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US5135838A Expired / Lapsed US ⏱️ 0.0 years remaining

Resist materials

Assignee: Nokia Bell Labs
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Filing: 1990-08-09
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Granted: 1992-08-04
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Expires: 2010-08-09
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Abstract

Abstract A class of resist compositions sensitive to deep ultraviolet radiation includes a resin sensitive to acid and a composition that generates acid upon exposure to such radiation. A group of nitrobenzyl materials is particularly suitable for use as the acid generator.

Inventors

  • 👤 Francis M. Houlihan
  • 👤 Thomas X. Neenan
  • 👤 Elsa Reichmanis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 14:18
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/039; Y; Y10; Y10S; Y10S430/00; Y10S430/146

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 168 words
A process for fabricating a device comprising the steps of forming a radiation sensitive region on a substrate exposing at least a portion of said region to radiation to produce a latent pattern, developing said pattern, and using said patterned region as a mask to further process said device characterized in that said radiation sensitive region comprises a material including 1) a polymeric material that undergoes a reaction in response to an acid moiety and 2) an acid generating material represented by the formula ##STR9## where R is not acidic and does not substantially absorb ultraviolet light, and R' provides suitable steric and electron withdrawing characteristics such that an acid generator with a given Y has enhanced thermal stability relative to said acid generator with the same Y when R' is NO 2 and R is hydrogen and wherein Y is chosen such that it requires a temperature of at least 75° C. to induce splitting of said Y moiety from the remainder of said acid generating material.
Claim 2
Dependent Claim 168 words
A process for fabricating a device comprising the steps of forming a radiation sensitive region on a substrate exposing at least a portion of said region to radiation to produce a latent pattern, developing said pattern, and using said patterned region as a mask to further process said device characterized in that said radiation sensitive region comprises a material including 1) a polymeric material that undergoes a reaction in response to an acid moiety and 2) an acid generating material represented by the formula ##STR9## where R is not acidic and does not substantially absorb ultraviolet light, and R' provides suitable steric and electron withdrawing characteristics such that an acid generator with a given Y has enhanced thermal stability relative to said acid generator with the same Y when R' is NO 2 and R is hydrogen and wherein Y is chosen such that it requires a temperature of at least 75° C. to induce splitting of said Y moiety from the remainder of said acid generating material.
Claim 3
Dependent Claim 22 words
The process of claim 1 wherein R' is chosen from the group consisting of perfluorinated alkyls, lower alkyls, alkoxides, cyano, or ##STR10##
Claim 4
Dependent Claim 16 words
The process of claim 2 where Y is an alkyl, substituted alkyl, aryl, or substituted aryl.
Claim 5
Dependent Claim 16 words
The process of claim 1 wherein Y is an alkyl, substituted alkyl, aryl, or substituted aryl.
Claim 6
Dependent Claim 11 words
The process of claim 1 wherein-said acid generator comprises bis(2-(trifluoromethyl)-6-nitrobenzyl)1,3-benzene disulfonate.

References Cited (Backward Citations)

US4491628A Cited
US4552833A Cited
US4939070A Cited
US4931379A Cited
US4808511A Cited
US4810613A Cited
US4996136A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-08-04 1996-02-03 1996-08-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-08-04 2000-02-03 2000-08-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-08-04 2004-02-03 2004-08-04 $7700.00 Window Closed / Lapsed

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