US5422308A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of fabricating a tungsten contact
Assignee: STMicroelectronics Ltd Great Britain
•
Filing: 1993-12-06
•
Granted: 1995-06-06
•
Expires: 2013-12-06
Abstract
Abstract A method of fabricating a tungsten contact in a semiconductor device comprises providing an oxide layer on a region of a silicon substrate; depositing a sealing dielectric layer over the oxide layer; and depositing an interlevel dielectric layer over the sealing layer. The interlevel dielectric layer, the sealing dielectric layer and the oxide layer are then etched through as far as the substrate thereby to form a contact hole and to expose the said region. A dopant is implanted into the said region whereby the implanted dopant is self-aligned to the contact hole. The substrate is thermally annealed. Tungsten is selectively deposited in the contact hole and an interconnect layer is deposited over the deposited tungsten contact. The invention also provides a semiconductor device which incorporates a tungsten contact and which can be fabricated by the method.
Inventors
- 👤 Howard C. Nicholls
- 👤 Michael J. Norrington
- 👤 Michael K. Thompson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 14:25
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/0698; H10W20/056; H10W20/40; H10W20/41; H10W20/44; H10W20/4403; H10W20/4437; H10W20/4441
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
120 words
A method of fabricating a tungsten contact in a semiconductor device, which method comprises the steps of: (a) providing an oxide layer on a region of a silicon substrate; (b) depositing a sealing dielectric layer over the oxide layer; (c) depositing an interlevel dielectric layer over the sealing layer; (d) etching through the interlevel dielectric layer, the sealing dielectric layer and oxide layer as far as the substrate thereby to form a contact hole and to expose said region; (e) implanting a dopant into said region whereby the implanted dopant is self-aligned to the contact hole; (f) thermally annealing the substrate; (g) selectively depositing tungsten in the contact hole; and (h) depositing an interconnect layer over the deposited tungsten contact.
Claim 2
Independent Claim
120 words
A method of fabricating a tungsten contact in a semiconductor device, which method comprises the steps of: (a) providing an oxide layer on a region of a silicon substrate; (b) depositing a sealing dielectric layer over the oxide layer; (c) depositing an interlevel dielectric layer over the sealing layer; (d) etching through the interlevel dielectric layer, the sealing dielectric layer and oxide layer as far as the substrate thereby to form a contact hole and to expose said region; (e) implanting a dopant into said region whereby the implanted dopant is self-aligned to the contact hole; (f) thermally annealing the substrate; (g) selectively depositing tungsten in the contact hole; and (h) depositing an interconnect layer over the deposited tungsten contact.
Claim 3
Dependent Claim
32 words
A method according to claim 1, wherein the sealing dielectric layer is provided at the interface between the oxide layer and the silicon substrate thereby to prevent tungsten encroachment along the interface.
Claim 4
Dependent Claim
16 words
A method according to claim 1 wherein the sealing dielectric layer is composed of silicon nitride.
Claim 5
Dependent Claim
14 words
A method according to claim 1 wherein step (f) is a rapid thermal anneal.
Claim 6
Dependent Claim
40 words
A method according to claim 4 wherein the interlevel dielectric layer is composed of a reflowable material and further comprising the step, after depositing step (c), of heating the substrate and said layers thereby to reflow the interlevel dielectric layer.
Claim 7
Dependent Claim
28 words
A method according to claim 1 wherein said region is initially doped with a dopant of the same conductivity as the dopant which is implanted in step (e).
Claim 8
Dependent Claim
30 words
A method according to claim 1 further comprising the step, before depositing step (g), of precleaning the exposed region with an agent containing hydrofluoric acid and with a plasma treatment.
Claim 9
Dependent Claim
73 words
A method according to claim 1 wherein the semiconductor device is a CMOS device, and wherein a plurality of the tungsten contacts are fabricated over a plurality of said regions, said regions being divided into pairs of said regions, each pair of regions defining a source and a drain for a respective semiconductor element, and wherein a polysilicon gate is deposited on said oxide layer between each pair of source and drain regions.
Claim 10
Dependent Claim
100 words
A method according to claim 8, wherein a first pair of source and drain regions is initially doped with an N+dopant and is disposed in a P doped well in the substrate which is N doped, and during the implantation step (e) an N dopant is implanted into the first pair of source and drain regions, and wherein a second pair of source and drain regions is initially doped with a P+dopant and is disposed in the N doped substrate, and during the implantation step (e) a P dopant is implanted into the second pair of source and drain regions.
Claim 11
Independent Claim
109 words
A method of fabricating a tungsten contact in a semiconductor device, which method comprises the steps of: (a) providing an oxide layer on a region of a silicon substrate; (b) depositing a dielectric layer over the oxide layer; (c) etching through the dielectric layer and the oxide layer as far as the substrate thereby to form a contact hole and to expose said region; (d) implanting a dopant into said region whereby the implanted dopant is self-aligned to the contact hole; (e) thermally annealing the substrate; (f) selectively depositing tungsten in the contact hole to form a tungsten contact; and (g) depositing an interconnect layer over the tungsten contact.
Claim 12
Independent Claim
109 words
A method of fabricating a tungsten contact in a semiconductor device, which method comprises the steps of: (a) providing an oxide layer on a region of a silicon substrate; (b) depositing a dielectric layer over the oxide layer; (c) etching through the dielectric layer and the oxide layer as far as the substrate thereby to form a contact hole and to expose said region; (d) implanting a dopant into said region whereby the implanted dopant is self-aligned to the contact hole; (e) thermally annealing the substrate; (f) selectively depositing tungsten in the contact hole to form a tungsten contact; and (g) depositing an interconnect layer over the tungsten contact.
Claim 13
Dependent Claim
15 words
A method according to claim 10 wherein the thermal annealing is a rapid thermal anneal.
Claim 14
Dependent Claim
22 words
A method according to claim 10 wherein the dielectric layer comprises a lower sealing dielectric layer and an upper interlevel dielectric layer.
Claim 15
Dependent Claim
32 words
A method according to claim 12 wherein the sealing dielectric layer is provided at the interface between the oxide layer and the silicon substrate thereby to prevent tungsten encroachment along the interface.
Claim 16
Dependent Claim
27 words
A method according to claim 12 wherein the sealing dielectric layer is composed of silicon nitride and the interlevel dielectric layer is composed of a reflowable material.
Claim 17
Dependent Claim
51 words
A method according to claim 10 wherein said region is initially doped with a dopant of the same conductivity as the dopant which is implanted in step (d), and in step (d) the implantation is carried out so as to implant the dopant deeper into the substrate than the initial dopant.
Claim 18
Dependent Claim
30 words
A method according to claim 10 further comprising the step, before depositing step (f), of precleaning the exposed region with an agent containing hydrofluoric acid and with a plasma treatment.
Claim 19
Dependent Claim
39 words
A method according to claim 1 wherein the sealing dielectric layer is provided at the interface between the silicon substrate and the oxide layer so as to impede lateral diffusion of tungsten into said interface during deposition step (g).
Claim 20
Dependent Claim
40 words
A method according to claim 1 further comprising the step (i), after step (h), of etching the interconnect layer to form an interconnect layer portion over the tungsten contact, the interconnect layer portion being non-overlapping on sides of the contact.
Claim 21
Dependent Claim
36 words
A method according to claim 18 wherein in the etching step (i) the interconnect layer is etched with an etch system having a selectivity to tungsten so that less than 2000 Angstroms of tungsten is removed.
Claim 22
Dependent Claim
28 words
A method according to claim 3 wherein the oxide layer comprises a gate oxide layer and the sealing layer has a thickness of from 200 to 600 Angstroms.
Claim 23
Dependent Claim
30 words
A method according to claim 1 wherein encroachment of tungsten from the contact along the interface between the oxide layer and the silicon substrate is up to about 0.1 microns.
Claim 24
Dependent Claim
39 words
A method according to claim 12 wherein the sealing dielectric layer is provided at the interface between the silicon substrate and the oxide layer so as to impede lateral diffusion of tungsten into said interface during deposition step (f).
Claim 25
Dependent Claim
40 words
A method according to claim 10, further comprising the step (h), after step (g), of etching the interconnect layer to form an interconnect layer portion over the tungsten contact, the interconnect layer portion being non-overlapping on sides of the contact.
Claim 26
Dependent Claim
36 words
A method according to claim 23 wherein in the etching step (h) the interconnect layer is etched with an etch system having a selectivity to tungsten so that less than 2000 Angstroms of tungsten is removed.
Claim 27
Dependent Claim
13 words
A method according to claim 12 wherein the sealing layer comprises silicon nitride.
Claim 28
Dependent Claim
28 words
A method according to claim 12 wherein the oxide layer comprises a gate oxide layer and the sealing layer has a thickness of from 200 to 600 Angstroms.
Claim 29
Dependent Claim
30 words
A method according to claim 10, wherein encroachment of tungsten from the contact along an interface between the oxide layer and the silicon substrate is up to about 0.1 microns.
References Cited (Backward Citations)
GB1208030A
Cited
US4028717A
Cited
US4169270A
Cited
GB1574582A
Cited
EP0008928A1
Cited
US4271582A
Cited
US4385308A
Cited
US4560582A
Cited
US4507853A
Cited
US4520041A
Cited
US4592802A
Cited
US4710241A
Cited
US4878096A
Cited
US4740883A
Cited
US4764248A
Cited
GB2206234A
Cited
US4764484A
Cited
US5231055A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1998-06-05 | 1998-12-05 | 1999-06-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-06-05 | 2002-12-05 | 2003-06-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-06-05 | 2006-12-05 | 2007-06-06 | $7700.00 | Window Closed / Lapsed |