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US5324686A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of manufacturing semiconductor device using hydrogen as a diffusion controlling substance

Assignee: Toshiba Corp
•
Filing: 1992-10-09
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Granted: 1994-06-28
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Expires: 2012-10-09
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Abstract

Abstract A method of manufacturing a semiconductor device, which comprises the steps of forming a solid phase diffusion source containing a conductive impurity on a surface of a semiconductor substrate, said impurity serving to enable said semiconductor substrate to exhibit a p-type or n-type conductivity, allowing said solid phase diffusion source to contain a diffusion control substance serving to reduce or oxidize said conductive impurity upon heating so as to change the diffusion coefficient of the conductive impurity contained in the solid phase diffusion source, and thermally diffusing the conductive impurity from the solid phase diffusion source into the semiconductor substrate.

Inventors

  • 👤 Yoshitaka Tsunashima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 18:34
CPC Classifications
H; H10; H10D; H10D30/00; H10D30/01; H10D30/021; H10D30/0223; H10D30/0227; H10D1/00; H10D1/01; H10D1/045; H10D1/047; H10D30/60; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/694; H10P14/6943; H10P14/69433; H10P32/00; H10P32/10; H10P32/14; H10P32/1408; H10P32/141; H10P32/17; H10P32/171; H10P32/19

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 128 words
A method of manufacturing a semiconductor device, comprising the steps of: forming, on a surface of a semiconductor substrate, a solid phase diffusion source layer including a first region containing a conductive impurity of n-type and a second region containing a conductive impurity of n-type and hydrogen as a diffusion control substance which serves to decrease the diffusion coefficient of said conductive impurity in said second region of the solid phase diffusion source layer; and thermally diffusing, in an inert atmosphere, the conductive impurity from said solid phase diffusion source layer into said semiconductor substrate, thereby forming a shallower impurity region under said second region of the solid phase diffusion source layer and a deeper impurity region under said first region of the solid phase diffusion source layer.
Claim 2
Independent Claim 128 words
A method of manufacturing a semiconductor device, comprising the steps of: forming, on a surface of a semiconductor substrate, a solid phase diffusion source layer including a first region containing a conductive impurity of n-type and a second region containing a conductive impurity of n-type and hydrogen as a diffusion control substance which serves to decrease the diffusion coefficient of said conductive impurity in said second region of the solid phase diffusion source layer; and thermally diffusing, in an inert atmosphere, the conductive impurity from said solid phase diffusion source layer into said semiconductor substrate, thereby forming a shallower impurity region under said second region of the solid phase diffusion source layer and a deeper impurity region under said first region of the solid phase diffusion source layer.
Claim 3
Dependent Claim 29 words
A method of manufacturing a semiconductor device according to claim 1, wherein said hydrogen is introduced into said solid phase diffusion source layer by means of an ion implantation.
Claim 4
Dependent Claim 17 words
A method of manufacturing a semiconductor device according to claim 1, wherein said n-type impurity is arsenic.
Claim 5
Dependent Claim 72 words
A method of manufacturing a semiconductor device according to claim 1, wherein said solid phase diffusion source layer is formed so as to also contain, in addition to said n-type impurity, a p-type impurity which is harder to be reduced with hydrogen than said n-type impurity, thereby during said diffusion step forming a double diffusion region consisting of a p-type impurity region and a n-type impurity region in said p-type impurity region.
Claim 6
Dependent Claim 23 words
A method of manufacturing a semiconductor device according to claim 4, wherein said n-type impurity is arsenic and said p-type impurity is boron.
Claim 7
Independent Claim 120 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a solid phase diffusion source layer containing a conductive impurity of n-type on a surface of a semiconductor substrate; selectively forming, on the surface of said solid phase diffusion source layer, a CVD-silicon nitride layer pattern containing hydrogen as a diffusion control substance which serves to cause reduction of the conductive impurity upon heating so as to change the diffusion coefficient of said conductive impurity in the solid phase diffusion source layer; and thermally diffusing, in an inert atmosphere, the conductive impurity from said solid phase diffusion source layer into said semiconductor substrate, thereby forming a shallower impurity region and a deeper impurity region at the same time.
Claim 8
Independent Claim 120 words
A method of manufacturing a semiconductor device, comprising the steps of: forming a solid phase diffusion source layer containing a conductive impurity of n-type on a surface of a semiconductor substrate; selectively forming, on the surface of said solid phase diffusion source layer, a CVD-silicon nitride layer pattern containing hydrogen as a diffusion control substance which serves to cause reduction of the conductive impurity upon heating so as to change the diffusion coefficient of said conductive impurity in the solid phase diffusion source layer; and thermally diffusing, in an inert atmosphere, the conductive impurity from said solid phase diffusion source layer into said semiconductor substrate, thereby forming a shallower impurity region and a deeper impurity region at the same time.
Claim 9
Dependent Claim 17 words
A method of manufacturing a semiconductor device according to claim 6, wherein said n-type impurity is arsenic.
Claim 10
Dependent Claim 72 words
A method of manufacturing a semiconductor device according to claim 6, wherein said solid phase diffusion source layer is formed so as to also contain, in addition to said n-type impurity, a p-type impurity which is harder to be reduced with hydrogen than said n-type impurity, thereby during said diffusion step forming a double diffusion region consisting of a p-type impurity region and a n-type impurity region in said p-type impurity region.
Claim 11
Dependent Claim 23 words
A method of manufacturing a semiconductor device according to claim 8, wherein said n-type impurity is arsenic and said p-type impurity is boron.
Claim 12
Dependent Claim 41 words
A method of manufacturing a semiconductor device according to claim 6, wherein said CVD-silicon nitride layer pattern is removed after said step of thermally diffusing is performed, and then followed by a further step of thermally diffusing under an oxygen-containing atmosphere.

References Cited (Backward Citations)

JPS52154341A Cited
EP0041786A1 Cited
JPS5778134A Cited
US4571366A Cited
DE3235588A1 Cited
US4490192A Cited
US4597824A Cited
US5173440A Cited

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