Production of membrane-derived nitrogen from combustion gases

Claim 2

A process for the production of nitrogen, which comprises: (a) combusting a carbonaceous fuel to form a combustion gas comprising nitrogen, carbon dioxide, and oxygen; (b) treating the combustion gas to remove to the extent present particulates, the oxides of sulfur, and the oxides of nitrogen and compressing the treated gas stream with or without water condensation in one or more stages of compression to a pressure sufficient to enable membrane separation of molecular nitrogen from carbon dioxide and oxygen; and (c) contacting the compressed, treated gas stream at a temperature of from about 70° to about 160° F. with at least one membrane preferentially selective to reject nitrogen to yield a permeate comprising carbon dioxide and oxygen and a residue concentrated in nitrogen, said membrane having an oxygen and/or carbon dioxide-to-nitrogen ratio of permeability of from about 2.0 to about 20.0 and there is formed a nitrogen enriched gas stream containing at least 90% by volume nitrogen and no more than about 1 to about 5% by volume oxygen.

Claim 3

A process as claimed in claim 1 in which the membrane is made of a material selected from the group of cellulose acetate resins, silicone polymers, and polysulfones.

Claim 4

A process as claimed in claim 1 in which the combustion gas stream contains particulate matter, and the particulate matter is removed by filtration.

Claim 5

A process as claimed in claim 1 in which the combustion gas stream is passed through membranes preferentially permeable to oxides of sulfur and oxides of nitrogen, and the resultant gas, substantially free of oxides of sulfur and nitrogen, is collected for feed to the nitrogen-separation membrane.

Claim 6

A process as claimed in claim 1 in which the compressed, treated gas stream is introduced to the nitrogen-separation membrane at a pressure of from about 100 psig to about 800 psig.

Claim 7

A process as claimed in claim 5 in which the compressed, treated gas stream is introduced to the nitrogen-separation membrane at a temperature of from about 70° F. to about 160° F.

Claim 8

A process as claimed in claim 6 in which the compressed, treated gas stream is introduced to the nitrogen-separation membrane with a water content of less than 50% relative humidity.

Claim 9

A process as claimed in claim 1 in which the carbonaceous fuel is sweet natural gas, the combustion gas contains, on a dry basis, about 86% by volume nitrogen, about 12% by volume carbon dioxide and about 2% by volume oxygen, and in which there is formed a residue product gas containing about 97% by volume or more of nitrogen, about 2% by volume or less of carbon dioxide and about 1% by volume oxygen.

Claim 10

A membrane-permeation process for producing nitrogen-enriched gas which comprises: (a) combusting a carbonaceous fuel to form a combustion gas comprising, on a dry basis, from about 70 to about 86% by volume nitrogen, from about 4 to about 20% by volume carbon dioxide and from about 0.1 to about 6% by volume oxygen; (b) processing the combustion gas stream in a first stage to remove to the extent present; (i) particulate matter by filtration; and (ii) gas oxides of nitrogen and oxides of sulfur; (c) compressing the treated combustion as to a pressure of about 100 to about 800 psig; (d) introducing the compressed combustion gas stream to a membrane separation zone comprising at least one membrane having an oxygen and/or carbon dioxide-to-nitrogen ratio of permeability of from about 2.0 to about nitrogen ratio of permeability of from about 2.0 to about 20.0 which rejects nitrogen gas to form a nitrogen-enriched gas stream to the preferential passage of oxygen and at a temperature of from about 70° to about 160° F. and above the dew point of water in the compressed combustion gas stream, said nitrogen enriched gas stream containing at least 90% by volume nitrogen and no more than about 1 to about 5% by volume oxygen; and (e) collecting the nitrogen-enriched gas stream as a residue of membrane separation.

Claim 11

A membrane-permeation process for producing nitrogen-enriched gas which comprises: (a) combusting a carbonaceous fuel to form a combustion gas comprising, on a dry basis, from about 70 to about 86% by volume nitrogen, from about 4 to about 20% by volume carbon dioxide and from about 0.1 to about 6% by volume oxygen; (b) processing the combustion gas stream in a first stage to remove to the extent present; (i) particulate matter by filtration; and (ii) gas oxides of nitrogen and oxides of sulfur; (c) compressing the treated combustion as to a pressure of about 100 to about 800 psig; (d) introducing the compressed combustion gas stream to a membrane separation zone comprising at least one membrane having an oxygen and/or carbon dioxide-to-nitrogen ratio of permeability of from about 2.0 to about nitrogen ratio of permeability of from about 2.0 to about 20.0 which rejects nitrogen gas to form a nitrogen-enriched gas stream to the preferential passage of oxygen and at a temperature of from about 70° to about 160° F. and above the dew point of water in the compressed combustion gas stream, said nitrogen enriched gas stream containing at least 90% by volume nitrogen and no more than about 1 to about 5% by volume oxygen; and (e) collecting the nitrogen-enriched gas stream as a residue of membrane separation.

Claim 12

A process as claimed in claim 9 in which the membrane is made of a material selected from the group of cellulose acetate, silicone polymers, and polysulfones.

Claim 13

A process as claimed in claim 9 in which the carbonaceous fuel is sweet natural gas, the combustion gas contains on a dry basis about 86% by volume nitrogen, about 12% by volume carbon dioxide and about 2% by volume oxygen, and in which there is formed a residue product gas containing about 97% by volume or more of nitrogen, about 2% by volume or less of carbon dioxide and about 1% by volume oxygen.

Claim 14

A process as claimed in claim 10 in which the carbonaceous fuel is sweet natural gas, the combustion gas contains on a dry basis about 86% by volume nitrogen, about 12% by volume carbon dioxide and about 2% by volume oxygen, and in which there is formed a residue product gas containing about 97% by volume or more of nitrogen, about 2% by volume or less of carbon dioxide and about 1% by volume oxygen.