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US4228071A Expired / Lapsed US ⏱️ 0.0 years remaining

Triazine containing fiber-reactive disazo dyestuffs

Assignee: BASF Corp
•
Filing: 1978-02-27
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Granted: 1980-10-14
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Expires: 1998-02-27
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Abstract

Abstract Fibre-reactive disazo dyestuffs of the formula <IMAGE> (1) wherein X represents a halogen atom, Y represents the radical of an enolisable coupling component, and the bridging member -NH-D-NH- represents the radical of an aliphatic or aromatic diamine. These dyestuffs are suitable for dyeing silk, leather, wool, superpolyamide, superpolyurethanes and cellulose-containing materials to produce dyeings of high depth of color and good fastness to light and wet processing.

Inventors

  • 👤 Henri Riat
  • 👤 Karl Seitz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 03:02
CPC Classifications
C; C09; C09B; C09B62/00; C09B62/02; C09B62/04; C09B62/043

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 156 words
A fiber-reactive disazo dyestuff of the formula ##STR5## wherein X is fluoro, chloro or bromo; Y is the radical of a coupling component which contains an enolised or enolisable keto group is bound to the azo group in a position adjacent to the enolised or enolisable keto group, said coupling component selected from the group consisting of dihydroxyquinolines, hydroxyquinoline-sulphonic acids, barbituric acid, 3-methyl-5-pyrazolone, 1-phenyl-3-methyl-5-aminopyrazole-4'-sulphonic acid, 1-(2'-chlorophenyl)-3-methyl-5-pyrazolone-5'-sulphonic acid, α- and β-naphthyl-5-pyrazolone-sulphonic acids, 1-phenyl-3-methyl-5-pyrazolone, 1-phenyl-3-methyl-5-pyrazolone-2'-, -3'- or -4'-sulphonic acid, 1-phenyl-5-pyrazolone-3-carboxylic acid, 1-phenyl-5-pyrazolone-3-carboxylic acid-4'-sulphonic acid, 5-pyrazolone-3-carboxylic acid amide, 1-(2',5'-dichlorophenyl)-3-methyl-5-pyrazolone-4'-sulphonic acid, 1-(2'-methyl-6'-chlorophenyl)-3-methyl-5-pyrazolone-4'-sulphonic acid, 1-phenyl-3-methyl-5-aminopyrazole, 1-phenyl-3-carboxy-5-aminopyrazole, 2,6-dihydroxy-3-cyano-4-methylpyridine, 1-ethyl-3-cyano-4-methyl-6-hydroxy-pyridone-(2), 1-ethyl-3-aminocarbonyl-4-methyl-6-hydroxy-pyridone-(2), 1-ethyl-3-sulphomethyl-4-methyl-6-hydroxy-pyridone-(2), acetoacetic acid isopropylamide, acetoacetic acid cyclohexlamide, acetoacetic acid monoethanolamide, acetoacetic acid diethanolamide, acetoacetylaminobenzene, acetoacetylaminonaphthalene, and acetoacetylaminobenzene-2-, -3- or -4-sulphonic acid; and D is straight or branched chain alkylene of 1 to 6 carbon atoms, N,N'-diphenyleneurea, cyclohexylene, or is naphthylene, diphenylene, stilbenylene or phenylene which are unsubstituted or substituted by halo, lower alkyl, lower alkoxy, amino, ureido, nitro, hydroxy, carboxy or sulfo.
Claim 2
Dependent Claim 156 words
A fiber-reactive disazo dyestuff of the formula ##STR5## wherein X is fluoro, chloro or bromo; Y is the radical of a coupling component which contains an enolised or enolisable keto group is bound to the azo group in a position adjacent to the enolised or enolisable keto group, said coupling component selected from the group consisting of dihydroxyquinolines, hydroxyquinoline-sulphonic acids, barbituric acid, 3-methyl-5-pyrazolone, 1-phenyl-3-methyl-5-aminopyrazole-4'-sulphonic acid, 1-(2'-chlorophenyl)-3-methyl-5-pyrazolone-5'-sulphonic acid, α- and β-naphthyl-5-pyrazolone-sulphonic acids, 1-phenyl-3-methyl-5-pyrazolone, 1-phenyl-3-methyl-5-pyrazolone-2'-, -3'- or -4'-sulphonic acid, 1-phenyl-5-pyrazolone-3-carboxylic acid, 1-phenyl-5-pyrazolone-3-carboxylic acid-4'-sulphonic acid, 5-pyrazolone-3-carboxylic acid amide, 1-(2',5'-dichlorophenyl)-3-methyl-5-pyrazolone-4'-sulphonic acid, 1-(2'-methyl-6'-chlorophenyl)-3-methyl-5-pyrazolone-4'-sulphonic acid, 1-phenyl-3-methyl-5-aminopyrazole, 1-phenyl-3-carboxy-5-aminopyrazole, 2,6-dihydroxy-3-cyano-4-methylpyridine, 1-ethyl-3-cyano-4-methyl-6-hydroxy-pyridone-(2), 1-ethyl-3-aminocarbonyl-4-methyl-6-hydroxy-pyridone-(2), 1-ethyl-3-sulphomethyl-4-methyl-6-hydroxy-pyridone-(2), acetoacetic acid isopropylamide, acetoacetic acid cyclohexlamide, acetoacetic acid monoethanolamide, acetoacetic acid diethanolamide, acetoacetylaminobenzene, acetoacetylaminonaphthalene, and acetoacetylaminobenzene-2-, -3- or -4-sulphonic acid; and D is straight or branched chain alkylene of 1 to 6 carbon atoms, N,N'-diphenyleneurea, cyclohexylene, or is naphthylene, diphenylene, stilbenylene or phenylene which are unsubstituted or substituted by halo, lower alkyl, lower alkoxy, amino, ureido, nitro, hydroxy, carboxy or sulfo.
Claim 3
Dependent Claim 61 words
A dyestuff according to claim 1, of the formula ##STR6## wherein Y is the radical of a coupling component selected from the group consisting of α- and β-naphthyl-5-pyrazolone-sulfonic acids, 1-phenyl-3-methyl-5-pyrazolone-2'-, -3'-, or -4'-sulfonic acid, 1-phenyl-5-pyrazolone-3-carboxylic acid-4'-sulfonic acid, 1-(2',5'-dichlorophenyl)-3-methyl-5-pyrazolone-4'-sulfonic acid; and D is phenylene which is unsubstituted or substituted by halo, lower alkyl, lower alkoxy, amino, ureido, nitro, hydroxy, carboxy or sulfo.
Claim 4
Dependent Claim 11 words
Fibre-reactive disazo dyestuff according to claim 1 of the formula ##STR7##

References Cited (Backward Citations)

GB854432A Cited
US3119807A Cited
US3474084A Cited
CH501041A Cited
US3398133A Cited
US3542753A Cited
US3697500A Cited
US3646002A Cited
US3647778A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-14 1984-04-14 1984-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-14 1988-04-14 1988-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-14 1992-04-14 1992-10-14 $7700.00 Window Closed / Lapsed

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