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Hydrocarbon conversion process including acidic zeolite reactivation

Assignee: Mobil Oil AS
•
Filing: 1988-12-12
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Granted: 1991-03-19
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Expires: 2008-12-12
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Abstract

Abstract A spent acidic zeolite catalyst, e.g., ZSM-5 obtained from a hydrocarbon conversion process such as a catalytic dewaxing operation, is reactivated by contacting the spent catalyst with aqueous alkali metal carbonate and/or alkaline earth metal carbonate.

Inventors

  • 👤 Clarence D. Chang
  • 👤 Cynthia T. W. Chu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 11:29
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/58; C10G45/60; C10G45/64; B; B01; B01J; B01J29/00; B01J29/90; B01J38/00; B01J38/48; B01J38/64

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 171 words
In a hydrocarbon conversion process in which a hydrocarbon is subjected to contact with an acidic intermediate or large pore size zeolite catalyst to produce conversion products and in which the catalyst undergoes a significant loss in acid catalytic activity as a result of accumulating carbonaceous matter during the conversion, the improvement comprising: subjecting the zeolite catalyst with the accumulated carbonaceous material to a burning operation in the presence of an oxygen-containing gas to remove at least a major part of the accumulated carbonaceous material, contacting the catalyst with an effective amount of an aqueous liquid solution of an alkali metal carbonate and/or aqueous alkaline earth metal carbonate at a temperature from 100° to 370° C. for a period of from 1 to 24 hours, subjecting the catalyst to ammonium ion exchange followed by calcination to convert the zeolite to the hydrogen form, under conditions sufficient to restore at least a significant amount of the acid catalytic activity of the fresh zeolite prior to reusing the catalyst in the conversion process.
Claim 2
Dependent Claim 171 words
In a hydrocarbon conversion process in which a hydrocarbon is subjected to contact with an acidic intermediate or large pore size zeolite catalyst to produce conversion products and in which the catalyst undergoes a significant loss in acid catalytic activity as a result of accumulating carbonaceous matter during the conversion, the improvement comprising: subjecting the zeolite catalyst with the accumulated carbonaceous material to a burning operation in the presence of an oxygen-containing gas to remove at least a major part of the accumulated carbonaceous material, contacting the catalyst with an effective amount of an aqueous liquid solution of an alkali metal carbonate and/or aqueous alkaline earth metal carbonate at a temperature from 100° to 370° C. for a period of from 1 to 24 hours, subjecting the catalyst to ammonium ion exchange followed by calcination to convert the zeolite to the hydrogen form, under conditions sufficient to restore at least a significant amount of the acid catalytic activity of the fresh zeolite prior to reusing the catalyst in the conversion process.
Claim 3
Dependent Claim 14 words
The process of claim 1 wherein the zeolite is an intermediate pore size zeolite.
Claim 4
Dependent Claim 10 words
The process of claim 2 wherein the zeolite is ZSM-5.
Claim 5
Dependent Claim 14 words
The process of claim 1 wherein the zeolite is a large pore size zeolite.
Claim 6
Dependent Claim 13 words
The process of claim 1 wherein the zeolite is X, Y or Beta.
Claim 7
Dependent Claim 16 words
The process of claim 1 wherein the zeolite is present in admixture with a matrix material.
Claim 8
Dependent Claim 19 words
The process of claim 1 wherein the zeolite is present in admixture with alumina or an alumina-containing matrix material.
Claim 9
Dependent Claim 17 words
The process of claim 1 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 10
Dependent Claim 27 words
The process of claim 1 wherein contacting of the spent zeolite with aqueous carbonate is carried out with from about 0.001 to about 1 molar aqueous carbonate.
Claim 11
Dependent Claim 19 words
The process of claim 1 wherein the zeolite possesses a Constraint Index of from about 1 to about 12.
Claim 12
Dependent Claim 17 words
The process of claim 1 wherein the zeolite possesses a Constraint Index of less than about 1.
Claim 13
Dependent Claim 17 words
The process of claim 2 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 14
Dependent Claim 17 words
The process of claim 3 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 15
Dependent Claim 17 words
The process of claim 4 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 16
Dependent Claim 17 words
The process of claim 7 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 17
Dependent Claim 17 words
The process of claim 9 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-03-18 1994-09-17 1995-03-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-03-18 1998-09-17 1999-03-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-03-18 2002-09-17 2003-03-19 $7700.00 Window Closed / Lapsed

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