Patent US4891152A successfully refreshed from Google Patents.
US4891152A
Expired / Lapsed
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Dispersion of liquid crystal droplets in a photopolymerized matrix and devices made therefrom
Assignee: Victor Company of Japan Ltd
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Filing: 1987-12-28
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Granted: 1990-01-02
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Expires: 2007-12-28
Abstract
Abstract A composite material having droplets of a liquid crystal material in a matrix of a coploymer of a multifunctional acrylate, or a mixture of different multifunctional acrylates, and a multifunctional mercaptan is prepared by photopolymerization. The liquid crystal material is initially mixed with a multifunctional acrylate monomer, a multifunctional mercaptan, and a photoinitiator to form a solution. The solution is exposed to ultraviolet light, whereupon the multifunctional acrylate monomer and multifunctional mercaptan copolymerize in a step reaction, and the liquid crystal separates from the copolymer as droplets dispersed throughout the copolymer matrix. The resulting material is placed between transparent, electrically conducting plates to form an electro-optic display device.
Inventors
- 👤 Leroy J. Miller
- 👤 Camille van Ast
- 👤 Frederick G. Yamagishi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 07:18
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/52; C09K19/54; C09K19/542; C09K19/544; C09K3/00; C09K2323/00
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
49 words
A composite material, comprising a plurality of droplets of a liquid crystal material within a matrix of a copolymer of a multifunctional acrylate and a multifunctional mercaptan, the liquid crystal having a solubility in the copolymer that is less than its solubility in a mixture of the unpolymerized constituents.
Claim 2
Dependent Claim
49 words
A composite material, comprising a plurality of droplets of a liquid crystal material within a matrix of a copolymer of a multifunctional acrylate and a multifunctional mercaptan, the liquid crystal having a solubility in the copolymer that is less than its solubility in a mixture of the unpolymerized constituents.
Claim 3
Dependent Claim
15 words
The composite material of claim 1, wherein the liquid crystal material is a cyanobiphenyl-containing mixture.
Claim 4
Dependent Claim
16 words
The composite material of claim 1, wherein the multifunctional acrylate is a mixture of multifunctional acrylates.
Claim 5
Dependent Claim
14 words
The composite material of claim 1, wherein the multifunctional acrylate is a multifunctional methacrylate.
Claim 6
Dependent Claim
81 words
The composite material of claim 1, wherein the multifunctional acrylate is an acrylate selected from the group consisting of bis(1-acryloxy-2-hydroxypropyl)phthalate, bisphenol-A diacrylate, 1,3-butanediol diacrylate, 1,4-butanediol diacrylate, diethylene glycol diacrylate, dipentaerthritol monohydroxypentaacrylate, ethylene diacrylate, glycerol triethoxy triacrylate, glycerol propoxy triacrylrate, 1,6-hexamethylene diacrylate, 3-methylpentanediol diacrylate, neopentyl glycol diacrylate, pentaerythritol tetraacrylate, pentaerythritol triacrylate, p-phenylene diacrylate, poly(ethylene glycol 400 diacrylate), 1,3-propanediol diacrylate, tetraethylene glycol diacrylate, thiodiethylene glycol diacrylate, triethylene glycol diacrylate, trimethylolpropanetriethoxytriacrylate, 1,1,1-trimethylolpropane triacrylate, tripropylene glycol diacrylate, tris(2-acryloxyethyl)isocyanurate, ethoxylated bisphenol-A diacrylate, tris(acryloxy-2-hydroxypropyl)ether, and mixtures thereof.
Claim 7
Dependent Claim
54 words
The composite material of claim 1, wherein the multifunctional acrylate monomer is a methacrylate selected from the group consisting of bis(2-methacryloxyethyl)phosphate, bis(methacryloxy-2-hydroxypropyloxy)diethylene glycol, 1,3-butanediol dimethacrylate, 2,2-dimethylpropanediol diemthacrylate, diurethane dimethacrylate, 1,1,2-dodecanediol dimethacrylate, glycerol trimethacrylate, methacrylic anhydride, 1,5-pentanediol dimethacrylate, poly(ethylene glycol 200 dimethacrylate), poly(ethylene glycol 400 dimethacrylate), silicone (IV) trimethacrylate, bisphenol-A diacrylate, phenylenediacrylate, and mixtures thereof.
Claim 8
Dependent Claim
29 words
The composite material of claim 1, wherein the multifunctional acrylate monomer is an acrylate selected from the group consisting of diurethane dimethacrylate, tripropyleneglycol diacrylate, pentaerythritol tetra-acrylate, and mixtures thereof.
Claim 9
Dependent Claim
51 words
The composite material of claim 1, wherein the multifunctional mercaptan is selected from the group consisting of 2,2'-dimercaptodiethyl ether, glycol dimercaptoacetate, glycol dimercaptopropionate (also termed ethylene bis(3-mercaptopropionate)), pentaerythritol tetra(3-mercaptopropionate), pentaerythritol tetrathioglycolate, trimethylolethane tri(3-mercaptopropionate), trimethylolethane trithioglycolate, trimethylolpropane tri(3-mercaptopropionate), trimethylolpropane trithioglycolate, dipentaerythritol hexa(3-mercaptopropionate), polyethylene glycol glycol dimercaptoacetate, polyethylene glycol di(3-mercaptopropionate), and mixtures thereof.
Claim 10
Dependent Claim
24 words
The composite material of claim 1, wherein the multifunctional mercaptan is selected from the group consisting of pentaerythritol tetramercaptopropionate, trimethylolpropane tri-3-mercaptopropionate, and mixtures thereof.
Claim 11
Dependent Claim
32 words
The composite material of claim 1, wherein the ratio of --SH groups in the multifunctional mercaptan to the carbon double bonds in the multifunctional acrylate is from about 0.5 to about 2.0.
Claim 12
Dependent Claim
31 words
The composite material of claim 1, wherein the ratio of --SH groups in the multifunctional mercaptan to the carbon double bonds in the multifunctional acrylate is from about 1.5 to 1.9.
Claim 13
Dependent Claim
99 words
A liquid crystal display device, comprising: a pair of spaced transparent conductive substrates; and a composite material disposed between said substrates, said composite material comprising a plurality of droplets of a liquid crystal material within a matrix of a copolymer of a multifunctional acrylate, having at least two functional groups selected from the group consisting of acryloyl and methacryloyl, and a multifunctional mercaptan, having at least two thiol groups, the solubility of the liquid crystal material being greater in a solution of the multifunctional acrylate and the multifunctional mercaptan than in the copolymer formed from the solution by photopolymerization.
Claim 14
Dependent Claim
99 words
A liquid crystal display device, comprising: a pair of spaced transparent conductive substrates; and a composite material disposed between said substrates, said composite material comprising a plurality of droplets of a liquid crystal material within a matrix of a copolymer of a multifunctional acrylate, having at least two functional groups selected from the group consisting of acryloyl and methacryloyl, and a multifunctional mercaptan, having at least two thiol groups, the solubility of the liquid crystal material being greater in a solution of the multifunctional acrylate and the multifunctional mercaptan than in the copolymer formed from the solution by photopolymerization.
Claim 15
Dependent Claim
15 words
The display device of claim 12, wherein the liquid crystal material is a cyanobiphenyl-containing mixture.
Claim 16
Dependent Claim
16 words
The display device of claim 12, wherein the multifunctional acrylate is a mixture of multifunctional acrylates.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-01-01 | 1993-07-03 | 1994-01-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-01-01 | 1997-07-03 | 1998-01-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-01-01 | 2001-07-03 | 2002-01-02 | $7700.00 | Window Closed / Lapsed |