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EP0170219A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Dental image formation and organosiloxane

Assignee: Dentsply Sirona Inc
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Filing: 1985-07-26
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Granted: —
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Expires: 2005-07-26
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Abstract

Abstract Disclosed in the present application is a method of curing a dental impression material by passing actinic light through a tray while the tray is in contact with the impression making composition, a new dental impression composition that is polymerizable by having an initiator activated by actinic light within the visible light range of 360 to 600 nanometers, a new composition of matter that is a compound having at least two terminal acrylate unsaturations and an organosilicone containing backbone and a new method of forming dental prosthetics by directly forming against the soft tissue of the oral cavity and then setting with visible light curing.

Inventors

  • 👤 Emery W. Dougherty
  • 👤 Wu-Lan Wang

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 19:05
CPC Classifications
A; A61; A61C; A61C9/00; A61K; A61K6/00; A61K6/90; C; C08; C08L; C08L83/00; C08L83/04; C08L83/06; A61F; A61F2/00; A61F2/0004

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 104 words
A method of forming a dental impression in the oral cavity comprising A. engaging composition that is flowable and at least substantially free of memory with a surface in the oral cavity that is to have its dental impression taken, including forcing a tray of said composition toward the surface until some of said composition flows to assure good engagement of said composition with the surface; and B. maintaining said tray in contact with said composition and passing actinic light through at least an integral part of said tray photopolymerizing said composition to a degree that said composition assumes a permanent elastomeric remembered form.
Claim 2
Independent Claim 104 words
A method of forming a dental impression in the oral cavity comprising A. engaging composition that is flowable and at least substantially free of memory with a surface in the oral cavity that is to have its dental impression taken, including forcing a tray of said composition toward the surface until some of said composition flows to assure good engagement of said composition with the surface; and B. maintaining said tray in contact with said composition and passing actinic light through at least an integral part of said tray photopolymerizing said composition to a degree that said composition assumes a permanent elastomeric remembered form.
Claim 3
Dependent Claim 110 words
The method of Claim 1 wherein said actinic light, except for ambient light, is substantially limited to the visible light spectrum of about 360 to about 600 nanometers, said tray passes actinic light through the majority of its mass to said composition, and said composition is substantially stable against assuming a permanent remembered form when stored actinic light free and is substantially non-adhering to tooth enamel when changed from said flowable to said remembered form by exposure to actinic light and in said remembered form being deformable in response to pressure applied by the human hand to pull off of teeth retaining the remembered shape of the teeth in detail.
Claim 4
Independent Claim 57 words
The method of any one of Claims 1 and 2 wherein said composition comprising a polysiloxane that is photopolymerized at least in part through photo-cross-linking of two pendent C-C-double bonds, said polysiloxane comprises organosiloxane with two pendent C-C-double bonds prior to photopolymerizing and said composition prior to said photopolymerizing is substantially free of sites for condensation polymerization.
Claim 5
Independent Claim 143 words
The method of forming a dental impression of any one of Claims 1 through 3 wherein said composition comprising a compound that has at least two acryl ethylenic unsaturated pendant groups that polymerize through free radical reaction, said compound having the general formula x = O to n y = O to n R = la, 2a, or 3a R 1 = H , alkyl, sub alkyl, F, CN, aryl, sub aryl. R 2 = alkylene, sub alkylene, arylene, sub arylene. B = An organic radical substituent; n = 1 or more; and it being further understood that the backbone of the compound of the general formula may be a homopolymer of A or B or an alternate block or random block copolymer of A or B and A and/or B may be the same or different for each n within the compound.
Claim 6
Dependent Claim 76 words
The method of Claim 4 wherein said dental impression composition includes at least two polyorganosiloxane compounds, a first polyorganosiloxane containing not more than 3 polymerizable acryl groups, and a second polyorganosiloxane containing at least 3 acryl groups, and in said general formula y is O and said first and said second polyorganosiloxanes are according to said general formula and x, for the first polyorgansiloxane is 2 to 20,000 and for the second polyorganosiloxane 2 to 10,000.
Claim 7
Dependent Claim 129 words
The method of Claim 5 wherein said dental impression composition includes at least about 20% by weight, exclusive of filler, of compounds according to said general formula and at least about one half of said 20% is of compounds wherein y=o and said first polyorganosiloxane has the formula R 3 = a saturated alkylene, sub alkylene, ary, sub arylene. R 3 may be the same or different. h = 1 to n and said second polyorganosiloxane has the formula j and m = 1 to n k = O to n u = 1 to n v = O to n Siloxane radicals with u, k and v exponents can repeat, alternately forming multiple blocks, the blocks can be the same or different powers of u, k and v.
Claim 8
Dependent Claim 128 words
A new composition of matter suitable for use in the practice of the methods of any one of Claims 1 and 2, said composition comprising a compound of the general formula x = 1 to n y = O to n R = la, 2a, or 3a R 1 = H, alkyl, sub alkyl, F, CN, aryl, sub aryl, R; R 2 = alkylene, sub alkylene, arylene, sub arylene; B = an organic radical substituent; n = 1 or more it being further understood that the backbone of the compound of the general formula may be a homopolymer of A or an alternate block or random block copolymer of A or B and A and/or B may be the same or different for each n within the compound.
Claim 9
Dependent Claim 45 words
The new composition of matter of Claim 7 wherein said compounds general formula provides that y=o and said general formula is R 3 = a saturated alkylene, sub alkylene, ary, sub arylene. R 3 may be the same or different h = 1 to n
Claim 10
Dependent Claim 71 words
The new composition of matter of Claim 7 wherein said compounds general formula provides that y=o and said general formula is j and m = 1 to n k = O to n u = 1 to n v = 0 to n Siloxane radicals with u, k and v exponents can repeat', alternately forming multiple blocks, the blocks can be the same or different powers of u, k and v.
Claim 11
Dependent Claim 194 words
The new composition of matter of Claim 7 wherein said compound is included in a composition and has no more than 3 terminal acrylates and another compound according to Claim 11 is present in said compositon and has 3 or more terminal acrylates, said compound that has no more than 3 terminal acrylates has two terminal acrylates and wherein said compound that has two terminal acrylates has the formula y=o and said formula is R 3 = a saturated alkylene, sub alkylene, ary, sub arylene. R 3 may be the same or different h = 1 to n and said other compound that has three or more terminal acrylates has the formula wherein y=o and said formula is j and m = 1 to n k = O to n u = 1 to n v = O to n Siloxane radicals with u, k and v exponents can repeat, alternately forming multiple blocks, the blocks can be the same or different powers of u, k and v and said new composition of matter of comprising an initiator activated by actinic light within the visible light range of about 360 to about 600 nanometers.
Claim 12
Independent Claim 106 words
A method of forming a dental prosthetic part comprising A. engaging composition that is flowable and at least substantially free of memory with a surface in the oral cavity that is to be reproduced as a negative dental prosthetic part of said surface, B. forcing said composition against the surface until some of said composition flows into good conformity with said surface to form said composition into an accurate negative impression of said surface, and C. impinging actinic light on said negative impression and D. photopolymerizing said composition to a degree that said composition assumes a permanent elastomeric remembered form of the negative of said surface.
Claim 13
Independent Claim 106 words
A method of forming a dental prosthetic part comprising A. engaging composition that is flowable and at least substantially free of memory with a surface in the oral cavity that is to be reproduced as a negative dental prosthetic part of said surface, B. forcing said composition against the surface until some of said composition flows into good conformity with said surface to form said composition into an accurate negative impression of said surface, and C. impinging actinic light on said negative impression and D. photopolymerizing said composition to a degree that said composition assumes a permanent elastomeric remembered form of the negative of said surface.
Claim 14
Dependent Claim 42 words
The method of Claim 11 wherein said composition is carried on the surface of a removable denture that is to be juxtaposed against tissues of the oral cavity when said composition is forced toward said surface and said tissue is said surface.
Claim 15
Dependent Claim 100 words
The method of Claim 12 wherein said actinic light, except for ambient light, is substantially limited to the visible light spectrum of about 360 to about 600 nanometers, said composition is substantially stable against assuming a permanent remembered form when stored actinic light free, non-toxic in use in the oral cavity, is stable in storage for at least one (1) month as a one-component composition when actinic light free, and assumes a permanent elastomeric memory when exposed to light filtered to limited wave lengths within the visible light range for one (1) minute to a depth of one (1) inch.
Claim 16
Independent Claim 58 words
The method of any one of Claims 11, 12 and 13 wherein said composition is photopolymerized at least in part through photo-cross-linking of two pendent C-C-double bonds on polysiloxane compounds and said composition prior to said photopolymerizing is substantially free of sites for condensation polymerization, and said composition is at least about 20% polysiloxane compound exclusive of filler.
Claim 17
Independent Claim 143 words
The method of forming a dental prosthetic of any one of Claims 11 through 14 wherein said composition comprising a compound that has at least two acryl ethylenic unsaturated pendant groups that polymerized through free radical reaction, said compound having the general formula x = O to n y = 0 to n R = la, 2a, or 3a R 1 = H , alkyl, sub alkyl, F, CN, aryl, sub aryl, R; R 2 = alkylene, sub alkylene, arylene, sub arylene; B = an organic radical; n = 1 or more; and it being further understood that the backbone of the compound of the general formula may be a homopolymer of A or B or an alternate block or random block copolymer of A or B and A and/or B may be the same or different for each n within the compound.
Claim 18
Dependent Claim 203 words
The method of Claim 15 wherein said dental prosthesis composition includes at least two polyorganosiloxane compounds, a first polyorganosiloxane containing not more than 3 polymerizable acryl groups, and a second polyorganosiloxane containing at least 3 acryl groups and wherein in said general formula y is O and said first and said second polyorganosiloxanes are according to said general formula and x, for the first polyorgansiloxane is 2 to 20,000 and for the second polyorganosiloxane 2 to 10,000 and wherein said dental prosthesis composition includes at least about 20% by weight, exclusive of filler, of compounds according to said general formula and at least about one half of said 20% is of compounds wherein y=o and said first polyorganosiloxane has the formula R 3 = a saturated alkylene, sub alkylene, ary, sub arylene. R 3 may be the same or different h = 1 to n; and said second polyorganosiloxane has the general formula j and m = 1 to n k = O to n u = 1 to n v = O to n siloxane radicals with u, k and v exponents can repeat, alternately forming multiple blocks, the blocks can be the same or different powers of u, k and v.

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