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US4927704A
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Abrasion-resistant plastic articles and method for making them
Assignee: SABIC Global Technologies BV
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Filing: 1989-04-11
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Granted: 1990-05-22
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Expires: 2009-04-11
Abstract
Abstract An abrasion-resistant article and method for making is disclosed. The article includes a plastic substrate and a gradational coating applied by plasma-enhanced chemical vapor deposition to the surface thereof.
Inventors
- 👤 Clive W. Reed
- 👤 Stefan J. Rzad
- 👤 John C. Devins
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 18:50
CPC Classifications
C; C08; C08J; C08J7/00; C08J7/12; C08J7/123; B; B05; B05D; B05D1/00; B05D1/62; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C23C16/308; C23C16/44; C23C16/455; Y; Y10; Y10T; Y10T428/00; Y10T428/249921; Y10T428/31504; Y10T428/31652; Y10T428/31663
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
106 words
A method for preparing an abrasion-resistant plastic article, comprising plasma-enhanced chemical vapor deposition of an abrasion-resistant gradational layer onto a plastic substrate, wherein the composition of the gradational layer changes gradually in a direction perpendicular to the substrate surface from a composition consisting essentially of an interfacial material selected from the group consisting of organosilicon, organometallic, acrylic, and polyolefin materials, to a composition consisting essentially of an abrasion-resistant material selected from the group consisting of silicon dioxide, silicon nitride, silicon oxynitride, silicon carbide, silicon carbonitride, boron oxide, boron nitride, aluminum oxide, aluminum nitride, titanium dioxide, tantalum oxide, iron oxide, germanium oxide, germanium carbide, and mixtures thereof.
Claim 2
Independent Claim
106 words
A method for preparing an abrasion-resistant plastic article, comprising plasma-enhanced chemical vapor deposition of an abrasion-resistant gradational layer onto a plastic substrate, wherein the composition of the gradational layer changes gradually in a direction perpendicular to the substrate surface from a composition consisting essentially of an interfacial material selected from the group consisting of organosilicon, organometallic, acrylic, and polyolefin materials, to a composition consisting essentially of an abrasion-resistant material selected from the group consisting of silicon dioxide, silicon nitride, silicon oxynitride, silicon carbide, silicon carbonitride, boron oxide, boron nitride, aluminum oxide, aluminum nitride, titanium dioxide, tantalum oxide, iron oxide, germanium oxide, germanium carbide, and mixtures thereof.
Claim 3
Dependent Claim
19 words
The method of claim 1 wherein the interfacial material is formed by polymerizing an olefinic monomer in the plasma.
Claim 4
Dependent Claim
19 words
The method of claim 1 wherein the interfacial material is formed by polymerizing an acrylic monomer in the plasma.
Claim 5
Dependent Claim
20 words
The method of claim 1 wherein the interfacial material is formed by polymerizing an organosilicon monomer vapor in the plasma.
Claim 6
Dependent Claim
22 words
The method of claim 4 wherein the organosilicon monomer is selected from the group consisting of hexamethyldisilazane, hexamethyldisiloxane, vinyl trimethylsilane, and octamethylcyclotetrasiloxane.
Claim 7
Dependent Claim
27 words
The method of claim 5 wherein the abrasion-resistant material is selected from the group consisting of silicon carbide, silicon dioxide, silicon nitride, silicon oxynitride, and mixtures thereof.
Claim 8
Dependent Claim
15 words
The article produced by applying the abrasion-resistant coating of claim 1 on a plastic substrate.
Claim 9
Dependent Claim
14 words
The method of claim 1 wherein the coating is deposited onto a polycarbonate substrate.
Claim 10
Dependent Claim
21 words
The method of claim 8 wherein a primer is applied to the polycarbonate substrate prior to the plasma-enhanced chemical vapor deposition.
Claim 11
Dependent Claim
67 words
The method of claim 1 wherein the plasma-enhanced chemical vapor deposition comprises passing a feed composition of gradational layer precursors into a reactor chamber in a laminar flow relative to a substrate surface situated therein while generating an electrical field in the chamber to form a plasma of the precursors, each of which reacts in the plasma and on the underlying surface to form the gradational layer.
Claim 12
Dependent Claim
18 words
The method of claim 10 wherein the laminar flow is characterized by a Reynolds value of about 2.5.
Claim 13
Dependent Claim
82 words
The method of claim 10 wherein the deposition is carried out by: (I) passing the interfacial material precursor into the reactor chamber for a preselected time in the absence of abrasion-resistant material precursors, followed by (II) changing the feed composition by controlled adjustment means from the interfacial material precursor to the abrasion-resistant material precursor over a preselected time period, and then (III) passing the abrasion-resistant material precursor into the reactor chamber in the absence of interfacial material precursors for a preselected time.
Claim 14
Dependent Claim
25 words
The method of claim 12 wherein the feed composition in step (II) is changed linearly from the interfacial material precursor to the abrasion-resistant material precursor.
Claim 15
Dependent Claim
25 words
The method of claim 12 wherein the feed composition in step (II) is changed exponentially from the interfacial material precursor to the abrasion-resistant material precursor.
Claim 16
Dependent Claim
29 words
The method of claim 12 wherein each gaseous reactant is passed into the chamber mixed with a carrier gas which flows at a constant rate throughout said plasma deposition.
Claim 17
Dependent Claim
19 words
The method of claim 15 wherein the reactor chamber pressure is maintained at a constant value throughout said deposition.
Claim 18
Dependent Claim
22 words
The method of claim 16 wherein the plasma is formed by an electrical generator operating at a constant power value and frequency.
Claim 19
Dependent Claim
55 words
The method of claim 17 wherein the reactor chamber pressure is maintained at a value between about 50 millitorrs and about 10 Torrs; and wherein the generator operates at dc or at ac frequencies of between about 50 kHz and about 10 GHz, and a power value of between about 10 watts and 5000 watts.
Claim 20
Dependent Claim
29 words
The method of claim 15 wherein the interfacial material precursor is an organosilicon compound; the abrasion-resistant material precursors are nitrous oxide and silane; and the carrier gas is helium.
Claim 21
Dependent Claim
101 words
The method of claim 19 wherein the organosilicon compound in step (I) has a flow rate ranging from about 5 sccm to about 250 sccm; the silane in step (III) has a flow rate from about 10 sccm to about 100 sccm; the nitrous oxide in step (III) has a flow rate of from about 300 sccm to about 5000 sccm; and the helium flow rate is maintained at a constant value in the range between about 500 sccm and 5000 sccm; the total gas flow in each of steps (I), (II) and (III) also being maintained at a constant value.
Claim 22
Dependent Claim
23 words
The method of claim 20 wherein the feed composition is changed exponentially from the interfacial material precursor to the abrasion resistant material precursor.
Claim 23
Dependent Claim
20 words
The method of claim 20 wherein the substrate is heated to a temperature between about room temperature and 130° C.
Claim 24
Dependent Claim
9 words
The article produced by the method of claim 22.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-05-21 | 1993-11-20 | 1994-05-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-05-21 | 1997-11-20 | 1998-05-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-05-21 | 2001-11-20 | 2002-05-22 | $7700.00 | Window Closed / Lapsed |