiety --(CH(Y)CH 2 O)-- comprises at least about 50% by weight of the moiety --(R 5 O) m (CH(Y)CH 2 O) n --, provided that when R 4 is the moiety --R 2 --A--R 5 --, m is 1; each n is at least about 6; p is 0 or at least 1; the average value of u is from about 2 to about 50; the average value of v is from about 1 to about 20; the average value of u+v is from about 3 to about 70.
Claim 3
Dependent Claim
10 words
The compound of claim 1, wherein each A is ##STR35##
Claim 4
Dependent Claim
14 words
The compound of claim 2, wherein each R 1 moiety is a 1,4-phenylene moiety.
Claim 5
Dependent Claim
17 words
The compound of claim 2 wherein the ratio of u to v is at least about 1.
Claim 6
Dependent Claim
13 words
The compound of claim 4 wherein said R 2 moieties are 1,2-propylene moieties.
Claim 7
Dependent Claim
20 words
The compound of claim 5 wherein said polyoxyethylene moieties comprise from about 90 to 100% of said R 3 moieties.
Claim 8
Dependent Claim
14 words
The compound of claim 6 wherein q is from about 12 to about 90.
Claim 9
Dependent Claim
12 words
The compound of claim 7 wherein the Y substituents are all H.
Claim 10
Dependent Claim
19 words
The compound of claim 8, wherein m is 0 and each n is from about 12 to about 113.
Claim 11
Dependent Claim
48 words
A laundry detergent composition, which comprises (a) from about 5 to about 75% by weight of a nonionic detergent surfactant; (b) from 0 to about 15% by weight synthetic anionic detergent surfactants; and (c) a soil release component having an effective amount of the compound of claim 1.
Claim 12
Dependent Claim
20 words
The composition of claim 10, wherein said compound comprises from about 0.01 to about 10% by weight of the composition.
Claim 13
Dependent Claim
20 words
The composition of claim 11, wherein said compound comprises from about 0.1 to about 5% by weight of the composition.
Claim 14
Dependent Claim
39 words
The composition of claim 12, wherein said nonionic detergent surfactant comprises from about 15 to about 30% by weight of the composition and wherein said anionic detergent surfactant comprises from 0 to about 10% by weight of the composition.
Claim 15
Dependent Claim
10 words
The composition of claim 13, which is in liquid form.
Claim 16
Dependent Claim
11 words
The composition of claim 14, which further comprises an optical brightener.
Claim 17
Dependent Claim
37 words
An aqueous fabric softener composition, which comprises: (a) from about 2 to about 50% by weight of a fabric softener component; and (b) a soil release component having an effective amount of the compound of claim 1.
Claim 18
Dependent Claim
20 words
The composition of claim 16, wherein said compound comprises from about 0.01 to about 10% by weight of the composition.
Claim 19
Dependent Claim
175 words
The composition of claim 17, wherein said fabric softener component comprises a quaternary ammonium salt selected from the group consisting of: (1) mononitrogen quaternary ammonium salts having the formula: ##STR36## wherein R 1 is an aliphatic C 12 -C 22 hydrocarbon group; R 2 is a C 1 -C 4 saturated alkyl or hydroxyalkyl group; R 3 is selected from R 1 and R 2 ; and A is an anion; (2) diamide quaternary ammonium salts having the formula: ##STR37## wherein R 4 is an aliphatic C 12 -C 22 hydrocarbon group; R 5 is a divalent alkylene group having 1 to 3 carbon atoms; R 6 is a C 1 -C 4 saturated alkyl or hydroxyalkyl group; R 7 is R 6 or the moiety (C a H 2a O) b H, wherein a is 2 or 3 and b is from 1 to about 5; and A is an anion; (3) quaternary imidazolinium salts selected from the group consisting of 1-methyl-1-tallowamidoethyl-2-tallowimidazolinium methylsulfate, 1-methyl-1-(hydrogenated tallowamidoethyl)methylsulfate, 1-ethylene-bis(2-tallow-1-methyl-imidazolinium methylsulfate); and 1-methyl-2-tallow-3[tallowamidoethyltallowamino)ethylene]-imidazolinium methylsulfate; (4) and mixtures thereof.
Claim 20
Dependent Claim
100 words
A composition according to claim 18 wherein said fabric softener component further comprises a cyclic amine having the formula: ##STR38## wherein c is 2 or 3; R 8 and R 9 are, independently, a C 8 -C 30 alkyl or alkenyl group, Q is CH or N, Z is R 10 or ##STR39## wherein T is 0 or NR 11 , R 11 is H or C 1 -C 4 alkyl; and R 10 is a divalent C 1 -C 3 alkylene or (C 2 H 4 O) d group; wherein d is a number of from 1 to 8.
Claim 21
Dependent Claim
22 words
The composition of claim 18, wherein said fabric softener component comprises from about 3 to about 10% by weight of the composition.
Claim 22
Dependent Claim
23 words
A composition according to claim 18, wherein said fabric softener component comprises from about 15 to about 25% by weight of the composition.
Claim 23
Dependent Claim
72 words
A composition according to claim 21, wherein said fabric softener component comprises: (A) from about 2 to about 15% by weight of said mononitrogen quaternary ammonium salts; (B) from 0 to about 14% by weight said diamide quaternary ammonium salts; (C) from about 2 to about 13% by weight of said quaternary imidazolimium salts; the total amount of said salts being from about 15 to about 22.5% by weight of the composition.
Claim 24
Dependent Claim
110 words
An article which provides fabric soil release and softening benefits when used within an automatic clothes dryer, which comprises: (a) a fabric conditioning component having a melting point above about 38° C. and being flowable at dryer operating temperatures and which comprises: (i) from about 1 to about 70% of the compound of claim 1; and (ii) from about 30 to about 99% of a fabric softening agent selected from the group consisting of cationic fabric softener compounds, nonionic fabric softener compounds and mixtures thereof; (b) said fabric conditioning component being associated with a dispensing means which provides for release thereof within an automatic clothes dryer at dryer operating temperatures.
Claim 25
Dependent Claim
43 words
The article of claim 23 wherein said dispensing means comprises a flexible substrate in sheet configuration having said fabric conditioning component releasably affixed thereto to provide a weight ratio of fabric conditioning component to dry substrate of from about 10:1 to about 0.5:1.
Claim 26
Dependent Claim
27 words
The article of claim 24 wherein said compound is present at a level of from about 10 to about 70% by weight of the fabric conditioning component.
Claim 27
Dependent Claim
44 words
The article of claim 25 wherein said fabric softening agent comprises a mixture of from about 5 to about 80% of a cationic fabric softener and from about 10 to about 85% of a nonionic fabric softener, by weight of said fabric conditioning component.
Claim 28
Dependent Claim
76 words
The article of claim 26 wherein said cationic fabric softener is selected from the group consisting of: (1) a quaternary ammonium salt; and (2) a carboxylic acid salt of a tertiary alkylamine; and mixtures of (1) and (2); and wherein said nonionic fabric softener is selected from the group consisting of: (3) a fatty alkyl sorbitan ester; (4) a fatty alcohol; and (5) a fatty amine; and binary and ternary mixtures of (3), (4) and (5).
Claim 29
Dependent Claim
46 words
The article of claim 27 wherein said fabric softening component comprises a mixture of from about 5 to about 25% of a quaternary ammonium salt, from about 10 to about 50% of a sorbitan ester, and from about 5 to about 25% of a fatty amine.
Claim 30
Dependent Claim
125 words
A capped, 1,2-propylene terephthalate ester compound having oligomeric or polymeric backbone incorporating polyoxyethylene moieties, said compound having the formula: ##STR40## wherein each R 1 is a 1,4-phenylene moiety; the R 2 moieties are 1,2-propylene moieties; the R 3 moieties are the polyoxyethylene moieties --(CH 2 CH 2 O) q --CH 2 CH 2 --; each X is ethyl or methyl; each n is from about 12 to about 45; q is from about 12 to about 90; the average value of u is from about 5 to about 20; the average value of v is from about 1 to about 10; the average value of u+v is from about 6 to about 30; the ratio u to v is from about 1 to about 6.
Claim 31
Dependent Claim
125 words
A capped, 1,2-propylene terephthalate ester compound having oligomeric or polymeric backbone incorporating polyoxyethylene moieties, said compound having the formula: ##STR40## wherein each R 1 is a 1,4-phenylene moiety; the R 2 moieties are 1,2-propylene moieties; the R 3 moieties are the polyoxyethylene moieties --(CH 2 CH 2 O) q --CH 2 CH 2 --; each X is ethyl or methyl; each n is from about 12 to about 45; q is from about 12 to about 90; the average value of u is from about 5 to about 20; the average value of v is from about 1 to about 10; the average value of u+v is from about 6 to about 30; the ratio u to v is from about 1 to about 6.
Claim 32
Dependent Claim
47 words
A laundry detergent composition, which comprises: (a) from about 15 to about 30% by weight of a nonionic detergent surfactant; (b) from 0 to about 10% by weight synthetic anionic detergent surfactants; and (c) from about 0.1 to about 5% by weight of the compound claim 29.
Claim 33
Dependent Claim
37 words
An aqueous fabric softener composition, which comprises: (a) from about 3 to about 25% by weight of a fabric softener component; and (b) from about 0.1 to about 5% by weight of the compound of claim 29.
Claim 34
Dependent Claim
110 words
An article which provides fabric soil release and softening benefits when used within an automatic clothes dryer, which comprises: (a) a fabric conditioning component having a melting point above about 38° C. and being flowable at dryer operating temperatures and which comprises: (i) from about 10 to about 70% of the compound of claim 29; and (ii) from about 30 to about 90% of a fabric softening agent selected from the group consisting of cationic fabric softener compounds, non-ionic fabric softener compounds and mixtures thereof; (b) said fabric conditioning component being associated with a flexible substrate which provides for release thereof within an automatic clothes dryer at dryer operating temperatures.
Claim 35
Dependent Claim
99 words
A method for imparting an improved combination of soil release, softening and anti-static effects to fabrics in an automatic laundry dryer which comprises the step of: commingling pieces of damp fabrics by tumbling the fabrics under heat in an automatic clothes dryer with a flexible substrate having releasably affixed thereto an effective amount of a fabric conditioning component having a melting point greater than about 38° C. and being flowable at dryer operating temperature, the fabric conditioning component comprising from about 10 to 70% of the compound of claim 29, and 30 to 90% of a fabric softening agent.
References Cited (Backward Citations)
GB1088984A
Cited
US3416952A
Cited
US3512920A
Cited
US3712873A
Cited
US3893929A
Cited
US3959230A
Cited
US3962152A
Cited
US4132680A
Cited
US4116885A
Cited
CA1100262A
Cited
US4238531A
Cited
US4427557A
Cited
US4411831A
Cited
US4597898A
Cited
US4664848A
Cited
GB2137221A
Cited
GB2137652A
Cited
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