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US5451341A Expired / Lapsed US ⏱️ 0.0 years remaining

Soil release polymer in detergent compositions containing dye transfer inhibiting agents to improve cleaning performance

Assignee: Procter and Gamble Co
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Filing: 1993-09-10
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Granted: 1995-09-19
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Expires: 2013-09-10
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Abstract

Abstract A granular detergent composition containing a mixture of dye transfer inhibiting agents in combination with a soil release agent is provided. The detergent composition overcomes cleaning deficiencies experienced as a result of the inclusion of dye transfer inhibiting agents. The granular detergent composition having comprises, by weight: (a) from about 1% to about 50% of a detersive surfactant; (b) from about 1% to about 80% of a builder; (c) from about 0.01% to about 10% of a polyamine N-oxide polymer; (d) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (e) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer.

Inventors

  • 👤 Chiquita V. White

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 09:26
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3746; C11D3/3769; C11D3/3776; C11D3/0005; C11D3/0021; C11D3/0036; C11D3/3703; C11D3/3715; C11D3/3792

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 335 words
A granular detergent composition comprising, by weight: (A) from about 1% to about 50% of a detersive surfactant (B) from about 1% to about 80% of a builder (C) from about 0.01% to about 10% of a polyamine N-oxide polymer; (D) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (E) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer comprising (i) from about 1 to about 2 moles of sulfonated poly-ethoxy/propoxy end-capping units of the formula (MO 3 S)(CH 2 ) m (CH 2 CH 2 O)(RO) n -- wherein M is a salt forming cation selected from the group consisting of sodium and tetraalkylammonium, m is 0 or 1, R is ethylene, propylene or a mixture thereof, and n is from 0 to 2; (ii) from about 0.5 to about 66 moles of units selected from the group consisting of: a) oxyethyleneoxy units; b) a mixture of oxyethyleneoxy and oxy-1,2-propyleneoxy units wherein said oxyethyleneoxy units are present in an oxyethyleneoxy to oxy-1,2-propyleneoxy mole ratio ranging from 0.5:1 to about 10:1; and c) a mixture of a) or b) with poly(oxyethylene)oxy units wherein said oligomer; poly(oxyethylene)oxy units have a degree of polymerization of from 2 to 4; provided that when said poly(oxyethylene)oxy units have a degree of polymerization of 2, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.33:1; and when said poly(oxyethylene)oxy units have a degree of polymerization of 3, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.22:1; and when said poly(oxyethylene oxy units have a degree of polymerization of 4, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.14:1; (iii) from about 1.5 to about 40 moles of terephthaloyl units; and iv) from 0 to about 26 moles of 5-sulfoisophthaloyl units of the formula --(O)C(C 6 H 3 )(SO 3 M)C(O)-- wherein M is a salt forming cation.
Claim 2
Dependent Claim 335 words
A granular detergent composition comprising, by weight: (A) from about 1% to about 50% of a detersive surfactant (B) from about 1% to about 80% of a builder (C) from about 0.01% to about 10% of a polyamine N-oxide polymer; (D) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (E) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer comprising (i) from about 1 to about 2 moles of sulfonated poly-ethoxy/propoxy end-capping units of the formula (MO 3 S)(CH 2 ) m (CH 2 CH 2 O)(RO) n -- wherein M is a salt forming cation selected from the group consisting of sodium and tetraalkylammonium, m is 0 or 1, R is ethylene, propylene or a mixture thereof, and n is from 0 to 2; (ii) from about 0.5 to about 66 moles of units selected from the group consisting of: a) oxyethyleneoxy units; b) a mixture of oxyethyleneoxy and oxy-1,2-propyleneoxy units wherein said oxyethyleneoxy units are present in an oxyethyleneoxy to oxy-1,2-propyleneoxy mole ratio ranging from 0.5:1 to about 10:1; and c) a mixture of a) or b) with poly(oxyethylene)oxy units wherein said oligomer; poly(oxyethylene)oxy units have a degree of polymerization of from 2 to 4; provided that when said poly(oxyethylene)oxy units have a degree of polymerization of 2, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.33:1; and when said poly(oxyethylene)oxy units have a degree of polymerization of 3, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.22:1; and when said poly(oxyethylene oxy units have a degree of polymerization of 4, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to about 0.14:1; (iii) from about 1.5 to about 40 moles of terephthaloyl units; and iv) from 0 to about 26 moles of 5-sulfoisophthaloyl units of the formula --(O)C(C 6 H 3 )(SO 3 M)C(O)-- wherein M is a salt forming cation.
Claim 3
Dependent Claim 20 words
The granular detergent composition of claim 1 further comprising from about 0.5% to about 20% of a crystallization reducing stabilizer.
Claim 4
Dependent Claim 27 words
The granular detergent composition of claim 2 wherein said crystallization reducing stabilizer is selected from the group consisting of sulfonate-based hydrotropes, alkylbenzenesulfonates, paraffin sulfonates and mixtures thereof.
Claim 5
Dependent Claim 24 words
The granular detergent composition of claim 1 wherein said copolymer of N-vinylpyrrolidone and N-vinylimidazole has a molecular weight from about 5000 to about 1,000,000.
Claim 6
Dependent Claim 24 words
The granular detergent composition of claim 1 wherein said copolymer of N-vinylpyrrolidone and N-vinylimidazole has a molecular weight from about 8000 to about 30,000.
Claim 7
Dependent Claim 25 words
The granular detergent composition of claim 1 wherein said builder is selected from the group consisting of aluminosilicates, crystalline layered silicates, citrates and mixtures thereof.
Claim 8
Dependent Claim 26 words
The granular detergent composition of claim 1 wherein said detersive surfactant is selected from the group consisting of anionics, nonionics, zwitterionics, ampholytics, cationics and mixtures thereof.
Claim 9
Dependent Claim 85 words
A granular detergent composition comprising, by weight: (a) from about 1% to about 50% of a detersive surfactant; (b) from about 1% to about 80% of a builder; (c) from about 0.01% to about 10% of a polyamine N-oxide polymer; (d) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (e) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer of the formula: ##STR10## wherein R is H or CH 3 in a ratio of 1.8:1
Claim 10
Dependent Claim 85 words
A granular detergent composition comprising, by weight: (a) from about 1% to about 50% of a detersive surfactant; (b) from about 1% to about 80% of a builder; (c) from about 0.01% to about 10% of a polyamine N-oxide polymer; (d) from about 0.01% to about 10% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; and (e) from about 0.01% to about 20% of a sulfonated poly-ethoxy/propoxy end-capped ester oligomer of the formula: ##STR10## wherein R is H or CH 3 in a ratio of 1.8:1
Claim 11
Dependent Claim 28 words
A method of laundering soiled clothes comprising the step contacting said clothes with an effective amount of a detergent composition according to claim 1 in an aqueous medium.
Claim 12
Dependent Claim 21 words
The granular detergent composition of claim 1 wherein said ester oligomer has a molecular weight from about 500 to about 5,000.
Claim 13
Dependent Claim 29 words
A method of laundering soiled clothes comprising the step of contacting said clothes with an effective amount of a detergent composition according to claim 8 in an aqueous medium.
Claim 14
Dependent Claim 113 words
A granular detergent composition according to claim 1, which composition comprises by weight: (a) a detersive surfactant selected from the group consisting of anionics, nonionics, zwitterionics, ampholytics, cationics and mixtures thereof; (b) a builder selected from group consisting aluminosilicates, crystalline layered silicates, citrates and mixtures thereof; (c) from about 0.1% to about 1% of a polyvinylpyridine N-oxide polymer; (d) from about 0.1% to about 1% of a copolymer of N-vinylpyrrolidone and N-vinylimidazole; (e) from about 0.01% to about 1% of the sulfonated poly-ethoxy/propoxy end-capped ester oligomer; and (f) from about 0.5% to about 20% of a crystallization reducing stabilizer selected from the group consisting of sulfonate-based hydrotropes, alkylbenzenesulfonates, paraffin sulfonates and mixtures thereof.
Claim 15
Dependent Claim 16 words
The granular detergent composition of claim 12 wherein said crystallization reducing stabilizer is a sulfonate-based hydrotrope.
Claim 16
Dependent Claim 29 words
A method of laundering soiled clothes comprising the step of contacting said clothes with an effective amount of a detergent composition according to claim 12 in an aqueous medium.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-09-18 1999-03-20 1999-09-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-09-18 2003-03-20 2003-09-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-09-18 2007-03-20 2007-09-19 $7700.00 Window Closed / Lapsed

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