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US4843150A Expired / Lapsed US ⏱️ 0.0 years remaining

Pyrazolone or pyridone type water soluble disazo colorant containing one or two triazine rings

Assignee: Dystar Japan Ltd
•
Filing: 1987-07-09
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Granted: 1989-06-27
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Expires: 2007-07-09
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Abstract

Abstract A water soluble disazo colorant represented by formula (I) in the form of free acid: <IMAGE> (I) wherein K represents <IMAGE> +TR <IMAGE> [wherein A represents a methyl group or a carboxylic group; R2 represents a hydrogen atom, an alkyl group of 1 to 8 carbon atoms, a sulfoalkyl grouop of 1 to 4 carbon atoms, or an alkyl group of 1 to 4 carbon atoms which is substituted by an alkoxy group of 1 to 4 carbon atoms; R3 represents a hydrogen atom, a halogen atom, a cyano group, a -CONH2 group, a carboxyl group, a sulfonic group, or a sulfomethyl group, p represents an integer of 1 or 2]; Z represents a fluorine atom or <IMAGE> [wherein R4 represents a hydrogen atom or an alkyl group of 1 to 4 carbon atoms; R5 and R6 each represents independently a hydrogen atom, an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, a sulfonic group, or a halogen atom; Y represents -SO2CH=CH2 or -SO2CH2CH2W (wherein W represents a group which is released by the action of an alkali)]; R1 represents a hydrogen atom or a lower alkyl group of 1 to 4 carbon atoms; Q represents a divalent aromatic or aliphatic residual group; and l, m, and n each represents an integer of 0 or 1. Such colorants are useful in the dyeing of fibrous materials.

Inventors

  • 👤 Toshio Hihara
  • 👤 Yukiharu Shimizu
  • 👤 Kanzi Shimizu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 05:01
CPC Classifications
C; C09; C09B; C09B62/00; C09B62/02; C09B62/04; C09B62/08; C09B62/09; C09B62/44; C09B62/503; C09B62/507; C09B62/513; D; D06; D06P; D06P1/00; D06P1/38

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 204 words
A water solule disazo colorant represented by formula (I) in the form of free acid: ##STR148## wherein K represents ##STR149## [wherein A represents methyl or carboxyl; R 2 represents hydrogen, allkyl of 1 to 8 carbon, sulfoalkyl of 1 to 4 carbon, or alkyl group of 1 to 4 carbon which is substituted by alkoxy of 1 to 4 carbon; R 3 represents hydrogen, halogen, cyano, --CONH 2 , carboxyl, sulfonic, or sulfomethyl; p represents an integer of 1 to 2]; Z represents ##STR150## [wherein R 4 represents hydrogen or alkyl of 1 to 4 carbon; R 5 and R 6 each represents independently hydrogen, alkyl of 1 to 4 carbon, alkoxy of 1 to 4 carbon, sulfonic, or halogen; Y represents --SO 2 CH═CH 2 or --SO 2 CH 2 CH 2 W (wherein W represents --OSO 3 H, --SSO 3 H, --OPO 3 H 2 , --OCOCH 3 , or halogen]; R 1 represents hydrogen or lower alkyl of 1 to 4 carbon; Q represents phenylene or naphtylene which may be substituted by alkyl of 1 to 4 carbon, alkoxy of 1 to 4 carbon, halogen, carboxylic, or sulfonic; and l, m, and n each represents an integer of 0 or 1.
Claim 2
Dependent Claim 204 words
A water solule disazo colorant represented by formula (I) in the form of free acid: ##STR148## wherein K represents ##STR149## [wherein A represents methyl or carboxyl; R 2 represents hydrogen, allkyl of 1 to 8 carbon, sulfoalkyl of 1 to 4 carbon, or alkyl group of 1 to 4 carbon which is substituted by alkoxy of 1 to 4 carbon; R 3 represents hydrogen, halogen, cyano, --CONH 2 , carboxyl, sulfonic, or sulfomethyl; p represents an integer of 1 to 2]; Z represents ##STR150## [wherein R 4 represents hydrogen or alkyl of 1 to 4 carbon; R 5 and R 6 each represents independently hydrogen, alkyl of 1 to 4 carbon, alkoxy of 1 to 4 carbon, sulfonic, or halogen; Y represents --SO 2 CH═CH 2 or --SO 2 CH 2 CH 2 W (wherein W represents --OSO 3 H, --SSO 3 H, --OPO 3 H 2 , --OCOCH 3 , or halogen]; R 1 represents hydrogen or lower alkyl of 1 to 4 carbon; Q represents phenylene or naphtylene which may be substituted by alkyl of 1 to 4 carbon, alkoxy of 1 to 4 carbon, halogen, carboxylic, or sulfonic; and l, m, and n each represents an integer of 0 or 1.
Claim 3
Dependent Claim 24 words
A water soluble disazo colorant as in claim 1, wherein K is ##STR151## in which A and p are as defined in claim 1.
Claim 4
Dependent Claim 13 words
A water solule disazo colorant as in claim 1 wherein l is 0.
Claim 5
Dependent Claim 16 words
A water soluble disazo colorant as in claim 1, wherein R 1 is a hydrogen atom.
Claim 6
Dependent Claim 16 words
A water soluble disazo colorant as in claim 1, wherein m and n each is 0.
Claim 7
Dependent Claim 28 words
A water soluble disazo colorant as in claim 1, wherein Z is ##STR152## in which R 4 , R 5 and Y are as defined in claim 1.
Claim 8
Dependent Claim 28 words
A water soluble disazo colorant as in claim 1, wherein K is ##STR153## in which A and p are as defined in claim 1 and l is 0.
Claim 9
Dependent Claim 50 words
A water soluble disazo colorant as in claim 1, wherein K is ##STR154## in which A and p are as defined in claim 1 and l is 0, and Z is ##STR155## in which R 4 , R 5 , R 6 and Y are as defined in claim 1.
Claim 10
Dependent Claim 56 words
A water soluble disazo colorant as in claim 1, wherein K is ##STR156## in which A and p are as defined in claim 1, Z is ##STR157## in which R 4 , R 5 and Y are as defined in claim 1, R 1 is a hydrogen atom, and l, m, and n each is 0.
Claim 11
Dependent Claim 23 words
A water soluble disazo colorant as in claim 1 wherein the colorant is a water soluble reactive dye stuff for dyeing cellulose-containing fiber.

References Cited (Backward Citations)

US3926944A Cited
GB1454210A Cited
GB1461125A Cited
US4228071A Cited
FR2413443A1 Cited
GB2085908A Cited
US4670547A Cited
JPS60215882A Cited
US4645832A Cited
GB2159829A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-26 1992-12-26 1993-06-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-26 1996-12-26 1997-06-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-26 2000-12-26 2001-06-27 $7700.00 Window Closed / Lapsed

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