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US5001094A
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Hydrocarbon conversion process including acidic zeolite reactivation
Assignee: Mobil Oil AS
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Filing: 1988-12-12
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Granted: 1991-03-19
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Expires: 2008-12-12
Abstract
Abstract A spent acidic zeolite catalyst, e.g., ZSM-5 obtained from a hydrocarbon conversion process such as a catalytic dewaxing operation, is reactivated by contacting the spent catalyst with aqueous alkali metal carbonate and/or alkaline earth metal carbonate.
Inventors
- 👤 Clarence D. Chang
- 👤 Cynthia T. W. Chu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 11:29
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/58; C10G45/60; C10G45/64; B; B01; B01J; B01J29/00; B01J29/90; B01J38/00; B01J38/48; B01J38/64
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
171 words
In a hydrocarbon conversion process in which a hydrocarbon is subjected to contact with an acidic intermediate or large pore size zeolite catalyst to produce conversion products and in which the catalyst undergoes a significant loss in acid catalytic activity as a result of accumulating carbonaceous matter during the conversion, the improvement comprising: subjecting the zeolite catalyst with the accumulated carbonaceous material to a burning operation in the presence of an oxygen-containing gas to remove at least a major part of the accumulated carbonaceous material, contacting the catalyst with an effective amount of an aqueous liquid solution of an alkali metal carbonate and/or aqueous alkaline earth metal carbonate at a temperature from 100° to 370° C. for a period of from 1 to 24 hours, subjecting the catalyst to ammonium ion exchange followed by calcination to convert the zeolite to the hydrogen form, under conditions sufficient to restore at least a significant amount of the acid catalytic activity of the fresh zeolite prior to reusing the catalyst in the conversion process.
Claim 2
Dependent Claim
171 words
In a hydrocarbon conversion process in which a hydrocarbon is subjected to contact with an acidic intermediate or large pore size zeolite catalyst to produce conversion products and in which the catalyst undergoes a significant loss in acid catalytic activity as a result of accumulating carbonaceous matter during the conversion, the improvement comprising: subjecting the zeolite catalyst with the accumulated carbonaceous material to a burning operation in the presence of an oxygen-containing gas to remove at least a major part of the accumulated carbonaceous material, contacting the catalyst with an effective amount of an aqueous liquid solution of an alkali metal carbonate and/or aqueous alkaline earth metal carbonate at a temperature from 100° to 370° C. for a period of from 1 to 24 hours, subjecting the catalyst to ammonium ion exchange followed by calcination to convert the zeolite to the hydrogen form, under conditions sufficient to restore at least a significant amount of the acid catalytic activity of the fresh zeolite prior to reusing the catalyst in the conversion process.
Claim 3
Dependent Claim
14 words
The process of claim 1 wherein the zeolite is an intermediate pore size zeolite.
Claim 4
Dependent Claim
10 words
The process of claim 2 wherein the zeolite is ZSM-5.
Claim 5
Dependent Claim
14 words
The process of claim 1 wherein the zeolite is a large pore size zeolite.
Claim 6
Dependent Claim
13 words
The process of claim 1 wherein the zeolite is X, Y or Beta.
Claim 7
Dependent Claim
16 words
The process of claim 1 wherein the zeolite is present in admixture with a matrix material.
Claim 8
Dependent Claim
19 words
The process of claim 1 wherein the zeolite is present in admixture with alumina or an alumina-containing matrix material.
Claim 9
Dependent Claim
17 words
The process of claim 1 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 10
Dependent Claim
27 words
The process of claim 1 wherein contacting of the spent zeolite with aqueous carbonate is carried out with from about 0.001 to about 1 molar aqueous carbonate.
Claim 11
Dependent Claim
19 words
The process of claim 1 wherein the zeolite possesses a Constraint Index of from about 1 to about 12.
Claim 12
Dependent Claim
17 words
The process of claim 1 wherein the zeolite possesses a Constraint Index of less than about 1.
Claim 13
Dependent Claim
17 words
The process of claim 2 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 14
Dependent Claim
17 words
The process of claim 3 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 15
Dependent Claim
17 words
The process of claim 4 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 16
Dependent Claim
17 words
The process of claim 7 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
Claim 17
Dependent Claim
17 words
The process of claim 9 wherein the carbonate is one of lithium, sodium, potassium, calcium or magnesium.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-03-18 | 1994-09-17 | 1995-03-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-03-18 | 1998-09-17 | 1999-03-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-03-18 | 2002-09-17 | 2003-03-19 | $7700.00 | Window Closed / Lapsed |