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Use of organometallic compounds to deposit thin films from the gas phase

Assignee: Merck Patent GmbH
•
Filing: 1990-03-03
•
Granted: 1993-05-11
•
Expires: 2010-03-03
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Abstract

Abstract The invention relates to the use of organometallic compounds containing, as metals, aluminum, gallium or indium for the deposition of thin films or epitactic layers from the gas phase.

Inventors

  • 👤 Dietrich Erdmann
  • 👤 Ludwig Pohl
  • 👤 Martin Hostalek

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:08
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C30; C30B; C30B25/00; C30B25/02; C07; C07F; C07F5/00; C23C16/301; C30B29/00; C30B29/10; C30B29/40

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 315 words
In a process for the deposition of epitactic layers employing an organometallic compound for the deposition of thin films or layers form the gas phase, the improvement comprising said organometallic compound being a compound of formula I (R.sup.1).sub.3-n M--Y.sub.n I, wherein M is aluminum, alllium or indium; n is 1, 2 or 3; Y is --NR 2 R 3 , --RP 2 R 3 , --ASR 2 R 3 ; R 1 , R 2 , R 4 and R 5 , in each case independently of one another, are H, an alkyl group having 1-8 C atoms, where the alkyl group may be partly or fully fluorinated, a cycloalkyl, alkenyl or cycloalkenyl group, in each case having 3-8 C atoms, or an aryl group, R 1 is alternatively 1,2--(CH 2 ) p --C 6 H 4 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 10 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q --Z, or 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --Z; p and q, in each case independently of one another, are 0, 1, 2 or 3; Z is --NR 4 R 5 , --PR 4 R 5 , --AsR 4 R 5 or --SbR 4 R 5 ; and is a branched alkyl or alkenyl group, in each case having 3-8 C atoms, it being possible for these groups to be partly or fully fluorinated, a cycloalkyl or cycloalkenyl group, in each case having 3,-8 C atoms, or an aryl group.
Claim 2
Dependent Claim 315 words
In a process for the deposition of epitactic layers employing an organometallic compound for the deposition of thin films or layers form the gas phase, the improvement comprising said organometallic compound being a compound of formula I (R.sup.1).sub.3-n M--Y.sub.n I, wherein M is aluminum, alllium or indium; n is 1, 2 or 3; Y is --NR 2 R 3 , --RP 2 R 3 , --ASR 2 R 3 ; R 1 , R 2 , R 4 and R 5 , in each case independently of one another, are H, an alkyl group having 1-8 C atoms, where the alkyl group may be partly or fully fluorinated, a cycloalkyl, alkenyl or cycloalkenyl group, in each case having 3-8 C atoms, or an aryl group, R 1 is alternatively 1,2--(CH 2 ) p --C 6 H 4 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 10 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q --Z, or 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --Z; p and q, in each case independently of one another, are 0, 1, 2 or 3; Z is --NR 4 R 5 , --PR 4 R 5 , --AsR 4 R 5 or --SbR 4 R 5 ; and is a branched alkyl or alkenyl group, in each case having 3-8 C atoms, it being possible for these groups to be partly or fully fluorinated, a cycloalkyl or cycloalkenyl group, in each case having 3,-8 C atoms, or an aryl group.
Claim 3
Dependent Claim 12 words
A process according to claim 1, for the deposition of epitactic layers.
Claim 4
Dependent Claim 310 words
In a process for the preparation of thin films on substrates by gas-phase deposition from an organometallic compounds, the improvement comprising said organometallic compound being a compound of formula I (R.sup.1).sub.3-n M--Y.sub.n I, wherein M is aluminum, gallium or indium; n is 1, 2 or 3; is --NR 2 R 3 , --PR 2 R 3 , --AsR 2 R 3 or --SbR 2 R 3 ; R 1 , R 2 , R 4 and R 5 , in each case independently of one another, are H, an alkyl group having 1-8 C atoms, where the alkyl group may be partly or fully fluorinated, a cycloalkyl, alkenyl or cycloalkenyl group, in each case having 3-8 C atoms, or an aryl group, R 1 is alternatively 1,2--(CH 2 ) p --C 6 H 4 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 10 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --Z; p and q, in each case independently of one another, are 0, 1, 2 or 3; is --NR 4 R 5 , --PR 4 R 5 , --AsR 4 R 5 or --SbR 4 R 5 ; and is a branch alkyl or alkenyl group, in each case having 3-8 C atoms, it being possible for these groups to be partly or fully fluorinated, a cycloalkyl or cycloalkenyl group, in each case having 3-8 C atoms, or an aryl group.
Claim 5
Dependent Claim 310 words
In a process for the preparation of thin films on substrates by gas-phase deposition from an organometallic compounds, the improvement comprising said organometallic compound being a compound of formula I (R.sup.1).sub.3-n M--Y.sub.n I, wherein M is aluminum, gallium or indium; n is 1, 2 or 3; is --NR 2 R 3 , --PR 2 R 3 , --AsR 2 R 3 or --SbR 2 R 3 ; R 1 , R 2 , R 4 and R 5 , in each case independently of one another, are H, an alkyl group having 1-8 C atoms, where the alkyl group may be partly or fully fluorinated, a cycloalkyl, alkenyl or cycloalkenyl group, in each case having 3-8 C atoms, or an aryl group, R 1 is alternatively 1,2--(CH 2 ) p --C 6 H 4 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 10 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --Z; p and q, in each case independently of one another, are 0, 1, 2 or 3; is --NR 4 R 5 , --PR 4 R 5 , --AsR 4 R 5 or --SbR 4 R 5 ; and is a branch alkyl or alkenyl group, in each case having 3-8 C atoms, it being possible for these groups to be partly or fully fluorinated, a cycloalkyl or cycloalkenyl group, in each case having 3-8 C atoms, or an aryl group.
Claim 6
Dependent Claim 41 words
A process according to claim 3, wherein, to produce compound semiconductors, electric, electronic, optical or optoelectronic components, one or more arsenic, antimony or phosphorus compounds in which are gaseous under the reaction conditions used are additionally added during the deposition process.
Claim 7
Dependent Claim 23 words
A process according to claim 3, wherein, in addition to the organometallic compounds of formula I, dopes are added during the deposition process.
Claim 8
Dependent Claim 22 words
A process according to claim 3, wherein the compounds of formula I are added during the deposition process of other organometallic compounds.
Claim 9
Dependent Claim 12 words
A process according to claim 3, wherein M is gallium or indium.
Claim 10
Dependent Claim 14 words
A process according to claim 3, wherein Y is --NR 2 R 3 .
Claim 11
Dependent Claim 19 words
A process according to claim 3, wherein Y is --PR 2 R 3 or --AsR 2 R 3 .
Claim 12
Dependent Claim 10 words
A process according to claim 3, wherein n is 1.
Claim 13
Dependent Claim 39 words
A process according to claim 3, wherein M is gallium or indium; Y is --NR 2 R 3 , PR 2 R 3 , PR 2 R 3 , or --AsR 2 R 3 ; and n is 1.
Claim 14
Dependent Claim 136 words
A process according to claim 3, wherein is 1,2--(CH 2 ) p --C 6 H 4 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 10 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --Z, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q --Z, or 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --Z; Z is --NR 4 R 5 or --AsR 4 R 5 ; and p and q are each independently 0, 1, or 2.
Claim 15
Dependent Claim 11 words
A process according to claim 1, wherein R 1 is ##STR3##
Claim 16
Dependent Claim 18 words
A process according to claim 3, wherein R 3 is a branched alkyl group having 3-8 C atoms.
Claim 17
Dependent Claim 34 words
A process according to claim 3, wherein R 1 and R 2 , are each a straight-chain or branched alkyl group having C 1 -C 8 atoms which are optionally partly or fully fluorinated.
Claim 18
Dependent Claim 29 words
A process according to claim 12, wherein R 2 is a straight-chain or branched alkyl group having C 1 -C 8 atoms which is optionally partly or fully fluorinated.

References Cited (Backward Citations)

EP0052979A1 Cited
WO1986003228A1 Cited
EP0251555A1 Cited
EP0331448A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-05-10 1996-11-09 1997-05-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-05-10 2000-11-09 2001-05-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-05-10 2004-11-09 2005-05-11 $7700.00 Window Closed / Lapsed

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