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US5235017A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluorine containing silicone polyester compounds

Assignee: Siltech Corp
•
Filing: 1992-08-26
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Granted: 1993-08-10
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Expires: 2012-08-26
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Abstract

Abstract The invention discloses novel fluorine containing polyester compounds. Compounds of the invention by virtue of (a) the silicone containing polyester group, (b) the fluorine containing terminal groups and (c) the polyoxyalkylene containing dimethicone copolyol group are extremely efficient lubricating materials when applied to a variety of surfaces and are water dispersible or water soluble depending upon the specific molecule. These materials have a water soluble portion in the silicone backbone which allows for the preparation of water dispersible and water soluble fluorine containing compounds useful in personal care applications as conditioners and softeners. The compounds of the present invention are prepared by reacting a dimethicone copolyol compound with a dicarboxylic acid and a fluorine containing alcohol.

Inventors

  • 👤 Anthony J. O'Lenick, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:12
CPC Classifications
A; A61; A61Q; A61Q5/00; A61Q5/12; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61K8/89; A61K8/896; A61K8/897; C; C08; C08G; C08G63/00; C08G63/68; C08G63/682; C08G63/6824; C08G63/695; C08G63/6954; C08G77/00; C08G77/42; C08G77/445; C08G77/46

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 141 words
A fluorine containing silicone polyester compound which is prepared by the esterification reaction of; (a) a dimethicone copolyol compound conforming to the following structure; ##STR12## wherein; R 1 is selected from the group consisting of CH 3 and phenyl; EO is --(CH 2 --CH 2 --O--)-- PO is --(--CH 2 --CH(CH 3 )--O--)-- o is an integer ranging from 1 to 20; q is an integer ranging from 0 to 200; x, y and z are independently integers each ranging from 0 to 20; (b) a diacid selected from the group consisting of HO(O)C--(CH 2 ) c --C(O)OH, HO(O)C--(CH 2 ) d --CH═CH--(CH 2 ) e --C(O)OH and dimer acid; c, d and e are independently integers from 1 to 10; and (c) a fluorine containing hydroxy compound conforming to the following structure; ##STR13## n is ranges from 3 to 17.
Claim 2
Dependent Claim 141 words
A fluorine containing silicone polyester compound which is prepared by the esterification reaction of; (a) a dimethicone copolyol compound conforming to the following structure; ##STR12## wherein; R 1 is selected from the group consisting of CH 3 and phenyl; EO is --(CH 2 --CH 2 --O--)-- PO is --(--CH 2 --CH(CH 3 )--O--)-- o is an integer ranging from 1 to 20; q is an integer ranging from 0 to 200; x, y and z are independently integers each ranging from 0 to 20; (b) a diacid selected from the group consisting of HO(O)C--(CH 2 ) c --C(O)OH, HO(O)C--(CH 2 ) d --CH═CH--(CH 2 ) e --C(O)OH and dimer acid; c, d and e are independently integers from 1 to 10; and (c) a fluorine containing hydroxy compound conforming to the following structure; ##STR13## n is ranges from 3 to 17.
Claim 3
Dependent Claim 19 words
A compound of claim 1 wherein the fluorine content in the compound ranges from 5% to 30% by weight.
Claim 4
Dependent Claim 19 words
A compound of claim 1 wherein the fluorine content in the compound ranges from 10% to 25% by weight.
Claim 5
Dependent Claim 11 words
A compound of claim 1 wherein the diacid is dimer acid.
Claim 6
Dependent Claim 11 words
A compound of claim 1 wherein the diacid is dodecanedioic acid.
Claim 7
Dependent Claim 11 words
A compound of claim 1 wherein x+y+z is greater than zero.
Claim 8
Dependent Claim 12 words
A compound of claim 1 wherein n ranges from 3 to 11.
Claim 9
Dependent Claim 9 words
A compound of claim 1 wherein n is 3.
Claim 10
Dependent Claim 9 words
A compound of claim 1 wherein n is 5.
Claim 11
Dependent Claim 9 words
A compound of claim 1 wherein n is 7.
Claim 12
Dependent Claim 9 words
A compound of claim 1 wherein n is 9.
Claim 13
Dependent Claim 9 words
A compound of claim 1 wherein n is 11.
Claim 14
Dependent Claim 9 words
A compound of claim 1 wherein n is 13.
Claim 15
Dependent Claim 9 words
A compound of claim 1 wherein n is 15.
Claim 16
Dependent Claim 9 words
A compound of claim 1 wherein n is 17.

References Cited (Backward Citations)

US3038000A Cited
US4937277A Cited
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US5164471A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-08-09 1997-02-08 1997-08-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-08-09 2001-02-08 2001-08-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-08-09 2005-02-08 2005-08-10 $7700.00 Window Closed / Lapsed

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