Fuel additives derived from amido-amines (PT-731)

Claim 2

A fuel coil composition containing an oil soluble dispersant comprising an adduct of: (A) a long chain hydrocarbyl substituted mono- or dicarboxylic acid producing material formed by reacting an olefin polymer of C 2 to C 10 monoolefin having a number average molecular weight of about 300 to 10,000 and at least one of a C 4 to C 10 monounsaturated dicarboxylic acid material and a C 3 to C 10 monounsaturated monocarboxylic acid material, said acid producing material having an average of at least about 0.3 dicarboxylic acid producing moieties, per molecule of said olefin polymer present in the reaction mixture used to form said acid producing material; and (B) an amido-amine or thioamido-amine characterized by being a reaction product of at least a polyamine and an alpha, beta-unsaturated compound of the formula: ##STR23## wherein X is sulfur or oxygen, Y is --OR 4 , --SR 4 , or --NR 4 (R 5 ), and R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl.

Claim 3

The fuel oil composition according to claim 1, wherein said polyamine comprises amines containing from 2 to 60 carbon atoms and from 2 to 12 nitrogen atoms per molecule.

Claim 4

The fuel oil composition according to claim 2, wherein said polyamine comprises a polyalkylenepolyamine wherein each said alkylene group contains from 2 to 6 carbons and said polyalkylenepolyamine contains from 5 to about 9 nitrogen atoms per molecule.

Claim 5

The fuel oil composition according to claim 1, wherein said hydrocarbyl substituted monounsaturated acid producing material comprises hydrocarbyl substituted C 4 to C 10 monounsaturated dicarboxylic acid producing material which comprises polyisobutylene of about 900 to 5000 number average molecular weight substituted with succinic anhydride moieties, said polyamine comprises polyalkylenepolyamine wherein each said alkylene group contains from 2 to 6 carbons and said polyalkylenepolyamine contains from 5 to 9 nitrogen atoms per molecule, and said alpha, beta-unsaturated compound comprises at least one member selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, and butyl methacrylate.

Claim 6

The fuel oil composition according to claims 1 or 4, wherein said amine comprises polyalkylenepolyamine or polypropyleneamine.

Claim 7

The fuel oil composition according to claims 1 or 4, wherein said olefin polymer comprises polyisobutylene.

Claim 8

The fuel oil composition of claim 5, wherein the ratio of acid producing moieties per molecule of olefin polymer in said dispersant is from about 0.9 to 1.3.

Claim 9

The fuel oil composition of claim 7, wherein said number average molecular weight of said olefin polymer is from about 1300 to 4,000.

Claim 10

The fuel oil composition of claim 1, wherein said monounsaturated acid material comprises maleic anhydride.

Claim 11

The fuel oil composition according to claims 1 or 4 wherein about 1 to 5 moles of said acid producing material per primary nitrogen equivalent of said amido-amine are present in said reaction mixture.

Claim 12

The fuel oil composition according to claims 1 or 4 wherein said polyamine contains an average of at least 2 primary nitrogen atoms per molecule, said X group is oxygen and said polyamine and said alpha, beta unsaturated compound are contacted in an amount of from about 3 to 5 equivalents of said polyamine per mole of said alpha, beta unsaturated compound.

Claim 13

The fuel oil composition according to claim 11 wherein said amido-amine contains an average of from 1 to 3 amido groups per molecule of said amido-amine.

Claim 14

The fuel oil composition according to claims 1 or 4 wherein said polyamine contains an average of at least 2 primary nitrogen atoms per molecule, said X group is sulfur and said polyamine and said alpha, beta unsaturated compound are contacted in an amount of from about 3 to 5 equivalents of said polyamine (based on said primary amine content) per mole of said alpha, beta unsaturated compound.

Claim 15

The fuel oil composition according to claim 13 wherein said amido-amine contains an average of from 1 to 3 amido groups per molecule of said amido-amine.

Claim 16

A fuel oil composition containing from about 0.001 to 0.5 wt. % of a dispersant comprising an adduct of: (A) a long chain hydrocarbyl substituted mono- or dicarboxylic acid producing material formed by reacting an olefin polymer of C 2 to C 10 monoolefin having a number average molecular weight of about 300 to 10,000 and at least one of a C 4 to C 10 monounsaturated dicarboxylic acid material and a C 3 to C 10 monounsaturated monocarboxylic acid material, said acid producing material having an average of at least about 0.3 dicarboxylic acid producing moieties, per molecule of said olefin polymer present in the reaction mixture used to form said acid producing material; and (B) an amido-amine or thioamido-amine characterized by being a reaction producing of at least a polyamine and an alpha, beta-unsaturated compound of the formula: ##STR24## wherein X is sulfur or oxygen, Y is --OR 4 , --SR 4 , or --NR 4 (R 5 ), and R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl.

Claim 17

A fuel oil composition containing from about 0.001 to 0.5 wt. % of a dispersant comprising an adduct of: (A) a long chain hydrocarbyl substituted mono- or dicarboxylic acid producing material formed by reacting an olefin polymer of C 2 to C 10 monoolefin having a number average molecular weight of about 300 to 10,000 and at least one of a C 4 to C 10 monounsaturated dicarboxylic acid material and a C 3 to C 10 monounsaturated monocarboxylic acid material, said acid producing material having an average of at least about 0.3 dicarboxylic acid producing moieties, per molecule of said olefin polymer present in the reaction mixture used to form said acid producing material; and (B) an amido-amine or thioamido-amine characterized by being a reaction producing of at least a polyamine and an alpha, beta-unsaturated compound of the formula: ##STR24## wherein X is sulfur or oxygen, Y is --OR 4 , --SR 4 , or --NR 4 (R 5 ), and R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl.

Claim 18

The fuel oil composition of claim 15 wherein said dispersant concentration is from about 0.001 to 0.1 wt. %.

Claim 19

The fuel oil composition of claim 15 wherein said hydrocarbyl substituted monounsaturated acid producing material comprises hydrocarbyl substituted C 4 to C 10 monounsaturated dicarboxylic acid producing material which comprises polyisobutylene of about 900 to 5000 number average molecular weight substituted with succinic anhydride moieties, said polyamine comprises polyalkylenepolyamine wherein each said alkylene group contains from 2 to 6 carbons and said polyalkylenepolyamine contains from 5 to 9 nitrogen atoms per molecule, and said alpha, beta-unsaturated compound comprises at least one member selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, and butyl methacrylate.