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US4645832A Expired / Lapsed US ⏱️ 0.0 years remaining

Cellulose fiber-reactive disazo or trisazo dyes having a triazine ring substituted by A(B-sulfatoethyl) sulfonylanilino group

Assignee: Dystar Japan Ltd
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Filing: 1985-04-09
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Granted: 1987-02-24
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Expires: 2005-04-09
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Abstract

Abstract Reactive azo dyes represented by the general formula (I) or (II): <IMAGE> (I) <IMAGE> <IMAGE> (II) <IMAGE> wherein M is a hydrogen atom or an alkali metal, R1 is a hydrogen atom, a chlorine atom, a lower alkyl group, a lower alkoxy group, a nitro group or a carboxyl group, R2 and R8 are a lower alkyl group, a lower alkoxy group or a sulfonic acid group, R3, R7 and R9 are a hydrogen atom, a lower alkyl group, a lower alkoxy group, an acetylamino group or a sulfonic acid group, R4 and R5 are a hydrogen atom, a methyl group, a methoxy group or a sulfonic acid group, R6 is a hydrogen atom, a lower alkyl group, a lower alkoxy group or a sulfonic acid group, Z1 is a chlorine atom, a fluorine atom, an aliphatic or an aromatic amino residual group, a methoxy group or a phenoxy group, Z2 is the same one as Z1 when Z3 is <IMAGE> Z2 is a chlorine atom or a fluorine atom when Z3 is an aliphatic amino residual group, an aromatic amino residual group except <IMAGE> a methoxy group or a phenoxy group, Z3 is <IMAGE> an aliphatic amino residual group, an aromatic amino residual group except <IMAGE>BN,00 R4R5SO2C2H4SO3M,+RE a methoxy group, or a phenoxy group, m is 1, 2 or 3, m' is 2 or 3, n is 0 or 1, and the benzene rings A, B and C may be naphthalene rings.

Inventors

  • 👤 Toshio Niwa
  • 👤 Yoshiaki Kato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 03:04
CPC Classifications
C; C09; C09B; C09B62/00; C09B62/44; C09B62/503; C09B62/507; C09B62/513; C09B62/4401; C09B62/4403; C09B62/4411; C09B62/4415

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 223 words
A reactive azo dye represented by the following formula: ##STR610## wherein M represents hydrogen or alkali metal; R 1 represents hydrogen, chlorine, lower alkyl, lower alkoxy, nitro, carboxy; R 2 and R 8 represent lower alkyl, lower alkoxy or sulfonic acid; R 3 , R 7 and R 9 represent hydrogen, lower alkyl, lower alkoxy, acetylamino or sulfonic acid; R 4 and R 5 represent hydrogen, methyl, methoxy or sulfonic acid; R 6 represents hydrogen, lower alkyl, lower alkoxy or sulfonic acid; Z 1 represents chlorine, fluorine, aliphatic or atomatic amino group, methoxy or phenoxy; Z 2 represents the same as Z 1 when Z 3 represents ##STR611## Z 2 represents chlorine or fluorine when Z 3 represents aliphatic amino group, aromatic amino group except ##STR612## methoxy or phenoxy; Z 3 is ##STR613## aliphatic amino group, aromatic amino group except ##STR614## methoxy, or phenoxy; m represents 1, 2 or 3; m' represents 2 or 3; n represents 0 or 1, and the rings A, B and C each represent a benzene ring or naphthalene ring, wherein the aliphatic and aromatic amino residue represented by Z 1 , Z 2 and Z 3 are --NH 2 , alkylamino having 1 to 4 carbon atoms, ethanol-amino, β-cyanoethylamino, β-sulfoethylamino, --NHCH 2 COOH, anilino or anilino substituted with sulfo, chlorine, lower alkyl, lower alkoxy, nitro or carboxyl.
Claim 2
Dependent Claim 223 words
A reactive azo dye represented by the following formula: ##STR610## wherein M represents hydrogen or alkali metal; R 1 represents hydrogen, chlorine, lower alkyl, lower alkoxy, nitro, carboxy; R 2 and R 8 represent lower alkyl, lower alkoxy or sulfonic acid; R 3 , R 7 and R 9 represent hydrogen, lower alkyl, lower alkoxy, acetylamino or sulfonic acid; R 4 and R 5 represent hydrogen, methyl, methoxy or sulfonic acid; R 6 represents hydrogen, lower alkyl, lower alkoxy or sulfonic acid; Z 1 represents chlorine, fluorine, aliphatic or atomatic amino group, methoxy or phenoxy; Z 2 represents the same as Z 1 when Z 3 represents ##STR611## Z 2 represents chlorine or fluorine when Z 3 represents aliphatic amino group, aromatic amino group except ##STR612## methoxy or phenoxy; Z 3 is ##STR613## aliphatic amino group, aromatic amino group except ##STR614## methoxy, or phenoxy; m represents 1, 2 or 3; m' represents 2 or 3; n represents 0 or 1, and the rings A, B and C each represent a benzene ring or naphthalene ring, wherein the aliphatic and aromatic amino residue represented by Z 1 , Z 2 and Z 3 are --NH 2 , alkylamino having 1 to 4 carbon atoms, ethanol-amino, β-cyanoethylamino, β-sulfoethylamino, --NHCH 2 COOH, anilino or anilino substituted with sulfo, chlorine, lower alkyl, lower alkoxy, nitro or carboxyl.
Claim 3
Dependent Claim 44 words
The reactive azo dye as claimed in claim 1 represented by formula: ##STR615## wherein R 1 , R 2 , R 3 , R 4 , R 5 , M, m, n and Z 1 have the same meanings as defined in claim 1.
Claim 4
Dependent Claim 48 words
The reactive azo dye as claimed in claim 1 represented by formula: ##STR616## wherein R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , M, Z 1 , m' and n have the same meanings as defined in claim 1.
Claim 5
Dependent Claim 58 words
The reactive azo dye as claimed in claim 1 represented by formula: ##STR617## wherein X represents chlorine or fluorine; Y is aliphatic amino group, aromatic amino group except ##STR618## methoxy or phenoxy; and R 6 , R 7 , R 8 , R 9 , M, m' and n have the same meanings as defined in claim 1.
Claim 6
Dependent Claim 44 words
The reactive azo dye as claimed in claim 1, wherein said lower alkyl and alkoxy represented by R 1 , R 3 , R 6 , R 7 , R 8 and R 9 is alkyl or alkoxy having 1 to 4 carbon atoms.
Claim 7
Dependent Claim 20 words
The reactive azo dye as claimed in claim 1, wherein said alkali metal represented by M is sodium or potassium.

References Cited (Backward Citations)

US3223470A Cited
US4378313A Cited
US4378313B1 Cited
US4412948A Cited
JPS56100861A Cited
US4425270A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-23 1990-08-25 1991-02-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-23 1994-08-25 1995-02-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-23 1998-08-25 1999-02-24 $7700.00 Window Closed / Lapsed

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