Dispersant additives derived from amido-amines

Claim 2

An oil soluble dispersant mixture useful as an oil additive comprising an adduct of: (A) a long chain hydrocarbyl substituted C 4 to C 10 monounsaturated dicarboxylic acid producing material formed by reacting an olefin polymer of C 2 to C 10 monoolefin having a number average molecular weight of about 300 to 10,000 and a C 4 to C 10 monounsaturated acid material, said acid producing material having an average of at least about 0.8 dicarboxylic acid producing moieties, per molecule of said olefin polymer present in the reaction mixture used to form said acid producing material; and (B) an amido-amine or a thioamido-amine by being a reaction product of at least a polyamine and an alpha, beta-unsaturated compound of the formula: ##STR23## wherein X is sulfur or oxygen, Y is --OR 4 , --SR 4 , or --NR 4 (R 5 ), and R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl.

Claim 3

The dispersant mixture according to claim 1, wherein said polyamine comprises amines containing from 2 to 60 carbon atoms and from 3 to 12 nitrogen atoms per molecule.

Claim 4

The dispersant mixture according to claim 2, wherein said amine comprises a polyalkylenepolyamine wherein said alkylene groups each contain 2 to 6 carbons and said polyalkylenepolyamine contains from 5 to about 9 nitrogen atoms per molecule.

Claim 5

The dispersant mixture according to claim 1, wherein said hydrocarbyl substituted C 4 to C 10 monounsaturated dicarboxylic acid producing material comprises polyisobutylene of about 900 to 5000 number average molecular weight substituted with succinic anhydride moieties, said polyamine comprises polyalkylene-polyamine wherein said alkylene groups contain 2 to 6 carbons and said polyalkylenepolyamine contains 5 to 9 nitrogen atoms per molecule, and said alpha, beta-unsaturated compound comprises at least one member selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, and butyl methacrylate.

Claim 6

The dispersant mixture according to claims 1 or 4, wherein said polyamine comprises polyethylenepolyamine or polypropyleneamine and said dispersant mixture is borated.

Claim 7

The dispersant mixture according to claims 1 or 4, wherein said adduct contains about 0.05 to 2.0 weight percent boron.

Claim 8

The dispersant mixture according to claims 1 or 4, wherein said olefin polymer comprises polyisobutylene.

Claim 9

The dispersant mixture of any one of claims 1 to 5, wherein the ratio of acid producing moieties per molecule of olefin polymer in said dispersant mixture is from about 1.05 to 1.8.

Claim 10

The dispersant mixture of claim 8, wherein said number average molecular weight of said olefin polymer is from about 1300 to 4,000.

Claim 11

The dispersant mixture of claim 1, wherein said monounsaturated acid material comprises maleic anhydride.

Claim 12

The dispersant mixture according to claims 1 or 4 wherein about 1 to 5 moles of said acid producing material dicarboxylic acid moiety content are employed per primary nitrogen equivalent of said amido-amine.

Claim 13

The dispersant mixture according to claims 1 or 4 wherein said polyamine contains an average of at least 2 primary nitrogen atoms per molecule, said X group is oxygen and said polyamine and said alpha, beta-unsaturated compound are contacted in an amount of from about 3 to 5 equivalents of said polyamine (based on said primary amine content) per mole of said alpha, beta-unsaturated compound.

Claim 14

The dispersant mixture according to claim 12 wherein said amido-amine contains an average of from 1 to 3 amido groups per molecule of said amido-amine.

Claim 15

The dispersant mixture according to claims 1 or 4 wherein said polyamine contains an average of at least 2 primary nitrogen atoms per molecule, said X group is sulfur and said polyamine and said alpha, beta-unsaturated compound are contacted in an amount of from about 3 to 5 equivalents of said polyamine (based on said primary amine content) per mole of said alpha, beta-unsaturated compound.

Claim 16

The dispersant mixture according to claim 14 wherein said amido-amine contains an average of from 1 to 3 amido groups per molecule of said amido-amine.

Claim 17

A process for producing a dispersant mixture useful as an oil additive which comprises: (a) providing a hydrocarbyl substituted C 4 to C 10 monoolefin having a number average molecular weight of about 700 to 10,000 and a C 4 to C 10 monounsaturated acid material, said acid producing material having an average of at least about 0.8 dicarboxylic acid producing moieties, per molecule of said olefin polymer present in the reaction mixture used to form said acid producing material; (b) providing an amido-amine compound having at least one primary amino group prepared by reacting at least one polyamine with at least one alpha, beta-unsaturated compound of the formula: ##STR24## wherein X is sulfur or oxygen, Y is --OR 4 , --SR 4 , or --NR 4 (R 5 ), and R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl; and (c) contacting the said acid producing material with said amido-amine compound under conditions sufficient to effect reaction of at least a ortion of the primary amino groups on said amido-amine compound with at least a portion of the acid-producing groups in said acid producing material, to form said dispersant mixture.

Claim 18

A process for producing a dispersant mixture useful as an oil additive which comprises: (a) providing a hydrocarbyl substituted C 4 to C 10 monoolefin having a number average molecular weight of about 700 to 10,000 and a C 4 to C 10 monounsaturated acid material, said acid producing material having an average of at least about 0.8 dicarboxylic acid producing moieties, per molecule of said olefin polymer present in the reaction mixture used to form said acid producing material; (b) providing an amido-amine compound having at least one primary amino group prepared by reacting at least one polyamine with at least one alpha, beta-unsaturated compound of the formula: ##STR24## wherein X is sulfur or oxygen, Y is --OR 4 , --SR 4 , or --NR 4 (R 5 ), and R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl; and (c) contacting the said acid producing material with said amido-amine compound under conditions sufficient to effect reaction of at least a ortion of the primary amino groups on said amido-amine compound with at least a portion of the acid-producing groups in said acid producing material, to form said dispersant mixture.

Claim 19

The process according to claim 16 wherein said polyamine comprises amines containing from 2 to 60 carbon atoms and from 3 to 12 nitrogen atoms per molecule.

Claim 20

The process according to claim 17, wherein said amine comprises a polyalkylenepolyamine wherein said alkylene groups each contain 2 to 40 carbons and said polyalkylenepolyamine contains from 5 to about 9 nitrogen atoms per molecule.

Claim 21

The process according to claim 16, wherein said hydrocarbyl substituted C 4 to C 10 monounsaturated dicarboxylic acid producing material comprises polyisobutylene of about 900 to 5000 number average molecular weight substituted with succinic anhydride moieties, said polyamine comprises polyalkylenepolyamine wherein said alkylene groups contain 2 to 6 carbons and said polyalkylenepolyamine contains 5 to 9 nitrogen atoms per molecule, and said acrylate-type compound comprises at least one member selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, and butyl methacrylate.

Claim 22

The process according to claims 16 or 19, wherein said polyamine comprises polyethylenepolyamine and wherein said dispersant mixture is borated.

Claim 23

The process according to claims 16 or 19, wherein said dispersant mixture is borated to provide from 0.05 to 2.0 weight percent boron in said borated dispersant mixture.

Claim 24

The process of claim 16, wherein the ratio of acid producing moieties per molecule of olefin polymer in said dispersant mixture is from about 1.05 to 1.8.

Claim 25

The process of claim 20, wherein said number average molecular weight of said olefin polymer is from about 1300 to 4,000.

Claim 26

The process of claim 16, wherein said monounsaturated acid material comprises maleic anhydride.

Claim 27

A concentrate containing from about 3 to 45 wt. % of the dispersant mixture of claim 1.

Claim 28

A concentrate containing from about 10 to 35 wt. % of the dispersant mixture of claim 4.

Claim 29

A lubricating oil composition containing from about 0.1 to 20 wt. % of the dispersant mixture prepared according to claim 16.

Claim 30

A process for producing a dispersant useful as an oil additive which comprises: (a) providing a hydrocarbyl substituted C 4 to C 10 monoolefin having a number average molecular weight of about 700 to 10,000 and a C 4 to C 10 monounsaturated acid material, said acid producing material having an average of at least about 0.8 dicarboxylic acid producing moieties, per molecule of said olefin polymer present in the reaction mixture used to form said acid producing material; (b) providing an amido-amine compound having at least one primary amino group prepared by reacting at least one polyamine with at least one alpha, beta-unsaturated compound of the formula: ##STR25## wherein Y is --OR 4 , --SR 4 , or --NR 4 (R 5 ), and R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl; and (c) contacting the said acid producing material with said amido-amine compound under conditions sufficient to effect reaction of at least a portion of the primary amino groups on said amido-amine compound with at least a portion of the acid-producing groups in said acid producing material, to form said dispersant.

Claim 31

A process for producing a dispersant useful as an oil additive which comprises: (a) providing a hydrocarbyl substituted C 4 to C 10 monoolefin having a number average molecular weight of about 700 to 10,000 and a C 4 to C 10 monounsaturated acid material, said acid producing material having an average of at least about 0.8 dicarboxylic acid producing moieties, per molecule of said olefin polymer present in the reaction mixture used to form said acid producing material; (b) providing an amido-amine compound having at least one primary amino group prepared by reacting at least one polyamine with at least one alpha, beta-unsaturated compound of the formula: ##STR25## wherein Y is --OR 4 , --SR 4 , or --NR 4 (R 5 ), and R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl; and (c) contacting the said acid producing material with said amido-amine compound under conditions sufficient to effect reaction of at least a portion of the primary amino groups on said amido-amine compound with at least a portion of the acid-producing groups in said acid producing material, to form said dispersant.

Claim 32

The process according to claim 28 wherein said polyamine comprises amines containing from 2 to 60 carbon atoms and from 3 to 12 nitrogen atoms per molecule.

Claim 33

The process according to claim 29, wherein said amine comprises a polyalkylenepolyamine wherein said alkylene groups each contain 2 to 6 carbons and said polyalkylenepolyamine contains from 5 to about 9 nitrogen atoms per molecule.

Claim 34

The process according to claim 28, wherein said hydrocarbyl substituted C 4 to C 10 monounsaturated dicarboxylic acid producing material comprises polyisobutylene of about 900 to 5000 number average molecular weight substituted with succinic anhydride moieties, said polyamine comprises polyalkylenepolyamine wherein said alkylene groups contain 2 to 6 carbons and said polyalkylenepolyamine contains 5 to 9 nitrogen atoms per molecule, and said acrylate-type compound comprises at least one member selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, and butyl methacrylate.

Claim 35

The process according to claims 28 or 31, wherein said polyamine comprises polyethylenepolyamine and wherein said dispersant is borated.

Claim 36

The process according to claims 28 or 31, wherein said dispersant is borated to provide from about 0.05 to 2.0 weight percent boron in said borated dispersant.

Claim 37

The process according to claim 28, wherein said olefin polymer comprises polyisobutylene.

Claim 38

The process of claim 28, wherein the ratio of acid producing moieties per molecule of olefin polymer in said dispersant is from about 1.05 to 1.8.

Claim 39

The process of claim 32, wherein said number average molecular weight of said olefin polymer is from about 1300 to 4,000.

Claim 40

The process of claim 28, wherein said monounsaturated acid material comprises maleic anhydride.

Claim 41

A lubricating oil composition containing from about 0.1 to 20 wt. % of the dispersant prepared according to claim 28.

Claim 42

The process according to claim 16, wherein said olefin polymer comprises polyisobutylene.