Patent US2180028A successfully refreshed from Google Patents.
Patent US4960579A successfully refreshed from Google Patents.
US4960579A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Membrane process and system for nitrogen production
Assignee: Praxair Technology Inc
•
Filing: 1988-04-01
•
Granted: 1990-10-02
•
Expires: 2008-04-01
Abstract
Abstract On-site membrane systems are used for air separation to produce a low purity nitrogen stream and for purifying impure hydrogen, the nitrogen and hydrogen being passed to a catalytic combustion system in which the oxygen content of the nitrogen stream is reacted with said hydrogen to reduce the residual oxygen content of the nitrogen in a final purification operation to produce high purity nitrogen. Pressure swing adsorption systems can be employed in place of the membrane systems for particular applications, and a cryogenic system can be employed for said hydrogen purification.
Inventors
- 👤 Michael J. Campbell
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 11:40
CPC Classifications
C; C01; C01B; C01B21/00; C01B21/04; B; B01; B01D; B01D53/00; B01D53/02; B01D53/04; B01D53/047; B01D53/22; B01D53/225; B01D53/226; B01D53/229; C01B21/0405; C01B21/0494; B01D2256/00; B01D2256/10; B01D2259/00; B01D2259/40; B01D2259/416; C01B2210/00; C01B2210/0001; C01B2210/0003; C01B2210/0006; C01B2210/0009; C01B2210/0014; C01B2210/0043; C01B2210/0045
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
240 words
An on-site system for the production of high purity nitrogen gas from air comprising: (a) a first membrane or pressure swing adsorption separation system capable of separating air into a partially purified nitrogen stream containing residual oxygen and an oxygen rich discharge stream; (b) means for supplying feed air to said first membrane or pressure swing adsorption separation system for separation therein; (c) a second membrane, pressure swing adsorption or cryogenic separation system capable of separating relatively pure hydrogen from an impure hydrogen stream containing a relatively high level of impurities, so as to produce a purified hydrogen stream having a desirably low level of said impurities; (d) means for supplying impure hydrogen feed gas available on-site to said second membrane, pressure swing adsorption or cryogenic separation system for purification therein; (e) a catalytic combustion system adapted for the reaction of said purified hydrogen stream with residual oxygen present in the partially purified nitrogen stream; (f) means for passing the partially purified nitrogen and purified hydrogen from said first and second separation systems to said catalytic combustion system; and (g) means for recovering a high purity nitrogen gas stream from said catalytic combustion system, said high purity nitrogen having a desirably low residual oxygen content, whereby high purity nitrogen can advantageously be produced on-site by the convenient purification of low cost, impure hydrogen available on-site and the economical use thereof in the final purification of the partially purified nitrogen stream.
Claim 2
Dependent Claim
240 words
An on-site system for the production of high purity nitrogen gas from air comprising: (a) a first membrane or pressure swing adsorption separation system capable of separating air into a partially purified nitrogen stream containing residual oxygen and an oxygen rich discharge stream; (b) means for supplying feed air to said first membrane or pressure swing adsorption separation system for separation therein; (c) a second membrane, pressure swing adsorption or cryogenic separation system capable of separating relatively pure hydrogen from an impure hydrogen stream containing a relatively high level of impurities, so as to produce a purified hydrogen stream having a desirably low level of said impurities; (d) means for supplying impure hydrogen feed gas available on-site to said second membrane, pressure swing adsorption or cryogenic separation system for purification therein; (e) a catalytic combustion system adapted for the reaction of said purified hydrogen stream with residual oxygen present in the partially purified nitrogen stream; (f) means for passing the partially purified nitrogen and purified hydrogen from said first and second separation systems to said catalytic combustion system; and (g) means for recovering a high purity nitrogen gas stream from said catalytic combustion system, said high purity nitrogen having a desirably low residual oxygen content, whereby high purity nitrogen can advantageously be produced on-site by the convenient purification of low cost, impure hydrogen available on-site and the economical use thereof in the final purification of the partially purified nitrogen stream.
Claim 3
Dependent Claim
15 words
The system of claim 1 in which said first separation system comprises a membrane system.
Claim 4
Dependent Claim
15 words
The system of claim 1 in which said second separation system comprises a membrane system.
Claim 5
Dependent Claim
17 words
The system of claim 1 in which both the first and second separation systems comprise membrane systems.
Claim 6
Dependent Claim
24 words
The system of claim 1 in which said first separation system comprises a membrane system and said second separation system comprises a cryogenic system.
Claim 7
Dependent Claim
26 words
The system of claim 1 in which said first separation system comprises a pressure swing adsorption system and said second separation system comprises a cryogenic system.
Claim 8
Dependent Claim
17 words
The system of claim 1 in which said first separation system comprises a pressure swing adsorption system.
Claim 9
Dependent Claim
17 words
The system of claim 1 in which said second separation system comprises a pressure swing adsorption system.
Claim 10
Dependent Claim
18 words
The system of claim 1 in which said first and second separation systems comprise pressure swing adsorption systems.
Claim 11
Dependent Claim
151 words
A process for the on site production of high purity nitrogen gas from air comprising: (a) passing feed air to a first membrane or pressure swing adsorption separation system for separation therein; (b) withdrawing a partially purified nitrogen stream containing residual oxygen and an oxygen rich discharge stream from said first separation system; (c) passing impure hydrogen available on-site to a second membrane, pressure swing adsorption or cryogenic separation system for purification therein; (d) reacting said purified hydrogen with residual oxygen present in said partially purified nitrogen stream in a catalytic combustion system; (e) recovering a high purity nitrogen gas stream from said catalytic combustion system, said high purity nitrogen having a desirably low residual oxygen content, whereby high purity nitrogen can advantageously be produced on-site by the convenient purification of low cost, impure hydrogen available on-site and the economical use thereof in the final purification of the partially purified nitrogen.
Claim 12
Dependent Claim
151 words
A process for the on site production of high purity nitrogen gas from air comprising: (a) passing feed air to a first membrane or pressure swing adsorption separation system for separation therein; (b) withdrawing a partially purified nitrogen stream containing residual oxygen and an oxygen rich discharge stream from said first separation system; (c) passing impure hydrogen available on-site to a second membrane, pressure swing adsorption or cryogenic separation system for purification therein; (d) reacting said purified hydrogen with residual oxygen present in said partially purified nitrogen stream in a catalytic combustion system; (e) recovering a high purity nitrogen gas stream from said catalytic combustion system, said high purity nitrogen having a desirably low residual oxygen content, whereby high purity nitrogen can advantageously be produced on-site by the convenient purification of low cost, impure hydrogen available on-site and the economical use thereof in the final purification of the partially purified nitrogen.
Claim 13
Dependent Claim
15 words
The process of claim 10 in which said first separation system comprises a membrane system.
Claim 14
Dependent Claim
15 words
The process of claim 10 in which said second separation system comprises a membrane system.
Claim 15
Dependent Claim
16 words
The process of claim 10 in which said first and second separation systems comprise membrane systems.
Claim 16
Dependent Claim
24 words
The process of claim 10 in which said first separation system comprises a membrane system and said second separation system comprises a cryogenic system.
Claim 17
Dependent Claim
26 words
The process of claim 10 in which said first separation system comprises a pressure swing adsorption system and said second separation system comprises a cryogenic system.
Claim 18
Dependent Claim
17 words
The process of claim 10 in which said first separation system comprises a pressure swing adsorption system.
Claim 19
Dependent Claim
17 words
The process of claim 10 in which said second separation system comprises a pressure swing adsorption system.
Claim 20
Dependent Claim
18 words
The process of claim 10 in which said first and second separation systems comprise pressure swing adsorption systems.
Claim 21
Dependent Claim
24 words
The process of claim 10 in which the partially purified nitrogen stream has an oxygen content of about 1,000 ppm to about 50,000 ppm.
Claim 22
Dependent Claim
19 words
The process of claim 19 in which said oxygen content is from about 10,000 ppm to about 30,000 ppm.
Claim 23
Dependent Claim
23 words
The process of claim 10 in which said high purity nitrogen stream has a residual oxygen content of less than about 5,000 ppm.
Claim 24
Dependent Claim
17 words
The process of claim 21 in which said residual oxygen content is less than about 1,000 ppm.
References Cited (Backward Citations)
CA529368A
Cited
US1166294A
Cited
US1272181A
Cited
US2582885A
Cited
US2826480A
Cited
US3240554A
Cited
US3215503A
Cited
US3339341A
Cited
US4238204A
Cited
US4367135A
Cited
US4595405A
Cited
US4654063A
Cited
US4645516A
Cited
US4654047A
Cited
US4781907A
Cited
US4814156A
Cited
US4701187A
Cited
JPS646396A
Cited
JPH0241A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-10-01 | 1994-04-02 | 1994-10-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-10-01 | 1998-04-02 | 1998-10-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-10-01 | 2002-04-02 | 2002-10-02 | $7700.00 | Window Closed / Lapsed |