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US4886728A Expired / Lapsed US ⏱️ 0.0 years remaining

Use of particular mixtures of ethyl lactate and methyl ethyl ketone to remove undesirable peripheral material (e.g. edge beads) from photoresist-coated substrates

Assignee: Olin Microelectronic Chemicals Inc
•
Filing: 1988-01-06
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Granted: 1989-12-12
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Expires: 2008-01-06
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Abstract

Abstract A process for removing unwanted photoresist material from the peripheral areas of a photoresist substrate comprising the steps of: (a) spin coating a photoresist solution onto a surface of a substrate, thereby applying a photoresist coating which comprises a uniform film over substantially all of said substrate surface except for unwanted photoresist material deposits at the peripheral areas of said surface; (b) contacting said peripheral area of the coated substrate with a sufficient amount of a solvent mixture comprising a mixture of ethyl lactate and methyl ethyl ketone present in a volume ratio of about 65:35 to about 25:75, respectively, to selectively dissolve said unwanted deposits without adversely affecting said uniform film; and (c) separating said dissolved deposits from said coated substrate.

Inventors

  • 👤 Thomas E. Salamy
  • 👤 Marvin L. Love, Jr.
  • 👤 Mark E. Towner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 18:44
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03F; G03F7/00; G03F7/16; G03F7/162

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 123 words
A process for removing unwanted photoresist material from the peripheral areas of a photoresist substrate comprising the steps of: (a) spin coating a photoresist solution onto a surface of a substrate, thereby applying a photoresist coating which comprises a uniform film over substantially all of said substrate surface except for unwanted photoresist material deposits at the peripheral areas of said surface; (b) contacting said peripheral areas of the coated substrate with a sufficient amount of a solvent mixture comprising a mixture of ethyl lactate and methyl ethyl ketone present in a volume ratio of about 65:35 to about 25:75, respectively, to selectively dissolve said unwanted deposits without adversely affecting said uniform film; and 1 (c) separating said dissolved deposits from said coated substrate.
Claim 2
Dependent Claim 123 words
A process for removing unwanted photoresist material from the peripheral areas of a photoresist substrate comprising the steps of: (a) spin coating a photoresist solution onto a surface of a substrate, thereby applying a photoresist coating which comprises a uniform film over substantially all of said substrate surface except for unwanted photoresist material deposits at the peripheral areas of said surface; (b) contacting said peripheral areas of the coated substrate with a sufficient amount of a solvent mixture comprising a mixture of ethyl lactate and methyl ethyl ketone present in a volume ratio of about 65:35 to about 25:75, respectively, to selectively dissolve said unwanted deposits without adversely affecting said uniform film; and 1 (c) separating said dissolved deposits from said coated substrate.
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein said substrate is silicon oxide/silicon wafer.
Claim 4
Dependent Claim 23 words
The process of claim 1, wherein said photoresist solutions comprise a solution of a novolak resin and a naphthoquinone diazide photosensitizer in a
Claim 5
Dependent Claim 24 words
The process of claim 1 wherein said volume ratio of ethyl lactate to methyl ethyl ketone is from about 60:40 to about 40:60, respectively.
Claim 6
Dependent Claim 11 words
The process of claim 4 wherein said volume ratio is 50:50.
Claim 7
Dependent Claim 46 words
The process of claim 1 wherein said solvent contacting step (b) is carried out by directing said solvent mixture against the backside surface of said substrate periphery by means of a nozzle and allowing said solvent mixture to migrate over the peripheral edge of said substrate.
Claim 8
Dependent Claim 133 words
A process for removing unwanted photoresist material from the peripheral areas of a silicon oxide/silicon wafer comprising: (a) spin coating a photoresist solution comprising a novolak resin and a naphthoquinone diazide photosensitizer in a solvent onto the top surface of said wafer, thereby applying a photoresist coating which comprises a uniform film over substantially all of said wafer surface except for unwanted photoresist material deposits at the periperal areas of said wafer; (b) contacting said peripheral areas of the coated wafer with a sufficient amount of a solvent mixture comprising a mixture of ethyl lactate and methyl ethyl ketone present in a volume ratio of about 65:35 to about 25:75, respectively, to selectively dissolve said unwanted deposits without adversely affecting said uniform film; and (c) separating said dissolved deposits from said coated wafer.
Claim 9
Dependent Claim 133 words
A process for removing unwanted photoresist material from the peripheral areas of a silicon oxide/silicon wafer comprising: (a) spin coating a photoresist solution comprising a novolak resin and a naphthoquinone diazide photosensitizer in a solvent onto the top surface of said wafer, thereby applying a photoresist coating which comprises a uniform film over substantially all of said wafer surface except for unwanted photoresist material deposits at the periperal areas of said wafer; (b) contacting said peripheral areas of the coated wafer with a sufficient amount of a solvent mixture comprising a mixture of ethyl lactate and methyl ethyl ketone present in a volume ratio of about 65:35 to about 25:75, respectively, to selectively dissolve said unwanted deposits without adversely affecting said uniform film; and (c) separating said dissolved deposits from said coated wafer.
Claim 10
Dependent Claim 24 words
The process of claim 7 wherein said volume ratio of ethyl lactate to methyl ethyl ketone is from about 60:40 to about 40:60, respectively.
Claim 11
Dependent Claim 11 words
The process of claim 8 wherein said volume ratio is 50:50.
Claim 12
Dependent Claim 43 words
The process of claim 7 wherein said solvent contacting step (b) is carried out by directing said solvent mixture against the backside of said wafer by means of a nozzle and allowing the solvent mixture to migrate over the edge of the wafer.
Claim 13
Dependent Claim 16 words
The process of claim 7 wherein said novolak resin is a mixed isomer cresol/formaldehyde novolak resin.

References Cited (Backward Citations)

US4113492A Cited
US4367071A Cited
US4685975A Cited
US4510176A Cited
US4518678A Cited
EP0211667A2 Cited
US4732836A Cited
US4732785A Cited
EP0273026A2 Cited
JPH05128001A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-12-11 1993-06-12 1993-12-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-12-11 1997-06-12 1997-12-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-12-11 2001-06-12 2001-12-12 $7700.00 Window Closed / Lapsed

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