Patent US5339068A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5339068A Expired / Lapsed US ⏱️ 0.0 years remaining

Conductive chip-type ceramic element and method of manufacture thereof

Assignee: Mitsubishi Materials Corp
•
Filing: 1993-06-18
•
Granted: 1994-08-16
•
Expires: 2013-06-18
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A chip-type ceramic element contains a terminal electrode at each end and an inorganic insulating layer on the surface of the ceramic element between the electrodes. The terminal electrodes include a baked electrode formed from a conductive paste reacted with the material of the inorganic insulating layer. Layers of nickel and tin are plated on the baked electrode for improved heat resistance and soldering adhesion, respectively. The insulating layer prevents unwanted portions of the terminal electrodes from coming into contact with the ceramic element, thereby preventing dispersion in the resistance values of the element.

Inventors

  • 👤 Masakiyo Tsunoda
  • 👤 Hiroaki Nakajima
  • 👤 Masami Koshimura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 12:39
CPC Classifications
H; H01; H01C; H01C17/00; H01C17/28; H01C1/00; H01C1/02; H01C1/14; H01C1/142

Claims Analysis

Total Claims: 48
Claim 1
Independent Claim 82 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; and said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste.
Claim 2
Dependent Claim 82 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; and said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste.
Claim 3
Dependent Claim 46 words
A chip-type element according to claim 1, said insulating layer includes: at least 50% by weight SiO 2 ; and a remainder being at least one oxide selected from the group consisting of Al 2 O 3 , MgO, ZrO 2 , and TiO 2 .
Claim 4
Dependent Claim 100 words
A chip-type element according to claim 1, wherein said insulating layer includes at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O PbO, ZnO and BaO; said chip-type element further comprising: said conductive paste including a binding material; and said conductive paste including at least one oxide selected form the group consisting of SiO 2 , B 2 O 3 , Na 2 O, PbO, ZnO, TiO 2 , K 2 O and BaO; said conductive paste having been heated to a temperature to react with said insulating layer.
Claim 5
Dependent Claim 15 words
A chip-type element according to claim 2, wherein said insulating layer is a crystallized glass.
Claim 6
Dependent Claim 15 words
A chip-type element according to claim 3, wherein said insulating layer is a crystallized glass.
Claim 7
Dependent Claim 112 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste; and each said terminal electrode includes a second layer of nickel on said baked electrode layer; and each said terminal further includes a third layer of tin on said second layer.
Claim 8
Dependent Claim 112 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste; and each said terminal electrode includes a second layer of nickel on said baked electrode layer; and each said terminal further includes a third layer of tin on said second layer.
Claim 9
Dependent Claim 96 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; wherein said insulating layer covers an entire surface of said ceramic body except for portions of said ceramic body covered by each of said terminal electrodes; each said terminal electrode including a first layer contacting said ceramic body; and said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste.
Claim 10
Dependent Claim 96 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; wherein said insulating layer covers an entire surface of said ceramic body except for portions of said ceramic body covered by each of said terminal electrodes; each said terminal electrode including a first layer contacting said ceramic body; and said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste.
Claim 11
Dependent Claim 30 words
A chip-type element according to claim 5, wherein said insulating layer is 0.1 to 6 μm thick, thin enough to permit substantial absorption during formation of said baked electrode layer.
Claim 12
Dependent Claim 15 words
A chip-type element according to claim 5, wherein said insulating layer is a crystallized glass.
Claim 13
Dependent Claim 99 words
A chip-type element according to claim 5, further comprising: a conductive inner electrode in electrical contact with each of said opposing end surfaces; said insulating layer covering said conductive inner electrode; said baked electrode layer covering said conductive inner electrode and at least a portion a portion of said insulating layer on sides of said conductive ceramic body; means for electrically connecting said conductive inner electrode to said baked electrode layer through said insulating layer; and said means for electrically connecting including openings in said insulating layer produced by reaction of said insulating layer with said baked electrode layer.
Claim 14
Dependent Claim 24 words
A chip-type element according to claim 10, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste.
Claim 15
Dependent Claim 31 words
A chip-type element according to claim 10, wherein said terminal electrode includes: a layer of nickel on said baked electrode layer; and a layer of tin on said layer of nickel.
Claim 16
Dependent Claim 17 words
A chip-type element according to claim 12, wherein said insulating layer is 0.1 to 10 μm thick.
Claim 17
Dependent Claim 46 words
A chip-type element according to claim 12, said insulating layer includes: at least 50% by weight SiO 2 ; and a remainder being at least one oxide selected from the group consisting of Al 2 O 3 , MgO, ZrO 2 , and TiO 2 .
Claim 18
Dependent Claim 37 words
A chip-type element according to claim 12, wherein said insulating layer comprises at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O PbO, ZnO and BaO.
Claim 19
Dependent Claim 52 words
A chip-type element according to claim 12, further comprising: said conductive paste including a binding material; and said binding material including at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O, PbO, ZnO, TiO 2 , K 2 O and BaO.
Claim 20
Dependent Claim 24 words
A chip-type element according to claim 12, wherein said conductive inner electrode includes substantially no wrapping area about peripheral surfaces of said ceramic body.
Claim 21
Dependent Claim 17 words
A chip-type element according to claim 17, wherein said insulating layer is 6 to 10 μm thick.
Claim 22
Dependent Claim 24 words
A chip-type element according to claim 12, wherein said conductive inner electrode includes a substantial wrapping area over peripheral surfaces of said ceramic body.
Claim 23
Dependent Claim 51 words
A chip-type element according to claim 19, further comprising: said terminal electrode including an outer electrode over said at least one layer; said conductive inner electrode having a first wrapping area; said outer electrode having a second wrapping area; and said first wrapping area being larger than said second wrapping area.
Claim 24
Dependent Claim 94 words
A chip-type element according to claim 12, further comprising: said insulating layer including at least 50% by weight SiO 2 ; a remainder of said insulating layer being at least one oxide selected from the group consisting of Al 2 O 3 , MgO, ZrO 2 , and TiO 2 ; said conductive paste including a binding material; and said binding material including at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O, PbO, ZnO, TiO 2 , K 2 O and BaO.
Claim 25
Dependent Claim 81 words
A chip-type element according to claim 12, further comprising: said insulating layer including at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O PbO, ZnO and BaO; said conductive paste including a binding material; and said binding material including at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O, PbO, ZnO, TiO 2 , K 2 O and BaO.
Claim 26
Dependent Claim 189 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; said means for electrically connecting including openings in said insulating layer produced by reaction of said insulating layer with said baked electrode layer; said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste; said insulating layer including at least 50% by weight SiO 2 ; a remainder of said insulating layer being at least one oxide selected from the group consisting of Al 2 O 3 , MgO, ZrO 2 , and TiO 2 ; said conductive paste including a binding material; and said binding material including at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O, PbO, ZnO, TiO 2 , K 2 O and BaO.
Claim 27
Dependent Claim 189 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; said means for electrically connecting including openings in said insulating layer produced by reaction of said insulating layer with said baked electrode layer; said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste; said insulating layer including at least 50% by weight SiO 2 ; a remainder of said insulating layer being at least one oxide selected from the group consisting of Al 2 O 3 , MgO, ZrO 2 , and TiO 2 ; said conductive paste including a binding material; and said binding material including at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O, PbO, ZnO, TiO 2 , K 2 O and BaO.
Claim 28
Dependent Claim 152 words
A chip-type element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste; said insulating layer including at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O PbO, ZnO and BaO; said conductive paste including a binding material; and said binding material including at least one oxide selected form the group consisting of SiO 2 , B 2 O 3 , Na 2 O, PbO, ZnO, TiO 2 , K 2 O and BaO.
Claim 29
Dependent Claim 152 words
A chip-type element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste; said insulating layer including at least one oxide selected from the group consisting of SiO 2 , B 2 O 3 , Na 2 O PbO, ZnO and BaO; said conductive paste including a binding material; and said binding material including at least one oxide selected form the group consisting of SiO 2 , B 2 O 3 , Na 2 O, PbO, ZnO, TiO 2 , K 2 O and BaO.
Claim 30
Dependent Claim 148 words
A chip-type element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; and said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste; a conductive inner electrode on each of said opposing end surfaces; said insulating layer covering said conductive inner electrode; said baked electrode layer covering a portion of said insulating layer; and means for electrically connecting said conductive inner electrode to said baked electrode layer; said means for electrically connecting including openings in said insulating layer produced by reaction of said insulating layer with said baked electrode layer.
Claim 31
Dependent Claim 148 words
A chip-type element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; and said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste; a conductive inner electrode on each of said opposing end surfaces; said insulating layer covering said conductive inner electrode; said baked electrode layer covering a portion of said insulating layer; and means for electrically connecting said conductive inner electrode to said baked electrode layer; said means for electrically connecting including openings in said insulating layer produced by reaction of said insulating layer with said baked electrode layer.
Claim 32
Dependent Claim 103 words
A chip-type ceramic element comprising; a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; and said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste, and wherein a melting point of said insulating layer is higher than a temperature used to form said baked electrode layer.
Claim 33
Dependent Claim 103 words
A chip-type ceramic element comprising; a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first layer contacting said ceramic body; and said first layer being a baked electrode layer, wherein said baked electrode layer is a burned combination of said insulating material and a conductive paste, and wherein a melting point of said insulating layer is higher than a temperature used to form said baked electrode layer.
Claim 34
Dependent Claim 89 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a baked electrode layer; at least a portion of said baked electrode being a baked combination of said insulating material and a conductive paste; and said conductive paste being a combination of a metal powder and an inorganic binding material.
Claim 35
Dependent Claim 89 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a baked electrode layer; at least a portion of said baked electrode being a baked combination of said insulating material and a conductive paste; and said conductive paste being a combination of a metal powder and an inorganic binding material.
Claim 36
Dependent Claim 30 words
chip-type element according to claim 27, further comprising: a plating electrode on each said terminal electrode; and said plating electrode including a layer of nickel and a layer of tin.
Claim 37
Dependent Claim 96 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first inner electrode layer; each said terminal electrode including a second baked electrode layer; said baked electrode layer being a baked combination of said insulating material and a conductive paste; and said conductive paste being a combination of a metal powder and an inorganic binding material.
Claim 38
Dependent Claim 96 words
A chip-type ceramic element comprising: a conductive ceramic body having opposing end surfaces; a terminal electrode covering each of said opposing end surfaces; an insulating layer made from an inorganic insulating material; said insulating layer covering at least a portion of said ceramic body; each said terminal electrode including a first inner electrode layer; each said terminal electrode including a second baked electrode layer; said baked electrode layer being a baked combination of said insulating material and a conductive paste; and said conductive paste being a combination of a metal powder and an inorganic binding material.
Claim 39
Dependent Claim 20 words
A chip-type element according to claim 29, wherein said inner electrode does not overlap peripheral surfaces of said ceramic body.
Claim 40
Dependent Claim 30 words
A chip-type element according to claim 30, further comprising: an plating electrode on each said terminal electrode; and said plating electrode including a layer of nickel and layer of tin.
Claim 41
Dependent Claim 20 words
A chip-type element according to claim 25, wherein said inner electrode does overlap said edge on to said ceramic body.
Claim 42
Dependent Claim 38 words
A chip-type element according to claim 32, further comprising: said inner electrode layer including a first wrapping area; said baked electrode layer including a second wrapping area; and said second wrapping area being smaller than first wrapping area.
Claim 43
Independent Claim 68 words
A method of producing a chip-type element comprising: burning a chip to produce a ceramic body; covering at least peripheral sides of said ceramic body with an insulating material; applying a conductive paste to a wrapping portion of said insulating material at opposing end surfaces of said body; and reacting said conductive paste with said insulating layer to form an electrode in electrical contact with each said portion.
Claim 44
Independent Claim 68 words
A method of producing a chip-type element comprising: burning a chip to produce a ceramic body; covering at least peripheral sides of said ceramic body with an insulating material; applying a conductive paste to a wrapping portion of said insulating material at opposing end surfaces of said body; and reacting said conductive paste with said insulating layer to form an electrode in electrical contact with each said portion.
Claim 45
Dependent Claim 34 words
A method for producing a chip-type element according to claim 34 further comprising: plating a first layer of nickel on said electrode; and plating a second layer of tin on said layer of nickel.
Claim 46
Dependent Claim 36 words
A method for producing a chip-type element according to claim 34, wherein, following said step of burning, the method further includes placing a conductive metal on each of said opposing end surfaces of said ceramic body.
Claim 47
Dependent Claim 18 words
A method for producing a chip-type element according to claim 34, wherein said step of covering includes sputtering.
Claim 48
Dependent Claim 20 words
A method for producing a chip-type element according to claim 34, wherein said step of covering includes physical vapor deposition.

References Cited (Backward Citations)

US4780702A Cited
US4984130A Cited
US4924205A Cited
US4992771A Cited
US5111117A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-08-15 1998-02-14 1998-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-08-15 2002-02-14 2002-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-08-15 2006-02-14 2006-08-16 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag