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US4844884A Expired / Lapsed US ⏱️ 0.0 years remaining

Cosmetic sunscreen product for the face and body

Assignee: Givaudan SA
•
Filing: 1987-10-23
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Granted: 1989-07-04
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Expires: 2007-10-23
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Abstract

Abstract Cosmetic sunscreen products which contain a tyrosine derivative of the formula: <IMAGE> in which R1 is H or CH3-(CH2)x, with X being 1 to 20, and R2 is CH3CO- or CH3-(CH2)y-CO, with Y being 1 to 20, provide a long lasting and dark, natural tan after a short exposure to sunlight. The sunscreen product may contain an activator which is an alkali metal or alkaline earth metal salt of adenosine-5'-tri-, di-, or monophosphoric acid and mixtures thereof with an alkali metal or alkaline earth metal hydrogen phosphate.

Inventors

  • 👤 Wladimir Tur

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:39
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/44; A61Q; A61Q17/00; A61Q17/04; A61Q19/00; A61Q19/04

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 66 words
A cosmetic sunscreen product for the face and body, which comprises at least one tyrosine derivative of the formula ##STR5## wherein R 1 is H or CH 3 --(CH 2 ) x , with x being an integer from 1 to 20 and R 2 is CH 3 CO or CH 3 --(CH 2 ) y CO, with y being an integer from 1 to 20.
Claim 2
Dependent Claim 66 words
A cosmetic sunscreen product for the face and body, which comprises at least one tyrosine derivative of the formula ##STR5## wherein R 1 is H or CH 3 --(CH 2 ) x , with x being an integer from 1 to 20 and R 2 is CH 3 CO or CH 3 --(CH 2 ) y CO, with y being an integer from 1 to 20.
Claim 3
Dependent Claim 34 words
A cosmetic sunscreen product for the face and body as claimed in claim 4, wherein ##STR6## R 1 is H, ethyl, myristyl, palmityl or stearyl, and R 2 is acetyl, myristoyl, palmitoyl or stearoyl.
Claim 4
Dependent Claim 170 words
A cosmetic sunscreen product for the face and body, which comprises at least one tyrosine derivative and an activator which is at least one member selected from the group consisting of: (i) an alkali metal salt of adenosine-5'-triphosphoric acid of the formula ##STR7## (ii) an equimolar mixture of an alkali metal dihydrogen phosphate and the alkali metal salt of adenosine-5'-diphosphoric acid of the formula ##STR8## (iii) a mixture of two equivalents of an alkali metal dihydrogen phosphate and one equivalent of the alkali metal salt of adenosine-5'-monophosphoric acid of the formula ##STR9## (iv) an alkaline earth metal salt of adenosine-5'-triphosphoric acid of the formula ##STR10## (v) an equimolar mixture of an alkaline earth metal hydrogen phosphate and the alkaline earth metal salt of adenosine-5'-diphosphoric acid of the formula ##STR11## (vi) an equimolar mixture of an alkaline earth metal hydrogen phosphate and the alkaline earth metal salt of adenosine-5'-monophosphoric acid of the formula ##STR12## ##STR13## wherein AK is an alkali metal, EAK is an alkaline earth metal, and Bu is butyl.
Claim 5
Dependent Claim 170 words
A cosmetic sunscreen product for the face and body, which comprises at least one tyrosine derivative and an activator which is at least one member selected from the group consisting of: (i) an alkali metal salt of adenosine-5'-triphosphoric acid of the formula ##STR7## (ii) an equimolar mixture of an alkali metal dihydrogen phosphate and the alkali metal salt of adenosine-5'-diphosphoric acid of the formula ##STR8## (iii) a mixture of two equivalents of an alkali metal dihydrogen phosphate and one equivalent of the alkali metal salt of adenosine-5'-monophosphoric acid of the formula ##STR9## (iv) an alkaline earth metal salt of adenosine-5'-triphosphoric acid of the formula ##STR10## (v) an equimolar mixture of an alkaline earth metal hydrogen phosphate and the alkaline earth metal salt of adenosine-5'-diphosphoric acid of the formula ##STR11## (vi) an equimolar mixture of an alkaline earth metal hydrogen phosphate and the alkaline earth metal salt of adenosine-5'-monophosphoric acid of the formula ##STR12## ##STR13## wherein AK is an alkali metal, EAK is an alkaline earth metal, and Bu is butyl.
Claim 6
Dependent Claim 59 words
The sunscreen of claim 3, wherein said tyrosine derivative has the formula ##STR14## wherein R 1 is H or CH 3 --(CH 2 ) x , with x being an integer from 1 to 20 and R 2 is CH 3 CO or CH 3 --(CH 2 ) y CO, with y being an integer from 1 to 20.
Claim 7
Dependent Claim 75 words
A cosmetic sunscreen product for the face and body as claimed in claim 4, wherein said activator is at least one member selected from the group consisting of an alkali metal salt of adenosine-5'-triphosphoric acid of the formula ##STR15## in which AK is an alkali element, and an equimolar mixture of an alkali metal hydrogen phosphate and the alkali metal salt of adenosine-5'-diphosphoric acid of the formula ##STR16## in which AK is an alkali element.
Claim 8
Dependent Claim 40 words
A cosmetic sunscreen product for the face and body as claimed in claim 5, wherein said tyrosine derivative is one or more members selected from the group consisting of N-acetyltyrosine and N-acetyltyrosine ethyl ester and said alkali metal is sodium.
Claim 9
Dependent Claim 25 words
A cosmetic sunscreen product for the face and body as claimed in claim 4, which contains at least 0.3% by weight of said tyrosine derivative
Claim 10
Dependent Claim 23 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 0.3% by weight of N-acetyltyrosine.
Claim 11
Dependent Claim 25 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 0.4% by weight of N-acetyltyrosine ethyl ester.
Claim 12
Dependent Claim 23 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 1.0% by weight of N-myristoyltyrosine.
Claim 13
Dependent Claim 25 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 1.0% by weight of N-myristoyltyrosine myristyl ester.
Claim 14
Dependent Claim 23 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 1.0% by eight of N-palmitoyltyrosine.
Claim 15
Dependent Claim 25 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 1.0% by weight of N-palmitoyltyrosine palmityl ester.
Claim 16
Dependent Claim 23 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 1.0% by weight of N-stearoyltyrosine.
Claim 17
Dependent Claim 25 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 1.0% by weight of N-stearoyltyrosine stearyl ester.
Claim 18
Dependent Claim 30 words
A cosmetic sunscreen product for the face and body as claimed in claim 7, which contains at least 0.3% by weight of a mixture of N-acetyltyrosine and N-acetyltyrosine ethyl ester.
Claim 19
Dependent Claim 24 words
A cosmetic sunscreen product for the face and body as claimed in claim 4, which contains at least 0.01% by weight of said activator.
Claim 20
Dependent Claim 26 words
A cosmetic sunscreen product for the face and body as claimed in claim 17, which contains at least 0.01% by weight of adenosine-5'-triphosphoric acid disodium salt.
Claim 21
Dependent Claim 41 words
A cosmetic sunscreen product for the face and body as claimed in claim 17, which contains at least 0.015% by weight of a mixture of adenosine-5'-diphosphoric acid disodium salt and sodium hydrogen phosphate in the mixing ratio by weight of 4:1.
Claim 22
Dependent Claim 39 words
A cosmetic sunscreen product for the face and body as claimed in claim 17, which contains at least 0.015% by weight of a mixture of adenosine-5'-monophosphoric acid sodium salt and sodium hydrogen phosphate in the molar ratio of 1:2.
Claim 23
Dependent Claim 25 words
A cosmetic sunscreenproduct for the face and body as claimed in claim 17, which contains at least 0.02% by weight of adenosine-5'-triphosphoric acid di-n-butyl ester.
Claim 24
Dependent Claim 26 words
A cosmetic sunscreen product for the face and body as claimed in claim 17, which contains at least 0.02% by weight of adenosine-5'-diphosphoric acid di-n-butyl ester.
Claim 25
Dependent Claim 26 words
A cosmetic sunscreen product for the face and body as claimed in claim 17, which contains at least 0.02% by weight of adenosine-5'-monophosphoric acid n-butyl ester.
Claim 26
Dependent Claim 47 words
A cosmetic sunscreen product for the face and body as claimed in claim 17, which contains at least 0.01% by weight of adenosine-5'-triphosphoric acid disodium salt and wherein said tyrosine derivative is at least one member selected from the group consisting of N-acetyltyrosine and N-acetyltyrosine ethyl ester.
Claim 27
Dependent Claim 62 words
A cosmetic sunscreen product for the face and body as claimed in claim 17, which contains at least 0.06% by weight of a mixture of adenosine-5'-diphosphoric acid disodium salt and sodium hydrogen phosphate in the mixing ratio by weight of 4:1 and wherein said tyrosine derivative is at least one member selected from the group consisting of N-acetyltyrosine and N-acetyltyrosine ethyl ester.
Claim 28
Dependent Claim 40 words
A cosmetic sunscreen product for the face and body as claimed in claim 14, which is in the form of a solution in a solvent selected from the group consisting of water, aqueous ethanol, aqueous isopropyl alcohol and aqueous glycols.
Claim 29
Dependent Claim 30 words
A cosmetic sunscreen product for the face and body as claimed in claim 4, which is in the form of a liquid emulsion or gel and further comprises suitable solvents.
Claim 30
Dependent Claim 39 words
A cosmetic sunscreen product for the face and body as claimed in claim 4, which further comprises one or more members selected from the group consisting of mineral oils, vegetable oils, animal oils, waxes, and fat-soluble glycols and polyglycols.
Claim 31
Dependent Claim 39 words
A cosmetic sunscreen product for the face and body as claimed in claim 4, which further comprises at least one member of the group consisting of swelling or thickening agents, protein hydrolyzate, surface-active agents, film-forming substances, perfume, and emulsifiers.
Claim 32
Dependent Claim 10 words
The sunscreen of claim 4, which further comprises a UV-filter.
Claim 33
Dependent Claim 21 words
The sunscreen of claim 4, which is in the form of an aerosol or foam and further comprises a propellant gas.

References Cited (Backward Citations)

DE964172C Cited
DE1617590A1 Cited
FR2077725A1 Cited
US3937804A Cited
US3937809A Cited
FR2324293A1 Cited
US4021538A Cited
US4419343A Cited
CH642537A5 Cited
EP0117080A2 Cited
US4515773A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-07-03 1993-01-02 1993-07-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-07-03 1997-01-02 1997-07-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-07-03 2001-01-02 2001-07-04 $7700.00 Window Closed / Lapsed

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