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US5013398A Expired / Lapsed US ⏱️ 0.0 years remaining

Anisotropic etch method for a sandwich structure

Assignee: Micron Technology Inc
•
Filing: 1990-05-29
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Granted: 1991-05-07
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Expires: 2010-05-29
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Abstract

Abstract A plasma etch process to anisotropically etch a sandwich structure of silicon dioxide, polycrystalline silicon, and silicon dioxide "in situ", that is, in a single etch chamber. The silicon dioxide is etched using a SF 6 /CHF 3 /He chemistry. The polycrystalline silicon is etched using a HBr/He chemistry. A non-erodible cathode is used. Tungsten silicide may replace the polycrystalline silicon. Silicon nitride may replace the silicon dioxide.

Inventors

  • 👤 Paul D. Long
  • 👤 Jose J. Guerricabeitia

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 19:03
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/268; H10P50/28; H10P50/282; H10P50/283

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 226 words
A method to etch a sandwich structure of a first layer selected from the group of silicon dioxide and silicon nitride, on a second layer selected from the group of polycrystalline silicon and a refractory metal silicide, on a third layer selected from the group of silicon dioxide and silicon nitride, comprising the steps of: providing a patterned mask layer on the structure, leaving a region of the first layer exposed; providing a plasma etch reactor having a non-erodible electrode and using it for: etching the exposed first layer in a first atmosphere of He and 16:1 to 22:1 CHF 3 :SF 6 , in a 2.0 to 2.6 W/cm 2 plasma, at 400 to 600 mTorr and 15° to 25° C., until the second layer is exposed and a sidewall is formed in the first layer; etching the exposed second layer in a second atmosphere of 3.2:1 to 3.5:1 HBr:He, in a 1.0 to 1.2 W/cm 2 plasma, at 180 to 220 mTorr and 15° to 25° C., until any prograde in said second layer is counteracted; and etching the exposed second layer in a third atmosphere of 1.7:1 to 2.3:1 HBr:He, in a 1.2 to 1.4 W/cm 2 plasma, at 135 to 165 mTorr and 15° to 25° C., until the third layer is exposed and a sidewall is formed in the second layer.
Claim 2
Independent Claim 226 words
A method to etch a sandwich structure of a first layer selected from the group of silicon dioxide and silicon nitride, on a second layer selected from the group of polycrystalline silicon and a refractory metal silicide, on a third layer selected from the group of silicon dioxide and silicon nitride, comprising the steps of: providing a patterned mask layer on the structure, leaving a region of the first layer exposed; providing a plasma etch reactor having a non-erodible electrode and using it for: etching the exposed first layer in a first atmosphere of He and 16:1 to 22:1 CHF 3 :SF 6 , in a 2.0 to 2.6 W/cm 2 plasma, at 400 to 600 mTorr and 15° to 25° C., until the second layer is exposed and a sidewall is formed in the first layer; etching the exposed second layer in a second atmosphere of 3.2:1 to 3.5:1 HBr:He, in a 1.0 to 1.2 W/cm 2 plasma, at 180 to 220 mTorr and 15° to 25° C., until any prograde in said second layer is counteracted; and etching the exposed second layer in a third atmosphere of 1.7:1 to 2.3:1 HBr:He, in a 1.2 to 1.4 W/cm 2 plasma, at 135 to 165 mTorr and 15° to 25° C., until the third layer is exposed and a sidewall is formed in the second layer.
Claim 3
Dependent Claim 36 words
A method according to claim 1, further comprising a final sidewall smoothing etch step in said third atmosphere, in a 0.7 to 0.9 W/cm 2 plasma, at 90 to 110 mTorr and 15° to 25° C.
Claim 4
Independent Claim 190 words
A method to etch a sandwich structure of a first layer selected from the group of silicon dioxide and silicon nitride, on a second layer selected from the group of polycrystalline silicon and a refractory metal silicide, on a third layer selected from the group of silicon dioxide and silicon nitride, comprising the steps of: providing a patterned mask layer on the structure, leaving a region of the first layer exposed; providing a plasma etch reactor having a non-erodible electrode and using it for: etching the exposed first layer in a first atmosphere of an inert carrier gas and 16:1 to 22:1 CHF 3 :SF 6 , until the second layer is exposed and a sidewall is formed in the first layer; etching the exposed second layer in a second atmosphere of 3.2:1 to 3.5:1 HBr:inert assisting gas, until any prograde in said second layer is counteracted; and etching the exposed second layer in a third atmosphere of 1.7:1 to 2.3:1 HBr:inert assisting gas, until the third layer is exposed and a sidewall is formed in the second layer, and said sidewalls of said first and second layers are smoothed.
Claim 5
Independent Claim 190 words
A method to etch a sandwich structure of a first layer selected from the group of silicon dioxide and silicon nitride, on a second layer selected from the group of polycrystalline silicon and a refractory metal silicide, on a third layer selected from the group of silicon dioxide and silicon nitride, comprising the steps of: providing a patterned mask layer on the structure, leaving a region of the first layer exposed; providing a plasma etch reactor having a non-erodible electrode and using it for: etching the exposed first layer in a first atmosphere of an inert carrier gas and 16:1 to 22:1 CHF 3 :SF 6 , until the second layer is exposed and a sidewall is formed in the first layer; etching the exposed second layer in a second atmosphere of 3.2:1 to 3.5:1 HBr:inert assisting gas, until any prograde in said second layer is counteracted; and etching the exposed second layer in a third atmosphere of 1.7:1 to 2.3:1 HBr:inert assisting gas, until the third layer is exposed and a sidewall is formed in the second layer, and said sidewalls of said first and second layers are smoothed.
Claim 6
Dependent Claim 13 words
A method according to claim 3, wherein said inert carrier gas is He.
Claim 7
Dependent Claim 13 words
A method according to claim 3, wherein said inert assisting gas is He.
Claim 8
Dependent Claim 38 words
A method according to claim 3, wherein said etching in said first atmosphere is performed in a 2.0 to 2.6 W/cm 2 plasma, at 400 to 600 mTorr and 15° to 25° C., and includes an overetch step.
Claim 9
Dependent Claim 55 words
A method according to claim 3, wherein said etching in said first atmosphere further comprises: bulk etching, in a 2.0 to 2.6 W/cm 2 plasma, at 400 to 600 mTorr and 15° to 25° C.; and overetching, in a 1.7 to 2.3 W/cm 2 plasma, at 400 to 600 mTorr and 15° to 25° C.
Claim 10
Dependent Claim 38 words
A method according to claim 3, wherein said etching in said third atmosphere is performed in a 1.2 to 1.4 W/cm 2 plasma, at 135 to 165 mTorr and 15° to 25° C., and includes an overetch step.
Claim 11
Dependent Claim 55 words
A method according to claim 3, wherein said etching in said third atmosphere further comprises: bulk etching, in a 1.2 to 1.4 W/cm 2 plasma, at 135 to 165 mTorr, and 15° to 25° C.; and overetching, in a 0.7 to 0.9 W/cm 2 plasma, at 90 to 110 mTorr and 15° to 25° C.
Claim 12
Dependent Claim 33 words
A method according to claim 3, wherein said etching in said second atmosphere is performed in a 1.0 to 1.2 W/cm 2 plasma, at 180 to 220 mTorr and 15° to 25° C.
Claim 13
Independent Claim 165 words
A method to etch a sandwich structure of a first layer selected from the group of silicon dioxide and silicon nitride, on a second layer selected from the group of polycrystalline silicon and a refractory metal silicide, on a third layer selected from the group of silicon dioxide and silicon nitride, comprising the steps of: providing a patterned mask layer on the structure, leaving a region of the first layer exposed; providing a plasma etch reactor having a non-erodible electrode and using it for: etching the exposed first layer in a first atmosphere of an inert carrier gas and 16:1 to 22:1 CHF 3 :SF 6 , until the second layer is exposed and a sidewall is formed in the first layer; and etching the exposed second layer in a second atmosphere of 1.7:1 to 3.5:1 HBr:inert assisting gas, until the third layer is exposed and a sidewall is formed in the second layer, and said sidewalls of the first and second layers are smoothed.
Claim 14
Independent Claim 165 words
A method to etch a sandwich structure of a first layer selected from the group of silicon dioxide and silicon nitride, on a second layer selected from the group of polycrystalline silicon and a refractory metal silicide, on a third layer selected from the group of silicon dioxide and silicon nitride, comprising the steps of: providing a patterned mask layer on the structure, leaving a region of the first layer exposed; providing a plasma etch reactor having a non-erodible electrode and using it for: etching the exposed first layer in a first atmosphere of an inert carrier gas and 16:1 to 22:1 CHF 3 :SF 6 , until the second layer is exposed and a sidewall is formed in the first layer; and etching the exposed second layer in a second atmosphere of 1.7:1 to 3.5:1 HBr:inert assisting gas, until the third layer is exposed and a sidewall is formed in the second layer, and said sidewalls of the first and second layers are smoothed.
Claim 15
Dependent Claim 13 words
A method according to claim 11, wherein said inert carrier gas is He.
Claim 16
Dependent Claim 13 words
A method according to claim 11, wherein said inert assisting gas is He.
Claim 17
Dependent Claim 31 words
A method according to claim 11, wherein said etching in said first atmosphere uses a 1.7 to 2.6 W/cm 2 plasma, at 400 to 600 mTorr and 15° to 25° C.
Claim 18
Dependent Claim 17 words
A method according to claim 11, wherein said etching in said first atmosphere includes an overetch step.
Claim 19
Dependent Claim 31 words
A method according to claim 11, wherein said etching in said second atmosphere uses a 0.7 to 1.4 W/cm 2 plasma, at 90 to 220 mTorr and 15° to 25° C.
Claim 20
Independent Claim 16 words
A method according to claim wherein said etching in said second atmosphere includes an overetch step.

References Cited (Backward Citations)

US4424621A Cited
US4521448A Cited
US4528066A Cited
US4965219A Cited
US4869781A Cited
US4818334A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-05-06 1994-11-05 1995-05-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-05-06 1998-11-05 1999-05-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-05-06 2002-11-05 2003-05-07 $7700.00 Window Closed / Lapsed

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