US5264278A — Radiation-curable acrylate/silicone pressure-sens…

Claim 1

Independent Claim 403 words

A pressure-sensitive adhesive tape comprising: (a) a pressure-sensitive adhesive layer comprising a polymerized pressure sensitive adhesive composition wherein said pressure sensitive adhesive composition comprises: (I) about 25 to about 99 weight percent of polymer of the formula ##STR16## wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different; Y are divalent linking groups which can be the same or different; D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl; R are divalent hydrocarbon groups which can be the same or different; R 1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R 2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R 3 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; R 4 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; n is an integer of about 200 to about 1000; (II) about 1 to about 75 weight percent free radically polymerizable vinyl monomer which is capable of copolymerizing with the polymer wherein said free radically polymerizable monomer comprises: (i) about 5 to about 100 parts by weight of an acidic monomer selected from the group consisting of methacrylic acid, acrylic acid, and mixtures thereof; (ii) correspondingly about 0 to about 95 parts by weight of an acrylate monomer selected from the group consisting of esters of acrylic acid comprising 4 to 21 carbon atoms and esters of methacrylic acid comprising 5 to 21 carbon atoms and mixtures thereof; based upon 100 parts total by weight of said free radically polymerizable monomer; wherein the weight percentages set forth in elements (I) and (II) are based upon the total weight of the polymer of element (I) plus the monomer of element (II); and (III) about 80 to about 200 parts per 100 parts by weight of the polymer of element (I) of a silicate MQ tackifying resin; and (b) a foam layer which is coated on at least one side with the adhesive layer.

Claim 2

Dependent Claim 403 words

A pressure-sensitive adhesive tape comprising: (a) a pressure-sensitive adhesive layer comprising a polymerized pressure sensitive adhesive composition wherein said pressure sensitive adhesive composition comprises: (I) about 25 to about 99 weight percent of polymer of the formula ##STR16## wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different; Y are divalent linking groups which can be the same or different; D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl; R are divalent hydrocarbon groups which can be the same or different; R 1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R 2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R 3 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; R 4 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; n is an integer of about 200 to about 1000; (II) about 1 to about 75 weight percent free radically polymerizable vinyl monomer which is capable of copolymerizing with the polymer wherein said free radically polymerizable monomer comprises: (i) about 5 to about 100 parts by weight of an acidic monomer selected from the group consisting of methacrylic acid, acrylic acid, and mixtures thereof; (ii) correspondingly about 0 to about 95 parts by weight of an acrylate monomer selected from the group consisting of esters of acrylic acid comprising 4 to 21 carbon atoms and esters of methacrylic acid comprising 5 to 21 carbon atoms and mixtures thereof; based upon 100 parts total by weight of said free radically polymerizable monomer; wherein the weight percentages set forth in elements (I) and (II) are based upon the total weight of the polymer of element (I) plus the monomer of element (II); and (III) about 80 to about 200 parts per 100 parts by weight of the polymer of element (I) of a silicate MQ tackifying resin; and (b) a foam layer which is coated on at least one side with the adhesive layer.

Claim 3

Dependent Claim 34 words

The tape of claim 1 wherein said pressure sensitive adhesive composition further comprises at least one of the additives selected from the group consisting of a filler, a crosslinker, and a free radical initiator.

Claim 4

Dependent Claim 30 words

The tape of claim 1 wherein said pressure sensitive adhesive composition further comprises about 0.1 to about 5 weight percent of an initiator based upon the weight of said composition.

Claim 5

Dependent Claim 11 words

The tape of claim 3 wherein said initiator is a photoinitiator.

Claim 6

Dependent Claim 68 words

The tape of claim 1 wherein said pressure sensitive adhesive composition further comprises about 2 to about 30 weight percent, based upon the weight of the adhesive composition, of polymer of the formula ##STR17## wherein p is an integer of about 35 to about 199; and X, Y, D, R, R 1 , R 2 , R 3 , and R 4 are as defined in claim 1.

Claim 7

Dependent Claim 147 words

The tape of claim 1 wherein X comprises ##STR18## R 5 is selected from the group consisting of hydrogen and --COOH; R 6 is selected from the group consisting of hydrogen, methyl, and --CH 2 COOH; n is an integer of about 200 to about 1000; R is selected from the group consisting of alkylene of one to about 12 carbon atoms, alkyl arylene, and arylene; R 1 and R 2 are independently selected from the group consisting of alkyl of one to about 12 carbon atoms, substituted alkyl of one to about 12 carbon atoms, aryl, and substituted aryl; R 3 and R 4 are at least 50% methyl with the remainder selected from the group consisting of alkyl of about 2 to about 12 carbon atoms, substituted alkyl of about 2 to about 12 carbon atoms, vinyl, aryl, and substituted aryl; and D is hydrogen.

Claim 8

Dependent Claim 41 words

The tape of claim 1 wherein n is an integer of about 200 to about 1000, R is alkylene of one to about 12 carbon atoms, and R 1 , R 2 , R 3 , and R 4 are methyl.

Claim 9

Dependent Claim 40 words

The tape of claim 1 wherein X comprises ##STR19## Y comprises ##STR20## D═H; R comprises --CH 2 CH 2 CH 2 --; and R 1 , R 2 , R 3 , and R 4 each comprise --CH 3 .

Claim 10

Dependent Claim 42 words

The tape of claim 1 wherein X comprises CH 2 ═CH--; Y comprises ##STR21## D═H; R comprises --CH 2 CH 2 CH 2 --; and R 1 , R 2 , R 3 , and R 4 each comprise --CH 3 .

Claim 11

Dependent Claim 42 words

The tape of claim 1 wherein X comprises CH 2 ═CH--; Y comprises ##STR22## D═H; R comprises --CH 2 CH 2 CH 2 --; and R 1 , R 2 , R 3 , and R 4 each comprise --CH 3 .

Claim 12

Dependent Claim 39 words

The tape of claim 1 wherein X comprises ##STR23## Y comprises ##STR24## D═H, R comprises --CH 2 CH 2 CH 2 --; and R 1 , R 2 , R 3 and R 4 each comprise --CH 3 .

Claim 13

Dependent Claim 39 words

The tape of claim 1 wherein X comprises ##STR25## Y comprises ##STR26## D═H, R comprises --CH 2 CH 2 CH 2 --; and R 1 , R 2 , R 3 and R 4 each comprise --CH 3 .

Claim 14

Dependent Claim 116 words

The tape of claim 1 which further comprises about 2 to about 30 weight percent, based upon the total weight of said composition, of a compound of the formula ##STR27## wherein q is an integer selected from the group consisting of 0 and 1; s is an integer selected from the group consisting of 1, 2 and 3; r is an integer of about 35 to about 700; R 7 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, alkoxy, alkylamino, hydroxyl, aryl, and substituted aryl; and X, Y, D, R, R 2 , R 3 , and R 4 are as defined in claim 1.

Claim 15

Dependent Claim 33 words

The tape of claim 1 wherein said pressure sensitive adhesive composition further comprises about 0.05 to about 2 weight percent of a multifunctional acrylate monomer based upon the total weight of said composition.

Claim 16

Dependent Claim 32 words

The tape of claim 1 wherein said pressure sensitive adhesive composition further comprises about 5 to about 100 parts by weight tackifier per 100 parts by weight free radically polymerizable vinyl monomer.

Claim 17

Dependent Claim 30 words

The tape of claim 15 wherein said tackifier is selected from the group consisting of rosin acids, rosin esters, synthetic aromatic resins, synthetic aliphatic resins, terpene resins, and mixtures thereof.

Claim 18

Dependent Claim 18 words

The tape of claim 1 wherein said pressure sensitive adhesive composition further comprises inert gas bubbles dispersed throughout.

Claim 19

Dependent Claim 27 words

The tape of claim 1 wherein said pressure sensitive adhesive composition further comprises microbubbles selected from the group consisting of glass microbubbles, plastic microbubbles, and mixtures thereof.

Claim 20

Dependent Claim 31 words

The tape of claim 1 wherein said pressure sensitive adhesive composition further comprises about 0.5 to about 15 weight percent of silica filler based upon the total weight of said composition.

Claim 21

Dependent Claim 391 words

A pressure-sensitive adhesive tape comprising: (a) a pressure-sensitive adhesive layer comprising a polymerized pressure sensitive adhesive composition wherein said pressure sensitive adhesive composition comprises: (I) about 80 to about 95 weight percent of polymer of the formula ##STR28## wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different; Y are divalent linking groups which can be the same or different; D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl; R are divalent hydrocarbon groups which can be the same or different; R 1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R 2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R 3 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; R 4 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; n is an integer of about 200 to about 1000; (II) about 5 to about 20 weight percent free radically polymerizable vinyl monomer which is capable of copolymerizing with the polymer wherein said free radically polymerizable monomer comprises: (i) about 10 to 100 parts by weight of an acidic monomer selected from the group consisting of methacrylic acid, acrylic acid, and mixtures thereof; (ii) correspondingly about 0 to 90 parts be weight of an acrylate monomer selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, hexyl acrylate, heptyl acrylate, isooctyl acrylate, and mixtures thereof; based upon the weight of said free radically polymerizable monomer; wherein the weight percentages set forth in elements (I) and (II) are based upon the total weight of the polymer of element (I) plus the monomer of element (II); and (III) about 80 to about 150 parts per 100 parts by weight of the polymer of element (I) of a silicate MQ tackifying resin; and (b) a foam layer which is coated on at least one side with the adhesive layer.

Claim 22

Dependent Claim 391 words

A pressure-sensitive adhesive tape comprising: (a) a pressure-sensitive adhesive layer comprising a polymerized pressure sensitive adhesive composition wherein said pressure sensitive adhesive composition comprises: (I) about 80 to about 95 weight percent of polymer of the formula ##STR28## wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different; Y are divalent linking groups which can be the same or different; D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl; R are divalent hydrocarbon groups which can be the same or different; R 1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R 2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R 3 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; R 4 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; n is an integer of about 200 to about 1000; (II) about 5 to about 20 weight percent free radically polymerizable vinyl monomer which is capable of copolymerizing with the polymer wherein said free radically polymerizable monomer comprises: (i) about 10 to 100 parts by weight of an acidic monomer selected from the group consisting of methacrylic acid, acrylic acid, and mixtures thereof; (ii) correspondingly about 0 to 90 parts be weight of an acrylate monomer selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, hexyl acrylate, heptyl acrylate, isooctyl acrylate, and mixtures thereof; based upon the weight of said free radically polymerizable monomer; wherein the weight percentages set forth in elements (I) and (II) are based upon the total weight of the polymer of element (I) plus the monomer of element (II); and (III) about 80 to about 150 parts per 100 parts by weight of the polymer of element (I) of a silicate MQ tackifying resin; and (b) a foam layer which is coated on at least one side with the adhesive layer.

Claim 23

Dependent Claim 18 words

A pressure-sensitive adhesive tape according to claim 1 wherein said foam layer comprises an ultraviolet-radiation polymerized acrylic copolymer.

Claim 24

Dependent Claim 75 words

A pressure-sensitive adhesive tape according to claim 21 wherein said ultraviolet-radiation polymerized acrylic copolymer comprises a) from about 80 parts to about 99 parts of an alkyl acrylate monomer, the alkyl groups of which have an average of 4 to 14 carbon atoms, and b) correspondingly, from about 20 parts to about 1 part of a monoethylenically unsaturated strongly polar copolymerizable monomer, and c) from about 0.01 part to about 1 part of a photoinitiator.

Claim 25

Dependent Claim 52 words

A pressure-sensitive adhesive tape having a foam layer according to claim 21 wherein said ultraviolet-radiation polymerized acrylic copolymer comprises from about 95 parts to about 99 parts by weight of said alkyl acrylate monomer, and correspondingly, from about 5 parts to about 1 part by weight of said strongly polar copolymerizable monomer.

Claim 26

Dependent Claim 15 words

The pressure-sensitive adhesive tape of claim 20 wherein said alkyl acrylate monomer is isooctyl acrylate.

Claim 27

Dependent Claim 26 words

The pressure-sensitive adhesive tape of claim 20 wherein said foam layer comprises a polymeric material selected from the group consisting of polyacrylates, neoprene, polyolefin, and polyurethane.

Claim 28

Dependent Claim 38 words

The tape of claim 1 wherein the free radically polymerizable monomer comprises about 5 to about 15 parts by weight of said acidic monomer and correspondingly about 95 to about 85 parts by weight of said acrylate monomer.

Claim 29

Dependent Claim 38 words

The tape of claim 1 wherein the free radically polymerizable monomer comprises about 95 to about 100 parts by weight of said acidic monomer and correspondingly about 5 to about 0 parts by weight of said acrylate monomer.

Claim 30

Dependent Claim 21 words

The tape of claim 1 wherein the free radically polymerizable monomer comprises about 100 parts by weight of said acidic monomer.

Claim 31

Dependent Claim 20 words

The pressure-sensitive adhesive tape of claim 25 wherein said polyolefin is selected from the group consisting of polyethylene and polypropylene.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1996-11-22	1997-05-24	1997-11-23	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	2000-11-22	2001-05-24	2001-11-23	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	2004-11-22	2005-05-24	2005-11-23	$7700.00	Window Closed / Lapsed

Radiation-curable acrylate/silicone pressure-sensitive adhesive coated tapes adherable to paint coated substrates

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